James Hargreaves (chemist)
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James Hargreaves (May 1834 – 4 April 1915) was a British
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...
and an
inventor An invention is a unique or novel device, method, composition, idea or process. An invention may be an improvement upon a machine, product, or process for increasing efficiency or lowering cost. It may also be an entirely new concept. If an ...
. He was born at Hoarstones in
Fence, Lancashire Fence is a village in the civil parish of Old Laund Booth, Pendle, Lancashire, England, close to the towns of Nelson and Burnley. It lies alongside the A6068 road, known locally as the Padiham bypass. The parish (which includes the adjoining vil ...
, the eldest child of James Hargreaves, a schoolmaster at
Slaithwaite Slaithwaite , locally ''Slawit'' (Old Norse: Timber-fell clearing), is a village within the Metropolitan Borough of Kirklees, in West Yorkshire, England. Historically part of the West Riding of Yorkshire, it lies in the Colne Valley, lying acr ...
near Marsden. His father moved to
Sabden Sabden is a village and civil parish in the Ribble Valley, Lancashire, England. Sabden is located south of Pendle Hill, in a valley about three miles north west of Padiham. The parish covers , of which is occupied by the village. It lies in the ...
but as he found his salary to be insufficient the father became a
druggist A pharmacist, also known as a chemist (Commonwealth English) or a druggist (North American and, archaically, Commonwealth English), is a healthcare professional who prepares, controls and distributes medicines and provides advice and instructi ...
in 1844, later moving to Preston.


Inventions

Hargreaves worked with his father for a time and began to experiment in
chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
. One of his interests was to attempt to recover
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
from
alkali In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
waste. At the same time
William Gossage William Gossage (12 May 1799 – 9 April 1877) was a chemical manufacturer who established a soap making business in Widnes, Lancashire, England. Early life William Gossage was born in the village of Burgh-le-Marsh, Lincolnshire to Thomas and E ...
was working at the same project at his factory in
Widnes Widnes ( ) is an Industrial city, industrial town in the Borough of Halton, Cheshire, England, which at the 2011 United Kingdom census, 2011 census had a population of 61,464. Historic counties of England, Historically in Lancashire, it is on t ...
. In 1859, at the age of 25, Hargreaves moved to Widnes and worked for Gossage. Here he made his first two important discoveries; the recovery of
chromates Chromate salts contain the chromate anion, . Dichromate salts contain the dichromate anion, . They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate i ...
which were used in the
bleach Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to ...
ing of fats and oils, and a method of bleaching brown soap. He was also involved with developing the process for making the commercially successful blue mottled soap. Around 1865 he left Gossage and worked with two other soap making firms, Hazlehurst & Sons in
Runcorn Runcorn is an industrial town and cargo port in the Borough of Halton in Cheshire, England. Its population in 2011 was 61,789. The town is in the southeast of the Liverpool City Region, with Liverpool to the northwest across the River Mersey. ...
and then Stephen Cox and Company in
Liverpool Liverpool is a city and metropolitan borough in Merseyside, England. With a population of in 2019, it is the 10th largest English district by population and its metropolitan area is the fifth largest in the United Kingdom, with a popul ...
. In 1871 he set up a business with his brother, John, who had studied chemistry in Preston, as consulting chemists. James then embarked on further experiments. He suggested using
sodium nitrate Sodium nitrate is the chemical compound with the formula . This alkali metal nitrate salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile) to distinguish it from ordinary saltpeter, potassium nitrate. T ...
instead of air in the
Bessemer process The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is steelmaking, removal of impurities from the iron by ox ...
for manufacturing
steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
but this proved to be too expensive. He developed a process for recovering
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phospho ...
s from
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...
slag Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
. In association with Thomas Robinson, he invented a process for producing saltcake (
sodium sulfate Sodium sulfate (also known as sodium sulphate or sulfate of soda) is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are white solids that are highly soluble in water. With an annual production of 6 milli ...
) from salt without the use of
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...
. The Atlas Chemical Company was established in Widnes to use this Hargreaves-Robinson process. It was cheaper to produce alkali by this process than by the
Leblanc process The Leblanc process (pronounced leh-blaank) was an early industrial process for making ''soda ash'' (sodium carbonate) used throughout the 19th century, named after its inventor, Nicolas Leblanc. It involved two stages: making sodium sulfate from ...
. The Atlas Chemical Company was absorbed by the
United Alkali Company United Alkali Company Limited was a British chemical company formed in 1890, employing the Leblanc process to produce soda ash for the glass, textile, soap, and paper industries. It became one of the top four British chemical companies merged in ...
in 1890 but the process continued to operate until 1918. With Thomas Bird, Hargreaves developed a process for the
electrolysis In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from n ...
of
brine Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for br ...
using
asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...
diaphragms. In 1893 the General Electric Parent Company was established to develop this process. Bird died in 1895 and 1899 the General Electrolytic Alkali Company was set up at
Middlewich Middlewich is a town in the unitary authority of Cheshire East and the ceremonial county of Cheshire, England, east of Chester, east of Winsford, southeast of Northwich and northwest of Sandbach. The population at the 2011 Census was 13,595. ...
, with Hargreaves as a director and his son Luke as general manager. Hargreaves cells were also built in France, Norway, and the USA. The process was in direct competition with the electrolysis of brine in
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
cells in the Castner-Kellner process but Hargreaves considered that mercury was too
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
a substance for workers to be exposed to. Hargreaves produced other ideas and inventions. He advocated the use of
chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
rather than
bleaching powder Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to ...
to disinfect
sewage Sewage (or domestic sewage, domestic wastewater, municipal wastewater) is a type of wastewater that is produced by a community of people. It is typically transported through a sewer system. Sewage consists of wastewater discharged from residenc ...
. He developed a "thermo-motor" which anticipated the
diesel engine The diesel engine, named after Rudolf Diesel, is an internal combustion engine in which ignition of the fuel is caused by the elevated temperature of the air in the cylinder due to mechanical compression; thus, the diesel engine is a so-call ...
and at the time of his death he was developing a new type of cattle food. He also wrote articles for scientific encyclopaedias, gave lectures and travelled widely, becoming a good linguist. He died at his home in Widnes in 1915.Hardie, pp. 132–133


References


Notes


Bibliography

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See also

Coley, N.G. 'Hargreaves, James (1834-1915)', rev., ''
Oxford Dictionary of National Biography The ''Dictionary of National Biography'' (''DNB'') is a standard work of reference on notable figures from British history, published since 1885. The updated ''Oxford Dictionary of National Biography'' (''ODNB'') was published on 23 September ...
'', Oxford University Press, 200

{{DEFAULTSORT:Hargreaves, James (chemist) 1834 births 1915 deaths British chemists English inventors People from Widnes People from Fence, Lancashire 19th-century English businesspeople