The Langer correction, named after the mathematician
Rudolf Ernest Langer
Rudolf Ernest Langer (8 March 1894 – 11 March 1968) was an American mathematician, known for the Langer correction and as a president of the Mathematical Association of America.
Career
Langer, the elder brother of William L. Langer, earned his P ...
, is a correction to the
WKB approximation for problems with radial symmetry.
Description
In 3D systems
When applying WKB approximation method to the radial
Schrödinger equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
,
:
,
where the
effective potential is given by
:
(
the
azimuthal quantum number
The azimuthal quantum number is a quantum number for an atomic orbital that determines its angular momentum operator, orbital angular momentum and describes the shape of the orbital. The wikt:azimuthal, azimuthal quantum number is the second of ...
related to the
angular momentum operator), the eigenenergies and the wave function behaviour obtained are different from the real solution.
In 1937,
Rudolf E. Langer suggested a correction
:
which is known as Langer correction or Langer replacement. This manipulation is equivalent to inserting a 1/4 constant factor whenever
appears. Heuristically, it is said that this factor arises because the range of the radial Schrödinger equation is restricted from 0 to infinity, as opposed to the entire real line. By such a changing of constant term in the effective potential, the results obtained by WKB approximation reproduces the exact spectrum for many potentials. That the Langer replacement is correct follows from the WKB calculation of the Coulomb eigenvalues with the replacement which reproduces the well known result.
In 2D systems
Note that for 2D systems, as the effective potential takes the form
:
,
so Langer correction goes:
:
.
This manipulation is also equivalent to insert a 1/4 constant factor whenever
appears.
Justification
An even more convincing calculation is the derivation of
Regge trajectories (and hence eigenvalues) of the radial Schrödinger equation with
Yukawa potential by both a perturbation method (with the old
factor) and independently the derivation by the WKB method (with Langer replacement)-- in both cases even to higher orders. For the perturbation calculation see
Müller-Kirsten book and for the WKB calculation Boukema.
See also
*
Einstein–Brillouin–Keller method
The Einstein–Brillouin–Keller method (EBK) is a semiclassical method (named after Albert Einstein, Léon Brillouin, and Joseph B. Keller) used to compute eigenvalues in quantum-mechanical systems. EBK quantization is an improvement from B ...
References
{{DEFAULTSORT:Langer Correction
Theoretical physics