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Bergius Process
The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of high-volatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius was awarded the Nobel Prize in Chemistry for his development of high-pressure chemistry. Process The coal is finely ground and dried in a stream of hot gas. The dry product is mixed with heavy oil recycled from the process. A catalyst is typically added to the mixture. A number of catalysts have been developed over the years, including tungsten or molybdenum disulfide, tin or nickel oleate, and others. Alternatively, iron sulfide present in the coal may have sufficient catalytic activity for the process, which was the original Bergius process. The mixture is pumped into a reactor. The reaction occurs at between 400 and 500 °C and 20 to 70 MPa hydrogen pressure. The reaction produces heavy oils, middle oils, gasoline, and gases. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Friedrich Bergius (1884-1949) Chemist Of Heidelberg Wellcome L0003155
Friedrich Karl Rudolf Bergius (, 11 October 1884 – 30 March 1949) was a German chemist known for the Bergius process for producing synthetic fuel from coal, Nobel Prize in Chemistry (1931, together with Carl Bosch) in recognition of contributions to the invention and development of chemical high-pressure methods. Having worked with IG Farben during World War II, his citizenship came into question following the war, causing him to ultimately flee to Argentina, where he acted as adviser to the Ministry of Industry. Bergius was born near Breslau (Wrocław), within the German Empire's Prussian Province of Silesia. Academic career Before studying chemistry, Bergius was sent to work for 6 months at the Friedrich Wilhelms steel works in Mülheim. His studies started at the University of Breslau in 1903 and ended with a PhD in chemistry at the University of Leipzig in 1907, after only 4 years. His thesis on sulfuric acid as solvent was supervised by Arthur Rudolf Hantzsch. In 1909 Be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Degree Of Unsaturation
In the analysis of the molecular formula of organic molecules, the degree of unsaturation (also known as the index of hydrogen deficiency (IHD), double bond equivalents, or unsaturation index) is a calculation that determines the total number of rings and π bonds. A formula is used in organic chemistry to help draw chemical structures. It does not give any information about those components individually—the specific number of rings, or of double bonds (one π bond each), or of triple bonds (two π bonds each). The final structure is verified with use of NMR, mass spectrometry and IR spectroscopy, as well as qualitative inspection. It is based on comparing the actual molecular formula to what would be a possible formula if the structure were saturated—having no rings and containing only σ bonds—with all atoms having their standard valence. General formula The formula for degree of unsaturation is: :\mathrm = 1 + \tfrac \sum n_i(v_i-2) where ''ni'' is the number of atoms ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fischer–Tropsch Process
The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of and pressures of one to several tens of atmospheres. The process was first developed by Franz Fischer and Hans Tropsch at the Kaiser Wilhelm Institute for Coal Research in Mülheim an der Ruhr, Germany, in 1925. As a premier example of C1 chemistry, the Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification. The process then converts these gases into synthetic oil, synthetic lubrication oil and synthetic fuel. This process has received intermittent attention as a source of low-s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lignite
Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat content. When removed from the ground, it contains a very high amount of moisture which partially explains its low carbon content. Lignite is mined all around the world and is used almost exclusively as a fuel for steam-electric power generation. The combustion of lignite produces less heat for the amount of carbon dioxide and sulfur released than other ranks of coal. As a result, environmental advocates have characterized lignite as the most harmful coal to human health. Depending on the source, various toxic heavy metals, including naturally occurring radioactive materials may be present in lignite which are left over in the coal fly ash produced from its combustion, further increasing health risks. Characteristics Lignite is brow ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liquid Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or exemplified by the odors of gasoline and lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to the naturally occurring petroleum, natural gas and coal, and to their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are carbon dio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Habilitation
Habilitation is the highest university degree, or the procedure by which it is achieved, in many European countries. The candidate fulfills a university's set criteria of excellence in research, teaching and further education, usually including a dissertation. The degree, abbreviated "Dr. habil." (Doctor habilitatus) or "PD" (for "Privatdozent"), is a qualification for professorship in those countries. The conferral is usually accompanied by a lecture to a colloquium as well as a public inaugural lecture. History and etymology The term ''habilitation'' is derived from the Medieval Latin , meaning "to make suitable, to fit", from Classical Latin "fit, proper, skillful". The degree developed in Germany in the seventeenth century (). Initially, habilitation was synonymous with "doctoral qualification". The term became synonymous with "post-doctoral qualification" in Germany in the 19th century "when holding a doctorate seemed no longer sufficient to guarantee a proficient transfer o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wilsonville, Alabama
