High-pressure chemistry is concerned with those chemical processes that are carried out under
high pressure
In science and engineering the study of high pressure examines its effects on materials and the design and construction of devices, such as a diamond anvil cell, which can create high pressure. By ''high pressure'' is usually meant pressures of th ...
– pressures in the thousands of
bars (100 k
Pa) or higher. High-pressure processes are generally faster and have a higher conversion efficiency than processes at ambient pressure. However, they are usually only beneficial on an industrial scale because of the investment in plant required.
[Rupert Stevenson Bradley, Duncan Cottrel Munro, ''High Pressure Chemistry'' Pergamon Press, 1965 .]
The
Haber–Bosch process
The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation process and is the main industrial procedure for the production of ammonia today. It is named after its inventors, the German chemists Fritz Haber and C ...
produces
ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
from
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
and atmospheric
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
. It was first demonstrated in 1909 and became an important industrial process for Germany during
World War One
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fightin ...
when it played a part in the manufacture of explosives. Today, it is mostly used to produce fertilizer.
The
Bergius process
The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of high-volatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius ...
produces
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
fuel from
bituminous coal and hydrogen. The process was first published in 1913 and was an important source of fuel for Germany during
World War Two
World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing ...
. The process was used in the US for a while after the war, but there are currently no commercial plants in the world.
The Bergius process and the Haber-Bosch process were two pioneering methods of high-pressure chemistry. The invention and development of these two processes led to the award of the
Nobel Prize in Chemistry
)
, image = Nobel Prize.png
, alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
for 1931 jointly to
Friedrich Bergius
Friedrich Karl Rudolf Bergius (, 11 October 1884 – 30 March 1949) was a German chemist known for the Bergius process for producing synthetic fuel from coal, Nobel Prize in Chemistry (1931, together with Carl Bosch) in recognition of contribu ...
and
Carl Bosch
Carl Bosch (; 27 August 1874 – 26 April 1940) was a German chemist and engineer and Nobel Laureate in Chemistry. He was a pioneer in the field of high-pressure industrial chemistry and founder of IG Farben, at one point the world's largest ...
.
See also
*
Jiri Jonas
*
Otto Ruff
Otto Ruff (12 December 1871 – 17 September 1939) was a German chemist.
Life
Otto Ruff was born in Schwäbisch Hall, Württemberg. After becoming a pharmacist under the supervision of Carl Magnus von Hell (known from the Hell-Volhard-Zelinsky ...
*
Hanns Hörbiger
Johannes "Hanns" Evangelist Hörbiger (29 November 1860, in Atzgersdorf – 11 October 1931, in Mauer), better known as Hanns Hörbiger, was an Austrian engineer from Vienna with roots in Tyrol. He took part in the construction of the Budapes ...
*
Vladimir Ipatieff
Vladimir Nikolayevich Ipatieff (also Ipatyev; russian: Владимир Николаевич Ипатьев); (November 21, 1867 (November 9 OS) – November 29, 1952) was a Russian and American chemist. His most important contributions are in the ...
*
Nylon
Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic.
Nylon is a silk-like thermoplastic, generally made from pe ...
References
History of chemistry
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