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Ink is a
gel A gel is a semi-solid that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute cross-linked system, which exhibits no flow when in the steady-state, although the liquid phase may still di ...
,
sol Sol or SOL may refer to: Astronomy * The Sun Currency * SOL Project, a currency project in France * French sol, or sou * Argentine sol * Bolivian sol, the currency of Bolivia from 1827 to 1864 * Peruvian sol, introduced in 1991 * Peruvian sol ( ...
, or
solution Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Soluti ...
that contains at least one colorant, such as a
dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...
or pigment, and is used to color a surface to produce an
image An image is a visual representation of something. It can be two-dimensional, three-dimensional, or somehow otherwise feed into the visual system to convey information. An image can be an artifact, such as a photograph or other two-dimensiona ...
, text, or design. Ink is used for
drawing Drawing is a form of visual art in which an artist uses instruments to mark paper or other two-dimensional surface. Drawing instruments include graphite pencils, pen and ink, various kinds of paints, inked brushes, colored pencils, crayons, ...
or writing with a pen,
brush A brush is a common tool with bristles, wire or other filaments. It generally consists of a handle or block to which filaments are affixed in either a parallel or perpendicular orientation, depending on the way the brush is to be gripped durin ...
, reed pen, or quill. Thicker inks, in paste form, are used extensively in letterpress and lithographic printing. Ink can be a complex medium, composed of solvents, pigments,
dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...
s, resins,
lubricant A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ...
s,
solubilizer Micellar solubilization (solubilization) is the process of incorporating the solubilizate (the component that undergoes solublization) into or onto micelles. Solublization may occur in a system consisting of a solvent, an association colloid (a co ...
s,
surfactant Surfactants are chemical compounds that decrease the surface tension between two liquids, between a gas and a liquid, or interfacial tension between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming ...
s,
particulate matter Particulates – also known as atmospheric aerosol particles, atmospheric particulate matter, particulate matter (PM) or suspended particulate matter (SPM) – are microscopic particles of solid or liquid matter suspended in the air. The ter ...
, fluorescents, and other materials. The components of inks serve many purposes; the ink's carrier, colorants, and other additives affect the flow and thickness of the ink and its dry appearance. In 2011, worldwide consumption of printing inks generated revenues of more than 20 billion US dollars. While demand by traditional print media (including newspapers) is shrinking; more and more printing inks are consumed for packaging.


