Junction Voltage
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In
semiconductor physics A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
, the depletion region, also called depletion layer, depletion zone, junction region, space charge region or space charge layer, is an insulating region within a conductive, doped
semiconductor A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
material where the mobile
charge carrier In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is used ...
s have been
diffused Molecular diffusion, often simply called diffusion, is the thermal motion of all (liquid or gas) particles at temperatures above absolute zero. The rate of this movement is a function of temperature, viscosity of the fluid and the size (mass) of ...
away, or have been forced away by an
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field fo ...
. The only elements left in the depletion region are ionized donor or acceptor impurities. This region of uncovered positive and negative ions is called the depletion region due to the depletion of carriers in this region. The depletion region is so named because it is formed from a conducting region by removal of all free charge carriers, leaving none to carry a current. Understanding the depletion region is key to explaining modern
semiconductor A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
electronics The field of electronics is a branch of physics and electrical engineering that deals with the emission, behaviour and effects of electrons using electronic devices. Electronics uses active devices to control electron flow by amplification ...
:
diode A diode is a two-terminal electronic component that conducts current primarily in one direction (asymmetric conductance); it has low (ideally zero) resistance in one direction, and high (ideally infinite) resistance in the other. A diode ...
s,
bipolar junction transistor A bipolar junction transistor (BJT) is a type of transistor that uses both electrons and electron holes as charge carriers. In contrast, a unipolar transistor, such as a field-effect transistor, uses only one kind of charge carrier. A bipolar ...
s,
field-effect transistor The field-effect transistor (FET) is a type of transistor that uses an electric field to control the flow of current in a semiconductor. FETs (JFETs or MOSFETs) are devices with three terminals: ''source'', ''gate'', and ''drain''. FETs contro ...
s, and variable capacitance diodes all rely on depletion region phenomena.


Formation in a p–n junction

A depletion region forms instantaneously across a
p–n junction A p–n junction is a boundary or interface between two types of semiconductor materials, p-type and n-type, inside a single crystal of semiconductor. The "p" (positive) side contains an excess of holes, while the "n" (negative) side contains ...
. It is most easily described when the junction is in thermal equilibrium or in a
steady state In systems theory, a system or a Process theory, process is in a steady state if the variables (called state variables) which define the behavior of the system or the process are unchanging in time. In continuous time, this means that for those p ...
: in both of these cases the properties of the system do not vary in time; they have been called
dynamic equilibrium In chemistry, a dynamic equilibrium exists once a reversible reaction occurs. Substances transition between the reactants and products at equal rates, meaning there is no net change. Reactants and products are formed at such a rate that the conc ...
.
Electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
s and
hole A hole is an opening in or through a particular medium, usually a solid body. Holes occur through natural and artificial processes, and may be useful for various purposes, or may represent a problem needing to be addressed in many fields of en ...
s diffuse into regions with lower concentrations of them, much as ink diffuses into water until it is uniformly distributed. By definition, the
N-type semiconductor An extrinsic semiconductor is one that has been '' doped''; during manufacture of the semiconductor crystal a trace element or chemical called a doping agent has been incorporated chemically into the crystal, for the purpose of giving it different ...
has an excess of free electrons (in the
conduction band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in w ...
) compared to the
P-type semiconductor An extrinsic semiconductor is one that has been '' doped''; during manufacture of the semiconductor crystal a trace element or chemical called a doping agent has been incorporated chemically into the crystal, for the purpose of giving it different ...
, and the P-type has an excess of holes (in the
valence band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in w ...
) compared to the N-type. Therefore, when N-doped and P-doped semiconductors are placed together to form a junction, free electrons in the N-side conduction band migrate (diffuse) into the P-side conduction band, and holes in the P-side valence band migrate into the N-side valence band. Following transfer, the diffused electrons come into contact with holes and are eliminated by recombination in the P-side. Likewise, the diffused holes are recombined with free electrons so eliminated in the N-side. The net result is that the diffused electrons and holes are gone. In a N-side region near to the junction interface, free electrons in the conduction band are gone due to (1) the diffusion of electrons to the P-side and (2) recombination of electrons to holes that are diffused from the P-side. Holes in a P-side region near to the interface are also gone by a similar reason. As a result, majority charge carriers (free electrons for the N-type semiconductor, and holes for the P-type semiconductor) are depleted in the region around the junction interface, so this region is called the depletion region or depletion zone. Due to the majority charge carrier diffusion described above, the depletion region is charged; the N-side of it is positively charged and the P-side of it is negatively charged. This creates an
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field fo ...
that provides a force opposing the charge diffusion. When the electric field is sufficiently strong to cease further diffusion of holes and electrons, the depletion region reaches the equilibrium. Integrating the electric field across the depletion region determines what is called the built-in voltage (also called the junction voltage or barrier voltage or contact potential). Physically speaking, charge transfer in semiconductor devices is from (1) the charge carrier drift by the electric field and (2) the charge carrier diffusion due to the spatially varying carrier concentration. In the P-side of the depletion region, where holes drift by the electric field with the electrical conductivity ''σ'' and diffuse with the diffusion constant ''D'', the net current density is given by =\sigma -e D \nabla p , where is the electric field, ''e'' is the
elementary charge The elementary charge, usually denoted by is the electric charge carried by a single proton or, equivalently, the magnitude of the negative electric charge carried by a single electron, which has charge −1 . This elementary charge is a fundame ...
(1.6×10−19 coulomb), and ''p'' is the hole density (number per unit volume). The electric field makes holes drift along the field direction, and for diffusion holes move in the direction of decreasing concentration, so for holes a negative current results for a positive density gradient. (If the carriers are electrons, the hole density ''p'' is replaced by the
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
density ''n'' with negative sign; in some cases, both electrons and holes must be included.) When the two current components balance, as in the p–n junction depletion region at
dynamic equilibrium In chemistry, a dynamic equilibrium exists once a reversible reaction occurs. Substances transition between the reactants and products at equal rates, meaning there is no net change. Reactants and products are formed at such a rate that the conc ...
, the current is zero due to the Einstein relation, which relates ''D'' to ''σ''.