Wilsonville is a town in southeastern Shelby County, Alabama, United States, located northeast of Columbiana. At the 2020 census, the population was 1,857. Wilsonville is named after the earliest settler in the area, Elisha Wilson. The town was incorporated in 1897. 3 years later in 1900, it had the distinction of being the largest community in Shelby County with 1,095, edging out the county seat of Columbiana by 20 people. It lost the distinction to Columbiana in 1910 and would not exceed its 1900 population again until 1990.1820-2010 U.S. Censuses research on Shelby County, Alabama communities Geography Wilsonville is located at (33.234924, -86.486283). The town is located in the southeastern part of Shelby County, with parts of its city limits extending east to the western shore of the Coosa River. Alabama State Route 25 is the main highway through the town, running northeast to southwest through the downtown area. Via AL 25, Harpersville is 9 mi (14 km) northeas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steam Reforming
Steam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is hydrogen production. The reaction is represented by this equilibrium: :CH4 + H2O CO + 3 H2 The reaction is strongly endothermic (Δ''H''SR = 206 kJ/mol). Hydrogen produced by steam reforming is termed 'grey hydrogen' when the waste carbon monoxide is released to the atmosphere and 'blue hydrogen' when the carbon monoxide is (mostly) captured and stored geologically - see carbon capture and storage. Zero carbon 'green' hydrogen is produced by thermochemical water splitting, using solar thermal, low- or zero-carbon electricity or waste heat, or electrolysis, using low- or zero-carbon electricity. Zero carbon emissions 'turquoise' hydrogen is produced by one-step methane pyrolysis of natural gas. Steam reforming of natural gas produces most of the world ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Research Octane Number
An octane rating, or octane number, is a standard measure of a fuel's ability to withstand compression in an internal combustion engine without detonating. The higher the octane number, the more compression the fuel can withstand before detonating. Octane rating does not relate directly to the power output or the energy content of the fuel per unit mass or volume, but simply indicates gasoline's capability against compression. Whether or not a higher octane fuel improves or impairs an engine's performance depends on the design of the engine. In broad terms, fuels with a higher octane rating are used in higher-compression gasoline engines, which may yield higher power for these engines. Such higher power comes from the fuel's higher compression by the engine design, and not directly from the gasoline. In contrast, fuels with lower octane (but higher cetane numbers) are ideal for diesel engines because diesel engines (also called compression-ignition engines) do not compress the fuel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Catalytic Reforming
Catalytic reforming is a chemical process used to convert petroleum refinery naphthas distilled from crude oil (typically having low octane ratings) into high-octane liquid products called reformates, which are premium blending stocks for high-octane gasoline. The process converts low-octane linear hydrocarbons (paraffins) into branched alkanes (isoparaffins) and cyclic naphthenes, which are then partially dehydrogenated to produce high-octane aromatic hydrocarbons. The dehydrogenation also produces significant amounts of byproduct hydrogen gas, which is fed into other refinery processes such as hydrocracking. A side reaction is hydrogenolysis, which produces light hydrocarbons of lower value, such as methane, ethane, propane and butanes. In addition to a gasoline blending stock, reformate is the main source of aromatic bulk chemicals such as benzene, toluene, xylene and ethylbenzene which have diverse uses, most importantly as raw materials for conversion into plastics. Howev ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Catalytic Reforming
Catalytic reforming is a chemical process used to convert petroleum refinery naphthas distilled from crude oil (typically having low octane ratings) into high-octane liquid products called reformates, which are premium blending stocks for high-octane gasoline. The process converts low-octane linear hydrocarbons (paraffins) into branched alkanes (isoparaffins) and cyclic naphthenes, which are then partially dehydrogenated to produce high-octane aromatic hydrocarbons. The dehydrogenation also produces significant amounts of byproduct hydrogen gas, which is fed into other refinery processes such as hydrocracking. A side reaction is hydrogenolysis, which produces light hydrocarbons of lower value, such as methane, ethane, propane and butanes. In addition to a gasoline blending stock, reformate is the main source of aromatic bulk chemicals such as benzene, toluene, xylene and ethylbenzene which have diverse uses, most importantly as raw materials for conversion into plastics. Howev ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cracking (chemistry)
In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of a large alkane into smaller, more useful alkenes. Simply put, hydrocarbon cracking is the process of breaking a long chain of hydrocarbons into short ones. This process requires high temperatures. More loosely, outside the field of petroleum chemistry, the term "cracking" is used to describe any type of splitting of molecules under the influence of heat, catalysts and solvents, such as in processes of destructive distillation or pyrolysis. Fluid catalytic cracking produces a high yield of petrol and LPG, while hydrocracking is a major source of jet fuel, die ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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