History

Many ancient cultures around the world have independently discovered and formulated inks for the purposes of writing and drawing. The knowledge of the inks, their recipes and the techniques for their production comes from archaeological analysis or from written text itself. The earliest inks from all civilizations are believed to have been made with '' lampblack'', a kind of soot, as this would have been easily collected as a by-product of fire. Ink was used in Ancient Egypt for writing and drawing on papyrus from at least the 26th century BC. Egyptian red and black inks included iron and ocher as a pigment, in addition to phosphate, sulfate, chloride, and carboxylate ions; meanwhile, lead was used as a drier. Chinese inks may go back as far as four millennia, to the Chinese Neolithic Period. These used plants, animal, and mineral inks based on such materials as graphite that were ground with water and applied with ink brushes. Direct evidence for the earliest Chinese inks, similar to modern inksticks, is around 256 BC in the end of the Warring States period and produced from soot and animal glue. The best inks for drawing or painting on paper or silk are produced from the resin of the pine tree. They must be between 50 and 100 years old. The Chinese inkstick is produced with a fish glue, whereas Japanese glue (膠 ''nikawa'') is from cow or stag. India ink was invented in China,Smith, Joseph A. (1992). ''The Pen and Ink Book: Materials and Techniques for Today's Artist''.p. 23. New York: Watson-Guptill Publications. . though materials were often traded from India, hence the name.Gottsegen, Mark D. (2006). ''The Painter's Handbook: A Complete Reference''.Page 30, New York: Watson-Guptill Publications. . The traditional Chinese method of making the ink was to grind a mixture of hide glue, carbon black, lampblack, and bone black pigment with a
pestle and mortar Mortar and pestle is a set of two simple tools used from the Stone Age to the present day to prepare ingredients or substances by crushing and grinding them into a fine paste or powder in the kitchen, laboratory, and pharmacy. The ''mortar'' () ...
, then pour it into a ceramic dish to dry. To use the dry mixture, a wet brush would be applied until it reliquified. The manufacture of India ink was well-established by the Cao Wei dynasty (220–265 AD). Indian documents written in
Kharosthi The Kharoṣṭhī script, also spelled Kharoshthi (Kharosthi: ), was an ancient Indo-Iranian script used by various Aryan peoples in north-western regions of the Indian subcontinent, more precisely around present-day northern Pakistan and ...
with ink have been unearthed in Chinese Turkestan. The practice of writing with ink and a sharp pointed needle was common in early South India. Several Buddhist and Jain sutras in India were compiled in ink. In ancient Rome,
atramentum Atramentum or atrament, generally means a very black, usually liquid, substance. For example, an octopus may emit a puff of atrament (see cephalopod ink). In ancient Rome, the term ''atramentum'' signified any black colouring substance used for a ...
was used; in an article for the '' Christian Science Monitor'', Sharon J. Huntington describes these other historical inks:
About 1,600 years ago, a popular ink recipe was created. The recipe was used for centuries. Iron salts, such as ferrous sulfate (made by treating iron with sulfuric acid), were mixed with tannin from
gall Galls (from the Latin , 'oak-apple') or ''cecidia'' (from the Greek , anything gushing out) are a kind of swelling growth on the external tissues of plants, fungi, or animals. Plant galls are abnormal outgrowths of plant tissues, similar to be ...
nuts (they grow on trees) and a thickener. When first put to paper, this ink is bluish-black. Over time it fades to a dull brown.
Scribes in medieval Europe (about AD 800 to 1500) wrote principally on parchment or vellum. One 12th century ink recipe called for hawthorn branches to be cut in the spring and left to dry. Then the bark was pounded from the branches and soaked in water for eight days. The water was boiled until it thickened and turned black. Wine was added during boiling. The ink was poured into special bags and hung in the sun. Once dried, the mixture was mixed with wine and iron salt over a fire to make the final ink.
The reservoir pen, which may have been the first fountain pen, dates back to 953, when Ma'ād al-Mu'izz, the caliph of Egypt, demanded a pen that would not stain his hands or clothes, and was provided with a pen that held ink in a reservoir. In the 15th century, a new type of ink had to be developed in Europe for the printing press by
Johannes Gutenberg Johannes Gensfleisch zur Laden zum Gutenberg (; – 3 February 1468) was a German inventor and Artisan, craftsman who introduced letterpress printing to Europe with his movable type, movable-type printing press. Though not the first of its ki ...
. According to Martyn Lyons in his book ''Books: A Living History'', Gutenberg's dye was indelible, oil-based, and made from the soot of lamps (lamp-black) mixed with
varnish Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...
and egg white. Two types of ink were prevalent at the time: the Greek and Roman writing ink (soot, glue, and water) and the 12th century variety composed of ferrous sulfate, gall, gum, and water. Neither of these handwriting inks could adhere to printing surfaces without creating blurs. Eventually an oily,
varnish Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...
-like ink made of soot, turpentine, and walnut oil was created specifically for the printing press.


Types

Ink formulas vary, but commonly involve two components: * Colorants * Vehicles (binders) Inks generally fall into four classes: * Aqueous * Liquid * Paste * Powder


Colorants


Pigments

Pigment inks are used more frequently than dyes because they are more color-fast, but they are also more expensive, less consistent in color, and have less of a color range than dyes. Pigments are solid, opaque particles suspended in ink to provide color. Pigment molecules typically link together in crystalline structures that are 0.1–2
µm The micrometre ( international spelling as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American spelling), also commonly known as a micron, is a unit of length in the International System of Unit ...
in size and comprise 5–30 percent of the ink volume. Qualities such as hue, saturation, and
lightness Lightness is a visual perception of the luminance (L) of an object. It is often judged relative to a similarly lit object. In colorimetry and color appearance models, lightness is a prediction of how an illuminated color will appear to a stan ...
vary depending on the source and type of pigment.


Dyes

Dye-based inks are generally much stronger than pigment-based inks and can produce much more color of a given density per unit of mass. However, because dyes are dissolved in the liquid phase, they have a tendency to soak into paper, potentially allowing the ink to bleed at the edges of an image. To circumvent this problem, dye-based inks are made with solvents that dry rapidly or are used with quick-drying methods of printing, such as blowing hot air on the fresh print. Other methods include harder paper
sizing Sizing or size is a substance that is applied to, or incorporated into, other materials—especially papers and textiles—to act as a protective filler or glaze. Sizing is used in papermaking and textile manufacturing to change the absorption ...
and more specialized paper coatings. The latter is particularly suited to inks used in non-industrial settings (which must conform to tighter toxicity and emission controls), such as inkjet printer inks. Another technique involves coating the paper with a charged coating. If the dye has the opposite charge, it is attracted to and retained by this coating, while the solvent soaks into the paper. Cellulose, the wood-derived material most paper is made of, is naturally charged, and so a compound that complexes with both the dye and the paper's surface aids retention at the surface. Such a compound is commonly used in ink-jet printing inks. An additional advantage of dye-based ink systems is that the dye molecules can interact with other ink ingredients, potentially allowing greater benefit as compared to pigmented inks from
optical brightener Optical brighteners, optical brightening agents (OBAs), fluorescent brightening agents (FBAs), or fluorescent whitening agents (FWAs), are chemical compounds that absorb light in the ultraviolet and violet region (usually 340-370 nm) of the ...
s and color-enhancing agents designed to increase the intensity and appearance of dyes. Dye-based inks can be used for anti-counterfeit purposes and can be found in some gel inks, fountain pen inks, and inks used for paper currency. These inks react with cellulose to bring about a permanent color change.


