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Nanocar The nanocar is a molecule designed in 2005 at Rice University by a group headed by Professor James Tour. Despite the name, the original nanocar does not contain a molecular motor, hence, it is not really a car. Rather, it was designed to answer t ...
Race is an international scientific competition with the aim of testing the performance of molecular machines and the scientific instruments used to control them. The race of the molecules takes place on a 100 nanometer track and was held for the first time in
Toulouse Toulouse ( , ; oc, Tolosa ) is the prefecture of the French department of Haute-Garonne and of the larger region of Occitania. The city is on the banks of the River Garonne, from the Mediterranean Sea, from the Atlantic Ocean and from Par ...
on 28 and 29 April 2017.


History

The idea for the race was formulated in January 2013 in the ACS Nano magazine by the Toulouse organizers of CEMES-
CNRS The French National Centre for Scientific Research (french: link=no, Centre national de la recherche scientifique, CNRS) is the French state research organisation and is the largest fundamental science agency in Europe. In 2016, it employed 31,637 ...
, this way a call for applications was launched to give the participating teams time to prepare appropriate nanocars. The race is officially announced by the National Centre for Scientific Research in November 2015 in Toulouse during Futurapolis1. On this occasion, five teams presented their prototype projects on November 27, 2015. The first race in the world of this type, between four vehicles, started on the 28 April 2017 at the CEMES-CNRS in Toulouse and lasted 36 hours. The Toulouse organizers also agreed on the competition of two more vehicles, which will then be remotely controlled via Internet from the CEMES-CNRS race room on the microscope of their own laboratory. These relates to the vehicles from
Ohio Ohio () is a state in the Midwestern region of the United States. Of the fifty U.S. states, it is the 34th-largest by area, and with a population of nearly 11.8 million, is the seventh-most populous and tenth-most densely populated. The sta ...
and Graz-Rice.


Competition


The track

The track of the first competition is a
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
surface, equipped with grooves to define race lanes in order to avoid losing vehicles. It is about 100 nanometres long, and includes two bends. It is located in a small enclosure cooled to -269°C under a primary vacuum of 10−10 mbar and is observed simultaneously by four
scanning tunneling microscope A scanning tunneling microscope (STM) is a type of microscope used for imaging surfaces at the atomic level. Its development in 1981 earned its inventors, Gerd Binnig and Heinrich Rohrer, then at IBM Zürich, the Nobel Prize in Physics in 1986. ...
s (STM) miniaturized for this event and operating on the same surface. Each microscope is responsible for driving a single vehicle (a single nanocar). During this competition, the nanocars should move as far as possible on the gold track during the 36 hours race. Speeds of 5 nanometers per hour were expected.


Nanocars

Nanocars are a new class of molecular machines that can roll across solid surfaces with structurally defined direction. They are molecules essentially composed of a few tens or hundreds of
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
and
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
atoms Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, an ...
and are measuring one to three
nanometers 330px, Different lengths as in respect to the molecular scale. The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm) or nanometer (American and British English spelling differences#-re ...
. The nanocar is propelled step by step by electrical impulses and
electron transfer Electron transfer (ET) occurs when an electron relocates from an atom or molecule to another such chemical entity. ET is a mechanistic description of certain kinds of redox reactions involving transfer of electrons. Electrochemical processes ar ...
from the tip of the STM. The resulting tunnel current flows through the nanocar between the tip of the microscope and the common metal track. There is no direct mechanical contact with the tip. The nanocar is therefore neither pushed nor deformed by the tip of the microscope during the race. Some of the electrons that pass through the nanocar release energy as small intramolecular vibrations that activate the nanocar's motor.