Forward bias

Forward bias (applying a positive voltage to the P-side with respect to the N-side) narrows the depletion region and lowers the barrier to carrier injection (shown in the figure to the right). In more detail, majority carriers get some energy from the bias field, enabling them to go into the region and neutralize opposite charges. The more bias the more neutralization (or screening of ions in the region) occurs. The carriers can be recombined to the ions but thermal energy immediately makes recombined carriers transition back as Fermi energy is in proximity. When bias is strong enough that the depletion region becomes very thin, the diffusion component of the current (through the junction interface) greatly increases and the drift component decreases. In this case, the net current flows from the P-side to the N-side. The carrier density is large (it varies exponentially with the applied bias voltage), making the junction conductive and allowing a large forward current. The mathematical description of the current is provided by the
Shockley diode equation The ''Shockley diode equation'' or the ''diode law'', named after transistor co-inventor William Shockley of Bell Telephone Laboratories, gives the I–V (current-voltage) characteristic of an idealized diode in either forward or reverse bias (appl ...
. The low current conducted under reverse bias and the large current under forward bias is an example of
rectification Rectification has the following technical meanings: Mathematics * Rectification (geometry), truncating a polytope by marking the midpoints of all its edges, and cutting off its vertices at those points * Rectifiable curve, in mathematics * Recti ...
.


Reverse bias

Under
reverse bias Reverse or reversing may refer to: Arts and media * ''Reverse'' (Eldritch album), 2001 * ''Reverse'' (2009 film), a Polish comedy-drama film * ''Reverse'' (2019 film), an Iranian crime-drama film * ''Reverse'' (Morandi album), 2005 * ''Reverse'' ...
(applying a negative voltage to the P-side with respect to the N-side), the potential drop (i.e., voltage) across the depletion region increases. Essentially, majority carriers are pushed away from the junction, leaving behind more charged ions. Thus the depletion region is widened and its field becomes stronger, which increases the drift component of current (through the junction interface) and decreases the diffusion component. In this case, the net current flows from the N-side to the P-side. The carrier density (mostly, minority carriers) is small and only a very small ''reverse saturation current'' flows.