Health and environmental aspects

There is a misconception that ink is non-toxic even if swallowed. Once ingested, ink can be hazardous to one's health. Certain inks, such as those used in digital printers, and even those found in a common pen can be harmful. Though ink does not easily cause death, repeated skin contact or ingestion can cause effects such as severe headaches, skin irritation, or nervous system damage. These effects can be caused by solvents, or by pigment ingredients such as ''p''-Anisidine, which helps create some inks' color and shine. Three main environmental issues with ink are: *
Heavy metals upright=1.2, Crystals of osmium, a heavy metal nearly twice as dense as lead">lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead Heavy metals are generally defined as ...
* Non-renewable oils * Volatile organic compounds Some regulatory bodies have set standards for the amount of heavy metals in ink. There is a trend toward vegetable oils rather than
petroleum oil Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils. The name 'mineral oil' by itself is imprecise, ...
s in recent years in response to a demand for better environmental sustainability performance. Ink uses up non-renewable oils and metals, which has a negative impact on the environment.


Carbon

Carbon inks were commonly made from lampblack or soot and a binding agent such as gum arabic or animal glue. The binding agent keeps carbon particles in suspension and adhered to paper. Carbon particles do not fade over time even when bleached or when in sunlight. One benefit is that carbon ink does not harm paper. Over time, the ink is chemically stable and therefore does not threaten the paper's strength. Despite these benefits, carbon ink is not ideal for permanence and ease of preservation. Carbon ink tends to smudge in humid environments and can be washed off surfaces. The best method of preserving a document written in carbon ink is to store it in a dry environment (Barrow 1972). Recently, carbon inks made from carbon nanotubes have been successfully created. They are similar in composition to traditional inks in that they use a polymer to suspend the carbon nanotubes. These inks can be used in inkjet printers and produce electrically conductive patterns.


Iron gall (common ink)

Iron gall inks became prominent in the early 12th century; they were used for centuries and were widely thought to be the best type of ink. However, iron gall ink is corrosive and damages paper over time (Waters 1940). Items containing this ink can become brittle and the writing fades to brown. The original scores of Johann Sebastian Bach are threatened by the destructive properties of iron gall ink. The majority of his works are held by the German State Library, and about 25% of those are in advanced stages of decay (American Libraries 2000). The rate at which the writing fades is based on several factors, such as proportions of ink ingredients, amount deposited on the paper, and paper composition (Barrow 1972:16). Corrosion is caused by acid catalysed hydrolysis and iron(II)-catalysed oxidation of cellulose (Rouchon-Quillet 2004:389). Treatment is a controversial subject. No treatment undoes damage already caused by acidic ink. Deterioration can only be stopped or slowed. Some think it best not to treat the item at all for fear of the consequences. Others believe that non-aqueous procedures are the best solution. Yet others think an aqueous procedure may preserve items written with iron gall ink. Aqueous treatments include distilled water at different temperatures, calcium hydroxide, calcium bicarbonate, magnesium carbonate, magnesium bicarbonate, and calcium phytate. There are many possible side effects from these treatments. There can be mechanical damage, which further weakens the paper. Paper color or ink color may change, and ink may bleed. Other consequences of aqueous treatment are a change of ink texture or formation of plaque on the surface of the ink (Reibland & de Groot 1999). Iron gall inks require storage in a stable environment, because fluctuating relative humidity increases the rate that formic acid, acetic acid, and furan derivatives form in the material the ink was used on. Sulfuric acid acts as a catalyst to cellulose hydrolysis, and iron (II) sulfate acts as a catalyst to cellulose oxidation. These chemical reactions physically weaken the paper, causing
brittleness A material is brittle if, when subjected to stress, it fractures with little elastic deformation and without significant plastic deformation. Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Bre ...
.