2017 Nanocar Race I


Teams

*
Switzerland ). Swiss law does not designate a ''capital'' as such, but the federal parliament and government are installed in Bern, while other federal institutions, such as the federal courts, are in other cities (Bellinzona, Lausanne, Luzern, Neuchâtel ...
: Swiss Nano Dragster,
University of Basel The University of Basel (Latin: ''Universitas Basiliensis'', German: ''Universität Basel'') is a university in Basel, Switzerland. Founded on 4 April 1460, it is Switzerland's oldest university and among the world's oldest surviving universit ...
*
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...
: Toulouse nanomobile club,
Paul Sabatier University Paul Sabatier University (''Université Paul Sabatier'', UPS, also known as Toulouse III) is a French public university, in the Academy of Toulouse. It is one of the several successor universities of the University of Toulouse. Toulouse III was ...
*
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...
/
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
: NanoPrix Team
University of Graz The University of Graz (german: link=no, Karl-Franzens-Universität Graz, ), located in Graz, Austria, is the largest and oldest university in Styria, as well as the second-largest and second-oldest university in Austria. History The unive ...
/
Rice University William Marsh Rice University (Rice University) is a Private university, private research university in Houston, Houston, Texas. It is on a 300-acre campus near the Houston Museum District and adjacent to the Texas Medical Center. Rice is ranke ...
*
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
: Nano-windmill Company
Technical University of Dresden TU Dresden (for german: Technische Universität Dresden, abbreviated as TUD and often wrongly translated as "Dresden University of Technology") is a public research university, the largest institute of higher education in the city of Dresden, th ...
(
TU Dresden TU Dresden (for german: Technische Universität Dresden, abbreviated as TUD and often wrongly translated as "Dresden University of Technology") is a public research university, the largest institute of higher education in the city of Dresden, th ...
) *
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
: Nano-Vehicle NIMS-MANA
National Institute for Materials Science is an Independent Administrative Institution and one of the largest scientific research centers in Japan. History The growth and development of today's scientific research center has passed through several phases in a number of locations: In ...
*
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
: Ohio Bobcat Nano-Wagon,
Ohio University Ohio University is a Public university, public research university in Athens, Ohio. The first university chartered by an Act of Congress and the first to be chartered in Ohio, the university was chartered in 1787 by the Congress of the Confeder ...


Results

The race on the
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
surface was won by the Swiss team that crossed the finish line first after covering a distance of 133 nanometers. On the
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
surface, the vehicle of the Austrian-American team from the Universities of Rice and Graz set the first speed record with a peak speed of 95 nanometers per hour, and was ranked equally with the Swiss team which raced on the gold surface, given that motion of the same nanocar on silver surfaces are slower than on gold surfaces. This vehicle was remotely controlled from the Toulouse race hall on the University of Graz microscope. Specific properties of the chemical structure as well as a completely new manipulation technique (without time-consuming imaging steps) rendered this nanocar very fast. These properties even allowed it to complete a distance of more than 1000 nm after completion of the official race track. The American team from Ohio University turned back for no apparent reason after 20 nanometers, the German team broke 2 vehicles without being able to restart, and the Japanese team ended up giving up. The French team lost sight of its vehicle on its surface area, and was also obliged to abandon, comforting itself with the symbolic prize of "the most elegant car in the competition".