Determining the depletion layer width

From a full depletion analysis as shown in figure 2, the charge would be approximated with suddenly drop at its limit points which in reality is gradually and explained by
Poisson's equation Poisson's equation is an elliptic partial differential equation of broad utility in theoretical physics. For example, the solution to Poisson's equation is the potential field caused by a given electric charge or mass density distribution; with th ...
. The amount of
flux density Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ph ...
would then be \begin \frac &=qN_d \\ \frac &=-qN_a \\ \end where Q_n and Q_p are the amount of negative and positive charge respectively, x_n and x_p are the distance for negative and positive charge respectively with zero at the center, N_a and N_d are the amount of
acceptor Acceptor may refer to: * Acceptor (accounting), the addressee of a bill of exchange * In the Indian Contract Act of 1872, the acceptor is the person to whom a proposal is made, and who has communicated his or her acceptance of the said proposal ...
and donor atoms respectively and q is the
electron charge The elementary charge, usually denoted by is the electric charge carried by a single proton or, equivalently, the magnitude of the negative electric charge carried by a single electron, which has charge −1 . This elementary charge is a fundame ...
. Taking the integral of the flux density D with respect to distance dx to determine electric field E (i.e.
Gauss's law In physics and electromagnetism, Gauss's law, also known as Gauss's flux theorem, (or sometimes simply called Gauss's theorem) is a law relating the distribution of electric charge to the resulting electric field. In its integral form, it sta ...
) creates the second graph as shown in figure 2: E=\frac where \epsilon_s is the
permittivity In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter ''ε'' ( epsilon), is a measure of the electric polarizability of a dielectric. A material with high permittivity polarizes more in ...
of the substance. Integrating electric field with respect to distance determines the electric potential V . This would also equal to the built in voltage \Delta V as shown in Figure 2. V=\int E dx=\Delta V The final equation would then be arranged so that the function of depletion layer width x_n would be dependent on the electric potential V . In summary, x_n and x_p are the negative and positive depletion layer width respectively with respect to the center, N_a and N_d are the amount of
acceptor Acceptor may refer to: * Acceptor (accounting), the addressee of a bill of exchange * In the Indian Contract Act of 1872, the acceptor is the person to whom a proposal is made, and who has communicated his or her acceptance of the said proposal ...
and donor atoms respectively, q is the
electron charge The elementary charge, usually denoted by is the electric charge carried by a single proton or, equivalently, the magnitude of the negative electric charge carried by a single electron, which has charge −1 . This elementary charge is a fundame ...
and \Delta V is the built-in voltage, which is usually the independent variable.