Indelible ink

''Indelible'' means "unremovable". Some types of indelible ink have a very short shelf life because of the quickly evaporating solvents used. India, Mexico, Indonesia, Malaysia and other developing countries have used indelible ink in the form of
electoral stain An election is a formal group decision-making process by which a population chooses an individual or multiple individuals to hold public office. Elections have been the usual mechanism by which modern representative democracy has operated ...
to prevent
electoral fraud Electoral fraud, sometimes referred to as election manipulation, voter fraud or vote rigging, involves illegal interference with the process of an election, either by increasing the vote share of a favored candidate, depressing the vote share of ...
. Election ink based on silver nitrate was first applied in the
1962 Indian general election General elections were held in India between 19 and 25 February 1962 to elect members of the 3rd Lok Sabha. Unlike the previous two elections, each constituency elected a single member. Jawaharlal Nehru won another landslide victory in his th ...
, after being developed at the National Physical Laboratory of India. The election commission in India has used indelible ink for many elections. Indonesia used it in its last election in
Aceh Aceh ( ), officially the Aceh Province ( ace, Nanggroë Acèh; id, Provinsi Aceh) is the westernmost province of Indonesia. It is located on the northernmost of Sumatra island, with Banda Aceh being its capital and largest city. Granted a s ...
. In Mali, the ink is applied to the fingernail. Indelible ink itself is not infallible as it can be used to commit electoral
fraud In law, fraud is intentional deception to secure unfair or unlawful gain, or to deprive a victim of a legal right. Fraud can violate civil law (e.g., a fraud victim may sue the fraud perpetrator to avoid the fraud or recover monetary compens ...
by marking opponent party members before they have chances to cast their votes. There are also reports of "indelible" ink washing off voters' fingers in Afghanistan.Afghanistan election: 'indelible' ink washes off voters' fingers
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See also

* Blue Wool Scale *
De-inked pulp Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops, waste paper, or rags. Mixed with water and other chemical or plant-based additives, pulp is the major raw mater ...
* Election ink *
Fountain pen inks Fountain pen ink is a water-based ink intended for use with fountain pens. Composition Fountain pen ink is almost exclusively dye-based because fountain pens operate on the principle of capillary action. Pigment-based inks (which contain soli ...
* Gel pen * Ink eraser * Inkjet printing * Inksaving typeface * Invisible ink * Lightfastness *
Pharmaceutical ink Pharmaceutical ink is an ingestible form of water-based ink used on most medicine pills to indicate which drug it is, and/or how many milligrams the pill contains. History The first U.S. patent for pharmaceutical inks was filed on 28 June 1966, ...
* Preservation (library and archival science) *
Preservation of illuminated manuscripts The conservation and restoration of illuminated manuscripts is the care and treatment of illuminated manuscripts which have cultural and historical significance so that they may be viewed, read, and studied now and in the future. It is a specialty ...
* Soy ink *
Squid ink Cephalopod ink is a dark-coloured or luminous ink released into water by most species of cephalopod, usually as an escape mechanism. All cephalopods, with the exception of the Nautilidae and the Cirrina (deep-sea octopuses), are able to release ...
*
Stark's ink Stark's ink is one of a number of types of homemade inks whose recipes were widely available in the 19th century. People often made their own ink before commercially available ink was inexpensively and easily obtainable. Dr. James Stark was a che ...
* Tattoo ink * Toner


References


Sources

* Ainsworth, Mitchell, C., "Inks and Their Composition and Manufacture," Charles Griffin and Company Ltd, 1904. * * Banerji, Sures Chandra (1989). ''A Companion to Sanskrit Literature''. Motilal Banarsidass. . * * Martín-Gil J., Ramos-Sánchez MC, Martín-Gil FJ and José-Yacamán M. "Chemical composition of a fountain pen ink". ''Journal of Chemical Education'', 2006, 83, 1476–78. * * * Sircar, D. C. (1996).''Indian epigraphy''. Motilal Banarsidass. . *


Further reading

* Cueppers, Christoph (1989). "On the Manufacture of Ink." ''Ancient Nepal – Journal of the Department of Archaeology'', Number 113, August–September 1989, pp. 1–7. [The Tibetan text and translation of a section of the work called, ''Bzo gnas nyer mkho'i za ma tog'' by 'Jam-mgon 'Ju Mi-pham-rgya-mtsho (1846–1912) describing various traditional Tibetan techniques of making inks from different sources of soot, and from earth, puffballs, dung, ''ser-sha'' – a yellow fungus, and the fruit of ''tsi dra ka'' (''Ricinus communis'').]


External links


Forty Centuries of Ink (David N. Carvalho); A detailed online textbook


* ttp://www.djmcadam.com/ink-recipe.html Ancient and Modern Ink Recipes (David N. Carvalho)
Gorgeous Portrayal Of How Ink Is Made
– video at '' The Huffington Post''
"A Light Note on the Science of Writing and Inks"
is a manuscript, in Arabic, from 1852. It discusses the process of making inks. {{Authority control Printing materials