2022 Nanocar Race II


Teams

*
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
: "TOULOUSE–NARA" from
Toulouse III - Paul Sabatier University Paul Sabatier University (''Université Paul Sabatier'', UPS, also known as Toulouse III) is a French public university, in the Academy of Toulouse. It is one of the several successor universities of the University of Toulouse. Toulouse III was ...
. CEMES (
CNRS The French National Centre for Scientific Research (french: link=no, Centre national de la recherche scientifique, CNRS) is the French state research organisation and is the largest fundamental science agency in Europe. In 2016, it employed 31,637 ...
) and
Nara Institute of Science and Technology ) , city = Ikoma (Kansai Science City) , state = Nara , country = Japan , postgrad = 1,043 , administrative_staff= 374 , campus = Suburban,139,967 m², , mascot = None , free_label = , free = , endowment= US$-- billion(JP¥-- billio ...
. *
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...
: "Rice–Graz nanoprix" from
Rice University William Marsh Rice University (Rice University) is a Private university, private research university in Houston, Houston, Texas. It is on a 300-acre campus near the Houston Museum District and adjacent to the Texas Medical Center. Rice is ranke ...
and
University of Graz The University of Graz (german: link=no, Karl-Franzens-Universität Graz, ), located in Graz, Austria, is the largest and oldest university in Styria, as well as the second-largest and second-oldest university in Austria. History The unive ...
*
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
: "GAZE" from
Technische Universitat Dresden TU Dresden (for german: Technische Universität Dresden, abbreviated as TUD and often wrongly translated as "Dresden University of Technology") is a public research university, the largest institute of higher education in the city of Dresden, th ...
*
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
: "Ohio Bobcat Nanowagon" from
Ohio University Ohio University is a Public university, public research university in Athens, Ohio. The first university chartered by an Act of Congress and the first to be chartered in Ohio, the university was chartered in 1787 by the Congress of the Confeder ...
*
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...
: "StrasNanocar" from
University of Strasbourg The University of Strasbourg (french: Université de Strasbourg, Unistra) is a public research university located in Strasbourg, Alsace, France, with over 52,000 students and 3,300 researchers. The French university traces its history to the ea ...
and Strasbourg Institute of Material Physics and Chemistry (IPCMS) *
Spain , image_flag = Bandera de España.svg , image_coat = Escudo de España (mazonado).svg , national_motto = ''Plus ultra'' (Latin)(English: "Further Beyond") , national_anthem = (English: "Royal March") , i ...
: "SAN SEBASTIAN" from
Donostia International Physics Center The Donostia International Physics Center (DIPC) Foundation was established in 1999 in the framework of a collaboration agreement reached by the Education and Industry Departments of the Basque Government, the University of the Basque Country, t ...
and
University of Santiago de Compostela , established = , type = Public , budget = €228 million (2011) , rector = Prof. Dr. Antonio López Díaz , city = Santiago de Compostela , state = Galicia , country = Spain , undergrad = 23,835 , postgrad = 1,716 , doctoral = 2,697 ...
*
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
: "NIMS-MANA" from
National Institute for Materials Science is an Independent Administrative Institution and one of the largest scientific research centers in Japan. History The growth and development of today's scientific research center has passed through several phases in a number of locations: In ...
(
Tsukuba is a city located in Ibaraki Prefecture, Japan. , the city had an estimated population of 244,528 in 108,669 households and a population density of 862 persons per km². The percentage of the population aged over 65 was 20.3%. The total ar ...
) *
Spain , image_flag = Bandera de España.svg , image_coat = Escudo de España (mazonado).svg , national_motto = ''Plus ultra'' (Latin)(English: "Further Beyond") , national_anthem = (English: "Royal March") , i ...
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
: "NANOHISPA" from
IMDEA Nanoscience Institute IMDEA Nanoscience Institute is a private non-profit foundation within the IMDEA Institutes network, created in 2006-2007 as a result of collaboration agreement between the Community of Madrid and Spanish Ministry of Education and Science. The foun ...
( University of Madrid) and
Linköping University Linköping University (, LiU) is a public research university based in Linköping, Sweden. Originally established in 1969, it was granted full university status in 1975 and is one of Sweden's largest academic institutions. The university has fou ...


Results

NANOHISPA and NIMS-MANA were both ranked first, both making about 54 turns and covering 678 nm and 1054 nm, respectively. The first demonstrated a change of lane for overpassing while the latter crossed a trench and go back. StrasNanocar ranked third covering 476 nm and performing 28 turns.


Scientific interest

To make this kind of race possible, a considerable number of problems had to be solved beforehand, such as the choice of the track and its preparation, the improvement of monitoring and control devices, in particular the sensitivity of current measurements, the evaporation of a large number of very different molecules on the same surface and microscope validation Among the benefits, the CNRS cites the development molecular motors and Tech-Atoms, that will make possible in the future the preparation of quantum electronic circuits on the surface of an insulator, atom by atom, whose calculating parts will measure less than 1 nm.


References

{{reflist 2017 establishments in France Molecular machines Nanotechnology 2017 in science