Formation in an MOS capacitor

Another example of a depletion region occurs in the
MOS capacitor The metal–oxide–semiconductor field-effect transistor (MOSFET, MOS-FET, or MOS FET) is a type of field-effect transistor (FET), most commonly fabricated by the controlled oxidation of silicon. It has an insulated gate, the voltage of which d ...
. It is shown in the figure to the right, for a P-type substrate. Supposing that the semiconductor initially is charge neutral, with the charge due to holes exactly balanced by the negative charge due to acceptor doping impurities. If a positive voltage now is applied to the gate, which is done by introducing positive charge ''Q'' to the gate, then some positively charged holes in the semiconductor nearest the gate are repelled by the positive charge on the gate, and exit the device through the bottom contact. They leave behind a ''depleted'' region that is insulating because no mobile holes remain; only the immobile, negatively charged acceptor impurities. The greater the positive charge placed on the gate, the more positive the applied gate voltage, and the more holes that leave the semiconductor surface, enlarging the depletion region. (In this device there is a limit to how wide the depletion width may become. It is set by the onset of an inversion layer of carriers in a thin layer, or
channel Channel, channels, channeling, etc., may refer to: Geography * Channel (geography), in physical geography, a landform consisting of the outline (banks) of the path of a narrow body of water. Australia * Channel Country, region of outback Austral ...
, near the surface. The above discussion applies for positive voltages low enough that an inversion layer does not form.) If the gate material is
polysilicon Polycrystalline silicon, or multicrystalline silicon, also called polysilicon, poly-Si, or mc-Si, is a high purity, polycrystalline form of silicon, used as a raw material by the solar photovoltaic and electronics industry. Polysilicon is produce ...
of opposite type to the bulk semiconductor, then a spontaneous depletion region forms if the gate is electrically shorted to the substrate, in much the same manner as described for the p–n junction above. For more on this, see polysilicon depletion effect. The principle of charge neutrality says the sum of positive charges must equal the sum of negative charges: :::n + N_A=p + N_D\,, where ''n'' and ''p'' are the number of free electrons and holes, and N_D and N_A are the number of ionized donors and acceptors "per unit of length", respectively. In this way, both N_D and N_A can be viewed as doping spatial densities. If we assume full ionization and that n, p \ll N_D, N_A , then: :::qN_Aw_P \approx qN_Dw_N \,. where w_P and w_N are depletion widths in the ''p'' and ''n'' semiconductor, respectively. This condition ensures that the net negative acceptor charge exactly balances the net positive donor charge. The total depletion width in this case is the sum w =w_N +w_P. A full derivation for the depletion width is presented in reference. This derivation is based on solving the Poisson equation in one dimension – the dimension normal to the metallurgical junction. The electric field is zero outside of the depletion width (seen in above figure) and therefore Gauss's law implies that the charge density in each region balance – as shown by the first equation in this sub-section. Treating each region separately and substituting the charge density for each region into the Poisson equation eventually leads to a result for the depletion width. This result for the depletion width is: w \approx \left \frac \left(\frac\right) \left(V_ - V\right)\right\frac where \epsilon_r is the relative dielectric permittivity of the semiconductor, V_ is the built-in voltage, and V is the applied bias. The depletion region is not symmetrically split between the n and p regions - it will tend towards the lightly doped side. A more complete analysis would take into account that there are still ''some'' carriers near the edges of the depletion region. This leads to an additional -2kT/q term in the last set of parentheses above.


Depletion width in MOS capacitor

As in p–n junctions, the governing principle here is charge neutrality. Let us assume a P-type substrate. If positive charge ''Q'' is placed on gate with area ''A'', then holes are depleted to a depth ''w'' exposing sufficient negative acceptors to exactly balance the gate charge. Supposing the dopant density to be N_A acceptors per unit volume, then charge neutrality requires the depletion width ''w'' to satisfy the relationship: :::Q/A=qN_Aw \, If the depletion width becomes wide enough, then electrons appear in a very thin layer at the semiconductor-oxide interface, called an inversion layer because they are oppositely charged to the holes that prevail in a P-type material. When an inversion layer forms, the depletion width ceases to expand with increase in gate charge ''Q''. In this case, neutrality is achieved by attracting more electrons into the inversion layer. In the
MOSFET The metal–oxide–semiconductor field-effect transistor (MOSFET, MOS-FET, or MOS FET) is a type of field-effect transistor (FET), most commonly fabricated by the controlled oxidation of silicon. It has an insulated gate, the voltage of which d ...
, this inversion layer is referred to as the
channel Channel, channels, channeling, etc., may refer to: Geography * Channel (geography), in physical geography, a landform consisting of the outline (banks) of the path of a narrow body of water. Australia * Channel Country, region of outback Austral ...
.


Electric field in depletion layer and band bending

Associated with the depletion layer is an effect known as
band bending In solid-state physics, band bending refers to the process in which the electronic band structure in a material curves up or down near a junction or interface. It does not involve any physical (spatial) bending. When the electrochemical potential ...
. This effect occurs because the electric field in the depletion layer varies linearly in space from its (maximum) value E_m at the gate to zero at the edge of the depletion width: :::E_m

qN_A, \,
where \epsilon_0 = 8.854×10−12 F/m, ''F'' is the
farad The farad (symbol: F) is the unit of electrical capacitance, the ability of a body to store an electrical charge, in the International System of Units (SI). It is named after the English physicist Michael Faraday (1791–1867). In SI base unit ...
and ''m'' is the meter. This linearly-varying electric field leads to an electrical potential that varies quadratically in space. The energy levels, or energy bands, ''bend'' in response to this potential.


See also

* Capacitance voltage profiling * Metal–oxide–semiconductor structure * Semiconductor diodes


References

{{DEFAULTSORT:Depletion Region Semiconductor structures MOSFETs