Lithium soap is a

soap Soap is a salt of a fatty acid used in a variety of cleansing and lubricating products. In a domestic setting, soaps are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are use ...

consisting of a

lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ...

salt of a

fatty acid In chemistry, particularly in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated or unsaturated. Most naturally occurring fatty acids have an unbranched chain of an even number of carbon atoms, ...

. Sodium-based and potassium-based soaps are used as cleaning agents in domestic and industrial applications, whereas lithium soaps are used as components of lithium grease (white lithium). Lithium soaps are produced by

saponification Saponification is a process of converting esters into soaps and alcohols by the action of aqueous alkali (for example, aqueous sodium hydroxide solutions). Soaps are salts of fatty acids, which in turn are carboxylic acids with long carbon chains. ...

of triglycerides, using

lithium hydroxide Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...

or lithium carbonate as the saponification agent. Lithium soaps are used as

lubricant A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ...

components and form-release agents at relatively high temperatures. The main components of lithium soaps are

lithium stearate Lithium stearate is a chemical compound with the formula LiO2C(CH2)16CH3. It is formally classified as a soap (a salt of a fatty acid). Lithium stearate is a white soft solid, prepared by the reaction of lithium hydroxide and stearic acid. Lithiu ...

and

lithium 12-hydroxystearate Lithium 12-hydroxystearate (C18H35LiO3) is a chemical compound classified as a lithium soap. In chemistry, "soap" refers to salts of fatty acids. Lithium 12-hydroxystearate is a white solid. Lithium soaps are key component of many lubricating g ...

Lithium grease

Lubricating greases are commonly formulated as mixtures of an oil and a lithium soap thickener.Angelo Nora, Alfred Szczepanek, Gunther Koenen, "Metallic Soaps" in Ullmann’s Encyclopedia of Industrial Chemistry 2005 Wiley-VCH, Weinheim. Some formulations include PTFE or other substances, such as molybdenum disulfide. Lithium grease adheres particularly well to

metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...

, is non-

corrosive A corrosive substance is one that will damage or destroy other substances with which it comes into contact by means of a chemical reaction. Etymology The word ''corrosive'' is derived from the Latin verb ''corrodere'', which means ''to gnaw'', ...

, may be used under heavy loads, and exhibits good temperature tolerance. It has a

dropping point The dropping point of a lubricating grease is an indication of the heat resistance of the grease and is the temperature at which it passes from a semi-solid to a liquid state under specific test conditions. It is dependent on the type of thickener ...

of and resists moisture, so it is commonly used as lubricant in household products, such as electric garage doors, as well as in automotive applications, such as

constant-velocity joint Constant-velocity joints (also known as homokinetic or CV joints) are mechanical joints which allow a drive shaft to transmit power through a variable angle, at constant rotational speed, without an appreciable increase in friction or play. The ...

s. Lithium greases using a thickener formed by reacting a simple lithium soap with an acid are known as lithium complex greases and have higher dropping points as well as improvements to other properties.

References

{{DEFAULTSORT:Lithium-Based Grease Greases * Organolithium compounds

Lithium grease

See also

References