Hauyne or haüyne, also called hauynite or haüynite ( ), is a

tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...

sulfate mineral with endmember formula . As much as 5 wt % may be present, and also and Cl. It is a

feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing prim ...

and a member of the

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an wikt:ornamental, ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite i ...

group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in

Monte Somma Mount Somma ( it, Monte Somma) is a mountain located in the Province of Naples, in the Campania region of southern Italy. Mount Somma is an integral part of the Somma–Vesuvius volcanic complex. It is high. Geography Mount Somma is the rem ...

, Italy,Farndon and Parker (2009). Minerals, Rocks and Fossils of the World. Lorenz Books and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

Sodalite group

Formulae: *haüyne *

nosean Nosean, also known as noselite, is a mineral of the feldspathoid group with formula: Na8 Al6 Si6 O24( SO4). H2O. It forms isometric crystals of variable color: white, grey, blue, green, to brown. It has a Mohs hardness of 5.5 to 6 and a specific ...

lazurite Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula . It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually ...

* tsaregorodtsevite *

tugtupite Tugtupite is a beryllium aluminium tectosilicate. It also contains sodium and chlorine and has the formula Na4 Al Be Si4 O12 Cl. Tugtupite is a member of the silica-deficient feldspathoid mineral group. It occurs in high alkali intrusive igneous ...

* vladimirivanovite All these minerals are

s. Haüyne forms a solid solution with nosean and with sodalite. Complete solid solution exists between synthetic nosean and haüyne at 600 °C, but only limited solid solution occurs in the sodalite-nosean and sodalite-haüyne systems.Bellatreccia, Della Ventura, Piccinini, Cavallo and Brilli (2009): H₂O and CO₂ in minerals of the haüyne-sodalite group: an FTIR spectroscopy study. Mineralogical Magazine 73:399-413 The characteristic blue color of sodalite-group minerals arises mainly from caged and clusters.

Unit cell

Haüyne belongs to the hexatetrahedral

class Class or The Class may refer to: Common uses not otherwise categorized * Class (biology), a taxonomic rank * Class (knowledge representation), a collection of individuals or objects * Class (philosophy), an analytical concept used differentl ...

of the isometric system, 3m, space group P3n. It has one formula unit per unit cell (Z = 1), which is a

cube In geometry, a cube is a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex. Viewed from a corner it is a hexagon and its net is usually depicted as a cross. The cube is the only r ...

with side length of 9 Å. More accurate measurements are as follows: *a = 8.9 Å *a = 9.08 to 9.13 Å *a = 9.10 to 9.13 Å *a = 9.11(2) Å *a = 9.116 Å *a = 9.13 ÅDeer Howie and Zussman (1963) Rock-forming minerals, Volume 4, Framework Silicates, pages 289 to 302

Structure

All

silicates In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...

have a basic structural unit that is a

tetrahedron In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the o ...

with an

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...

O at each apex, and a

silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...

ion Si in the middle, forming (SiO₄)⁴⁻. In

tectosilicates Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...

(framework silicates) each oxygen ion is shared between two tetrahedra, linking all the tetrahedra together to form a framework. Since each O is shared between two tetrahedra only half of it "belongs" to the Si ion in either tetrahedron, and if no other components are present then the formula is SiO₂, as in

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...

Aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...

ions Al, can substitute for some of the silicon ions, forming (AlO₄)⁵⁻ tetrahedra. If the substitution is random the ions are said to be disordered, but in haüyne the Al and Si in the tetrahedral framework are fully ordered. Si has a charge 4+, but the charge on Al is only 3+. If all the cations (positive ions) are Si then the positive charges on the Si's exactly balance the negative charges on the O's. When Al replaces Si there is a deficiency of positive charge, and this is made up by extra positively charged ions (cations) entering the structure, somewhere in between the tetrahedra. In haüyne these extra cations are

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...

Na⁺ and

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...

Ca²⁺, and in addition the negatively charged sulfate group (SO₄)²⁻ is also present. In the haüyne structure the tetrahedra are linked to form six-membered rings that are stacked up in an ..ABCABC.. sequence along one direction, and rings of four tetrahedra are stacked up parallel to another direction. The resulting arrangement forms continuous channels that can accommodate a large variety of cations and

anions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

Appearance

Haüyne crystallizes in the

isometric The term ''isometric'' comes from the Greek for "having equal measurement". isometric may mean: * Cubic crystal system, also called isometric crystal system * Isometre, a rhythmic technique in music. * "Isometric (Intro)", a song by Madeon from ...

system forming rare dodecahedral or pseudo- octahedral crystals that may reach 3 cm across; it also occurs as rounded grains. The crystals are transparent to translucent, with a vitreous to greasy luster. The color is usually bright blue, but it can also be white, grey, yellow, green and pink. In thin section the crystals are colorless or pale blue, and the streak is very pale blue to white.

