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Moisture vapor transmission rate (MVTR), also water vapor transmission rate (WVTR), is a measure of the passage of water vapor through a substance. It is a measure of the permeability for
vapor barrier A vapor barrier (or vapour barrier) is any material used for damp proofing, typically a plastic or foil sheet, that resists diffusion of moisture through the wall, floor, ceiling, or roof assemblies of buildings and of packaging to prevent inter ...
s. There are many industries where moisture control is critical. Moisture sensitive
food Food is any substance consumed by an organism for nutritional support. Food is usually of plant, animal, or fungal origin, and contains essential nutrients, such as carbohydrates, fats, proteins, vitamins, or minerals. The substance is inge ...
s and
pharmaceutical A medication (also called medicament, medicine, pharmaceutical drug, medicinal drug or simply drug) is a drug used to diagnose, cure, treat, or prevent disease. Drug therapy (pharmacotherapy) is an important part of the medical field and re ...
s are put in
packaging Packaging is the science, art and technology of enclosing or protecting products for distribution, storage, sale, and use. Packaging also refers to the process of designing, evaluating, and producing packages. Packaging can be described as a co ...
with controlled MVTR to achieve the required
quality Quality may refer to: Concepts *Quality (business), the ''non-inferiority'' or ''superiority'' of something *Quality (philosophy), an attribute or a property *Quality (physics), in response theory *Energy quality, used in various science discipli ...
,
safety Safety is the state of being "safe", the condition of being protected from harm or other danger. Safety can also refer to risk management, the control of recognized hazards in order to achieve an acceptable level of risk. Meanings There are ...
, and
shelf life Shelf life is the length of time that a commodity may be stored without becoming unfit for use, consumption, or sale. In other words, it might refer to whether a commodity should no longer be on a pantry shelf (unfit for use), or no longer on a ...
. In
clothing Clothing (also known as clothes, apparel, and attire) are items worn on the body. Typically, clothing is made of fabrics or textiles, but over time it has included garments made from animal skin and other thin sheets of materials and natural ...
, MVTR as a measure of breathability has contributed to greater comfort for wearers of clothing for outdoor activity. The
building material Building material is material used for construction. Many naturally occurring substances, such as clay, rock (geology), rocks, sand, wood, and even twigs and leaves, have been used to construct buildings. Apart from naturally occurring materia ...
s industry also manages the moisture barrier properties in architectural components to ensure the correct moisture levels in the internal spaces of buildings.
Optoelectronic Optoelectronics (or optronics) is the study and application of electronic devices and systems that find, detect and control light, usually considered a sub-field of photonics. In this context, ''light'' often includes invisible forms of radiatio ...
devices based on organic material, generally named
OLED An organic light-emitting diode (OLED or organic LED), also known as organic electroluminescent (organic EL) diode, is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound that emits light i ...
s, need an encapsulation with low values of WVTR to guarantee the same performances over the lifetime of the device. MVTR generally decreases with increasing thickness of the film/barrier, and increases with increasing temperature.


Measurement

There are various techniques to measure MVTR, ranging from
gravimetric Gravimetry is the measurement of the strength of a gravitational field. Gravimetry may be used when either the magnitude of a gravitational field or the properties of matter responsible for its creation are of interest. Units of measurement G ...
techniques that measure the gain or loss of moisture by mass, to highly sophisticated instrumental techniques that in some designs can measure extremely low transmission rates. Special care has to be taken in measuring porous substances such as fabrics, as some techniques are not appropriate. For very low levels, many techniques do not have adequate resolution. Numerous
standard Standard may refer to: Symbols * Colours, standards and guidons, kinds of military signs * Standard (emblem), a type of a large symbol or emblem used for identification Norms, conventions or requirements * Standard (metrology), an object th ...
methods are described in
ISO ISO is the most common abbreviation for the International Organization for Standardization. ISO or Iso may also refer to: Business and finance * Iso (supermarket), a chain of Danish supermarkets incorporated into the SuperBest chain in 2007 * Iso ...
,
ASTM ASTM International, formerly known as American Society for Testing and Materials, is an international standards organization that develops and publishes voluntary consensus technical standards for a wide range of materials, products, systems, an ...
, BS, DIN etc.—these are quite often industry-specific. Instrument manufacturers are often able to provide test methods developed to fully exploit the specific design which they are selling. The search for the most appropriate instrument is a zealous task which is in itself part of the measurement., Water Vapor Permeation Testing of Ultra-Barriers: Limitations of Current Methods and Advancements Resulting in Increased Sensitivity, M. Stevens et Al. The conditions under which the measurement is made has a considerable influence on the result. Both the temperature and humidity gradients across the sample need to be measured, controlled and recorded with the result, and the thickness of the sample should be the same. An MVTR result without specifying these conditions is almost meaningless. Certainly no two results should be compared unless the conditions are known. For example, the effect of temperature on the permeability can be as high as 10% per °C, making it possible that MVTR results achieved at 23°C and 37°C can differ by a factor 4. The most common international unit for the MVTR is g/m2/day. In the USA, g/100in2/day is also in use, which is 0.064516 (approximately 1/15) of the value of g/m2/day units. Typical rates in aluminium foil laminates may be as low as 0.001 g/m2/day, whereas the rate in fabrics can measure up to several thousand g/m2/day. Often, barrier testing is conducted on a sheet of material. Calculations based on that can be useful when designing completed structures, clothing, and packages. Seams, creases, access points, and heat seals are critical to end-use performance. For example, the glass of a bottle may have an effective total barrier, but the
screw cap A screw cap or closure is a common type of closure for bottles, jars, and tubes. Usage A screw closure is a mechanical device which is screwed on and off of a "finish" on a container. Either continuous threads or lugs are used. It must be engi ...
closure and the closure liner might not. Performance
verification and validation Verification and validation (also abbreviated as V&V) are independent procedures that are used together for checking that a product, service, or system meets requirements and specifications and that it fulfills its intended purpose. These are ...
of complete containers, structures, or irregular objects is often recommended. For the special case of
OLED An organic light-emitting diode (OLED or organic LED), also known as organic electroluminescent (organic EL) diode, is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound that emits light i ...
s, where the levels of allowed permeation are in the 10−6 g/m2/day level
"Institute of Materials Research and Engineering (IMRE) MEDIA RELEASE, 29 April 2008, Singapore research produces world's best protection from moisture and oxygen"
,
Water Vapour Transmission Rate Measurements, 1 June 2011
the methods preferred exploit an oxidation of a metal upon the exposure to water
G. Nisato, Permeation Methods, Deliverable D5b FLEXled-phr-0209-009/Public Report, September 2002,
.
, Electrical Calcium Test for Measuring Barrier Permeability, National Renewable Energy Laboratory


