Mogovidite
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Mogovidite is a very rare mineral of the
eudialyte group Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...
, with formula .Chukanov, N.V., Moiseyev, M.M., Rastsvetayeva, R.K., Rozenberg, K.A., and Zadov, A.E., 2005. Golyshevite (Na,Ca)10Ca9(Fe3+,Fe2+)2Zr3NbSi25O72(CO3)(OH)3·H2O, and Mogovidite, Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si25O72(CO3)(OH,H2O)4, new eudialyte-group minerals from calcium-rich agpaitic pegmatites of the Kovdor massif, Kola Peninsula. Zapiski Rossiyskogo Mineralogicheskogo Obshchestva 134(6), 36-47 (in Russian, with English abstract) The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies (at the M3 site) and
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
group. Another specific feature is the dominance of ferric iron - a feature shared with other eudialyte-group members, including
feklichevite Feklichevite is a rare mineral of the eudialyte group with the formula Na11Ca9(Fe3+,Fe2+)2Zr3NbSi(Si3O9)2(Si9O27)2.Pekov, I.V., Ekimenkova, I.A., Chukanov, N.V., Rastsvetaeva, R.K., Kononkova, N.N., Pekova, N.A., and Zadov, A.E., 2001. Feklichevit ...
,
fengchengite Fengchengite is a rare mineral of the eudialyte groupMindat, Fengchengite, http://www.mindat.org/min-42378.html with the formula .Shen, G., Xu, J., Yao, P., and Li, G., 2011. Fengchengite, IMA 2007-018a. CNMNC Newsletter No. 11, December 2011, 289 ...
,
golyshevite Golyshevite is a rare mineral of the eudialyte group,Mindat, Golyshevite, http://www.mindat.org/min-27418.html with the formula Na10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3•H2O. The original formula was extended to show both the presence of cyc ...
and
ikranite Ikranite is a member of the eudialyte group, named after the Shubinov Institute of Crystallography of the Russian Academy of Sciences. It is a cyclosilicate mineral that shows trigonal symmetry with the space group ''R''3''m'', and is often seen ...
. Similarly to
golyshevite Golyshevite is a rare mineral of the eudialyte group,Mindat, Golyshevite, http://www.mindat.org/min-27418.html with the formula Na10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3•H2O. The original formula was extended to show both the presence of cyc ...
, it is
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
-dominant, however on three (not two) sites: M(1), N(3) and N(4).Mindat, Mogovidite, http://www.mindat.org/min-27487.html It has a
molecular mass The molecular mass (''m'') is the mass of a given molecule: it is measured in daltons (Da or u). Different molecules of the same compound may have different molecular masses because they contain different isotopes of an element. The related quanti ...
of 3,066.24 gm.


Occurrence and association

As
golyshevite Golyshevite is a rare mineral of the eudialyte group,Mindat, Golyshevite, http://www.mindat.org/min-27418.html with the formula Na10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3•H2O. The original formula was extended to show both the presence of cyc ...
, mogovidite was discovered in
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
-bearing peralkaline
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
s of the Kovdor massif, Kola Peninsula, Russia. The mineral name is of geographical origin - mogovidite is named after Mt. Mogo-Vid located in the vicinity of type locality. Association of mogovidite: aegirine-
augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group. ...
,
andradite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
, humite,
nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites ...
, pectolite,
scolecite Scolecite is a tectosilicate mineral belonging to the zeolite group; it is a hydrated calcium silicate, Ca Al2 Si3 O10· 3H2O. Only minor amounts of sodium and traces of potassium substitute for calcium. There is an absence of barium, strontium, ...
,
titanite Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals in ...
,
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the r ...
.


Notes on chemistry

Chemical impurities in mogovidite include
chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
,
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
, and
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
, with trace
titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
,
cerium Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 o ...
, and
lanthanum Lanthanum is a chemical element with the symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lantha ...
.


References

Cyclosilicates Sodium minerals Calcium minerals Iron(II,III) minerals Zirconium minerals {{silicate-mineral-stub