Optical properties

Haüyne is

isotropic Isotropy is uniformity in all orientations; it is derived . Precise definitions depend on the subject area. Exceptions, or inequalities, are frequently indicated by the prefix ' or ', hence ''anisotropy''. ''Anisotropy'' is also used to describe ...

. Truly isotropic minerals have no

birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...

, but haüyne is weakly birefringent when it contains inclusions. The

refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...

is 1.50; although this is quite low, similar to that of ordinary window glass, it is the largest value for minerals of the sodalite group. It may show reddish orange to purplish pink

fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...

under longwave

ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...

light.

Physical properties

Cleavage is distinct to perfect, and twinning is common, as contact, penetration and polysynthetic twins. The fracture is uneven to

conchoidal Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically sli ...

, the mineral is brittle, and it has

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...

to 6, almost as hard as

feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...

. All the members of the sodalite group have quite low densities, less than that of

; haüyne is the densest of them all, but still its

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

is only 2.44 to 2.50. If haüyne is placed on a glass slide and treated with

nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...

HNO₃, and then the solution is allowed to evaporate slowly,

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...

needles of

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...

form. This distinguishes haüyne from

, which forms cubic crystals of

chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...

under the same conditions. The mineral is not

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...

Geological setting and associations

Haüyne occurs in

phonolite Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous ...

s and related leucite- or

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites ...

-rich,

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

-poor,

igneous rocks Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...

; less commonly in nepheline-free extrusives and metamorphic rocks (

marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the ...

). Associated minerals include

, leucite, titanian

andradite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".melilite,

augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group. ...

sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system ...

biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...

, phlogopite and

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...

Localities

The type locality is Lake Nemi,

Alban Hills The Alban Hills ( it, Colli Albani) are the caldera remains of a quiescent volcano, volcanic complex in Italy, located southeast of Rome and about north of Anzio. The high Monte Cavo forms a highly visible peak the centre of the caldera, bu ...

, Rome Province, Latium, Italy. Occurrences include: *Canary Islands: A pale blue mineral intermediate between haüyne and

has been found in

spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties S ...

dunite Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with mi ...

xenoliths A xenolith ("foreign rock") is a rock fragment (country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ign ...

from La Palma, Canary Islands.Wulff-Pedersen et al (2000) American Mineralogist 85:1397-1405 *Ecuador: Phenocrysts found in alkaline extrusive rocks ( tephrite), product of effusive volcanism of the

Sumaco Sumaco is a symmetrical, isolated stratovolcano, that is set off from the main Ecuador volcanic axis. Its rocks are very distinct from those from most Andean volcanoes because of its lack of andesitic composition, in favour of basanite and phonolit ...

volcano, of northeast

Ecuador Ecuador ( ; ; Quechua: ''Ikwayur''; Shuar: ''Ecuador'' or ''Ekuatur''), officially the Republic of Ecuador ( es, República del Ecuador, which literally translates as "Republic of the Equator"; Quechua: ''Ikwadur Ripuwlika''; Shuar: ''Eku ...

. *Germany: In ejected rocks of hornblende-haüyne- scapolite rock from the Laach lake volcanic complex, Eifel, Rhineland-Palatinate *Italy: Anhedral blue to dark grey phenocrysts in leucite- melilite-bearing

lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...

at Monte Vulture, Melfi, Basilicata, Potenza *Italy: Millimetric transparent blue crystals in ejecta consisting mainly of K-feldspar and plagioclase from Albano Laziale, Roma *Italy: Ejected blocks in the peperino of the

, Rome Province, Latium, contain white octahedral haüyne associated with leucite,

garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...

, melilite and latiumite. *US: Haüyne of metamorphic origin occurs at the Edwards Mine,

St. Lawrence County, New York St. Lawrence County is a county in the U.S. state of New York. As of the 2020 census, the population was 108,505. The county seat is Canton. The county is named for the Saint Lawrence River, which in turn was named for the Christian saint L ...

. *US: Haüyne occurs in nepheline alnoite with melilite, phlogopite and

at Winnett,

Petroleum County, Montana Petroleum County is a county in the U.S. state of Montana. As of the 2020 census, the population was 496, making it the least populous county in Montana and the eighth-least populous in the United States. Its county seat is Winnett. The count ...

, US. *US: Haüyne is common in small quantities as phenocrysts in

and

lamprophyre Lamprophyres () are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxid ...

at the Cripple Creek, Colorado Mining District, Colorado, US.Carnein and Bartos (2005) Mineralogical Record 36-2:173

References

{{reflist

External links

JMol: http://rruff.geo.arizona.edu/AMS/viewJmol.php?id=05334 V. Nasti, "L’olotipo dell'haüyna" (2009), Il Cercapietre, Notiziario del Gruppo Mineralogico Romano, n. 1-2/2009, pagg.16-43. Feldspathoid Sodalite group Sodium minerals Calcium minerals Aluminium minerals Cubic minerals Minerals in space group 218 Luminescent minerals Gemstones