See also

*
Carbon dioxide transmission rate Carbon dioxide transmission rate (COTR) is the measurement of the amount of carbon dioxide gas that passes through a substance over a given period. It is mostly carried out on non-porous materials, where the mode of transport is diffusion, but there ...
*
Moisture sorption isotherm At equilibrium, the relationship between water content and equilibrium relative humidity of a material can be displayed graphically by a curve, the so-called moisture sorption isotherm. For each humidity value, a sorption isotherm indicates the co ...
*
Oxygen transmission rate Oxygen transmission rate (OTR) is the measurement of the amount of oxygen gas that passes through a substance over a given period. It is mostly carried out on non-porous materials, where the mode of transport is diffusion, but there are a growing nu ...
*
Packaging Packaging is the science, art and technology of enclosing or protecting products for distribution, storage, sale, and use. Packaging also refers to the process of designing, evaluating, and producing packages. Packaging can be described as a co ...
*
Permeation In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrinsic ...
*
Shelf life Shelf life is the length of time that a commodity may be stored without becoming unfit for use, consumption, or sale. In other words, it might refer to whether a commodity should no longer be on a pantry shelf (unfit for use), or no longer on a ...
*
Vapor barrier A vapor barrier (or vapour barrier) is any material used for damp proofing, typically a plastic or foil sheet, that resists diffusion of moisture through the wall, floor, ceiling, or roof assemblies of buildings and of packaging to prevent inter ...


Further reading

* Bell, L.N., and Labuza, T.P. 2000. "Practical Aspects of Moisture Sorption Isotherm Measurement and Use". 2nd Edition AACC Egan Press, Egan, MN * Yam, K.L., "Encyclopedia of Packaging Technology", John Wiley & Sons, 2009, * Massey, L K, "Permeability Properties of Plastics and Elastomers", 2003, Andrew Publishing,


USP Regulatory Standards

For drugs sold in the United States, the U.S. Pharmacopeia (USP) defines standards for moisture transmission of drug packaging. * USP <671>


ASTM Standards

*ASTM D1434 - Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting *ASTM D3079 - Standard Test Method for Water Vapor Transmission of Flexible Heat-Sealed Packages for Dry Products *ASTM D4279 - Standard Test Methods for Water Vapor Transmission of Shipping Containers-Constant and Cycle Methods *ASTM D7709{{Cite web, url=http://www.astm.org/Standards/D7709.htm, title=ASTM D7709 - 12(2017) Standard Test Methods for Measuring Water Vapor Transmission Rate (WVTR) of Pharmaceutical Bottles and Blisters - Standard Test Methods for Measuring Water Vapor Transmission Rate (WVTR) of Pharmaceutical Bottles and Blisters *ASTM E96 - Standard Test Methods for Water Vapor Transmission of Materials *ASTM E398 - Standard Test Method for Water Vapor Transmission Rate of Sheet Materials Using Dynamic Relative Humidity Measurement *ASTM F1249 - Standard Test Method for Water Vapor Transmission Rate Through Plastic Film and Sheeting Using a Modulated Infrared Sensor * ASTM F2298- Standard Test Methods for Water Vapor Diffusion Resistance and Air Flow Resistance of Clothing Materials Using the Dynamic Moisture Permeation Cell


References

Psychrometrics Packaging Food technology Pharmaceutical industry Moisture protection Rates