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Luminescence is
spontaneous emission of
light
Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 tera ...
by a substance not resulting from heat; or "cold light".
It is thus a form of cold-body
radiation
In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes:
* ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
. It can be caused by
chemical reaction
A chemical reaction is a process that leads to the IUPAC nomenclature for organic transformations, chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the pos ...
s,
electrical energy, subatomic motions or
stress on a crystal. This distinguishes luminescence from
incandescence, which is light emitted by a substance as a result of heating. Historically,
radioactivity was thought of as a form of "radio-luminescence", although it is today considered to be separate since it involves more than electromagnetic radiation.
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The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as "luminising".
Types
The following are types of luminescence:
*
Chemiluminescence, the emission of light as a result of a
chemical reaction
A chemical reaction is a process that leads to the IUPAC nomenclature for organic transformations, chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the pos ...
**
Bioluminescence
Bioluminescence is the production and emission of light by living organisms. It is a form of chemiluminescence. Bioluminescence occurs widely in marine vertebrates and invertebrates, as well as in some fungi, microorganisms including some b ...
, a result of biochemical reactions in a living organism
**
Electrochemiluminescence
Electrochemiluminescence or electrogenerated chemiluminescence (ECL) is a kind of luminescence produced during electrochemical reactions in solutions. In electrogenerated chemiluminescence, electrochemically generated intermediates undergo a highl ...
, a result of an
electrochemical reaction
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outco ...
**
Lyoluminescence
Lyoluminescence refers to the emission of light while dissolving a solid into a liquid solvent. It is a form of chemiluminescence. The most common lyoluminescent effect is seen when solid samples which have been heavily irradiated by ionizing radia ...
, a result of dissolving a solid (usually heavily irradiated) in a liquid solvent
**
Candoluminescence Candoluminescence is the light given off by certain materials at elevated temperatures (usually when exposed to a flame) that has an intensity at some wavelengths which can, through chemical action in flames, be higher than the blackbody emission ex ...
, is light emitted by certain materials at elevated temperatures, which differs from the
blackbody
A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The name "black body" is given because it absorbs all colors of light. A black body ...
emission expected at the temperature in question.
*
Crystalloluminescence, produced during
crystallization
Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposi ...
*
Electroluminescence
Electroluminescence (EL) is an optical phenomenon, optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emissi ...
, a result of an electric current passed through a substance
**
Cathodoluminescence
Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example is ...
, a result of a luminescent material being struck by electrons
*
Mechanoluminescence Mechanoluminescence is light emission resulting from any mechanical action on a solid. It can be produced through ultrasound, or through other means.
* Fractoluminescence is caused by stress that results in the formation of fractures.
* Piezolum ...
, a result of a mechanical action on a solid
**
Triboluminescence
Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation a ...
, generated when bonds in a material are broken when that material is scratched, crushed, or rubbed
**
Fractoluminescence, generated when bonds in certain crystals are broken by fractures
**
Piezoluminescence Piezoluminescence is a form of luminescence created by pressure upon certain solids. This phenomenon is characterized by recombination processes involving electrons, holes and impurity ion centres. Some piezoelectric crystals give off a certain amo ...
, produced by the action of pressure on certain solids
**
Sonoluminescence
Sonoluminescence is the emission of light from imploding bubbles in a liquid when excited by sound.
History
The sonoluminescence effect was first discovered at the University of Cologne in 1934 as a result of work on sonar. Hermann Frenzel an ...
, a result of imploding bubbles in a liquid when excited by sound
*
Photoluminescence
Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photon ...
, a result of absorption of photons
**
Fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
, photoluminescence as a result of
singlet–singlet electronic
relaxation (typical
lifetime: nanoseconds)
**
Phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...
, photoluminescence either as a result of
triplet–triplet electronic relaxation or of
persistent luminescence
Commonly referred as phosphorescence, persistent luminescence is the emission of light by a phosphorescent material after an excitation by ultraviolet or visible light. Such materials would "glow in the dark".
Mechanism
The mechanism underlying ...
(typical lifetime: microseconds to hours)
*
Radioluminescence
Radioluminescence is the phenomenon by which light is produced in a material by bombardment with ionizing radiation such as alpha particles, beta particles, or gamma rays. Radioluminescence is used as a low level light source for night illumi ...
, a result of bombardment by ionizing radiation
*
Thermoluminescence
Thermoluminescence is a form of luminescence that is exhibited by certain crystalline materials, such as some minerals, when previously absorbed energy from electromagnetic radiation or other ionizing radiation is re-emitted as light upon he ...
, the re-emission of absorbed energy when a substance is heated
**Cryoluminescence, the emission of light when an object is cooled
(an example of this is
wulfenite
Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form ...
)
Applications
*
Light-emitting diode
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...
s (LEDs) emit light via electro-luminescence.
*
Phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or vi ...
s, materials that emit light when irradiated by higher-energy
electromagnetic radiation
In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic field, electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, inf ...
or
particle radiation
Particle radiation is the radiation of energy by means of fast-moving subatomic particles. Particle radiation is referred to as a particle beam if the particles are all moving in the same direction, similar to a light beam.
Due to the wave–par ...
*Laser, and lamp industry
*
Phosphor thermometry Phosphor thermometry is an optical method for surface temperature measurement. The method exploits luminescence emitted by phosphor material. Phosphors are fine white or pastel-colored inorganic powders which may be stimulated by any of a variety of ...
, measuring temperature using
phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...
*
Thermoluminescence dating
Thermoluminescence dating (TL) is the determination, by means of measuring the accumulated radiation dose, of the time elapsed since material containing crystalline minerals was either heated (lava, ceramics) or exposed to sunlight (sediments ...
*
Thermoluminescent dosimeter
A thermoluminescent dosimeter, or TLD, is a type of radiation dosimeter, consisting of a piece of a thermoluminescent crystalline material inside a radiolucent package.
When a thermoluminescent crystal is exposed to ionizing radiation, it abso ...
*Non-disruptive observation of processes within a cell.
Luminescence occurs in some
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s when they are exposed to low-powered sources of
ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
or
infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
electromagnetic radiation
In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic field, electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, inf ...
(for example,
portable UV lamps), at
atmospheric pressure
Atmospheric pressure, also known as barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1013.25 millibars, 7 ...
and atmospheric temperatures. This property of these minerals can be used during the process of mineral identification at rock
outcrop
An outcrop or rocky outcrop is a visible exposure of bedrock or ancient superficial deposits on the surface of the Earth.
Features
Outcrops do not cover the majority of the Earth's land surface because in most places the bedrock or superficial ...
s in the
field
Field may refer to:
Expanses of open ground
* Field (agriculture), an area of land used for agricultural purposes
* Airfield, an aerodrome that lacks the infrastructure of an airport
* Battlefield
* Lawn, an area of mowed grass
* Meadow, a grass ...
, or in the laboratory.
See also
*
List of light sources
This is a list of sources of light, the visible part of the electromagnetic spectrum. Light sources produce photons from another energy source, such as heat, chemical reactions, or conversion of mass or a different frequency of electromagnetic ener ...
*
Scientific American
''Scientific American'', informally abbreviated ''SciAm'' or sometimes ''SA'', is an American popular science magazine. Many famous scientists, including Albert Einstein and Nikola Tesla, have contributed articles to it. In print since 1845, it i ...
,
Luminous Paint (historical aspects), 10-Dec-1881, pp.368
References
External links
Fluorophores.org A database of luminescent dyes
{{Authority control
Light sources
1880s neologisms