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Harry Wesley Coover Jr. (March 6, 1917 – March 26, 2011) was the inventor of Eastman 910, commonly known as
Super Glue Cyanoacrylates are a family of strong fast-acting adhesives with industrial, medical, and household uses. They are derived from ethyl cyanoacrylate and related esters. The cyanoacrylate group in the monomer rapidly polymerizes in the presence ...
.


Life and career

Coover was born in
Newark, Delaware Newark ( )Not as in Newark, New Jersey. is a small city in New Castle County, Delaware, New Castle County, Delaware, United States. It is located west-southwest of Wilmington, Delaware, Wilmington. According to the 2010 United States Census, ...
. He lived in Delaware until his teen years. During this time he was hit by a train while driving which resulted in him being in a
coma A coma is a deep state of prolonged unconsciousness in which a person cannot be awakened, fails to respond normally to painful stimuli, light, or sound, lacks a normal wake-sleep cycle and does not initiate voluntary actions. Coma patients exhi ...
for about six weeks. After he recovered, Coover moved to
Weedsport, New York Weedsport is a village in Cayuga County, New York, United States. The population was 1,815 at the 2010 census. The name is from Elihu and Edward Weed, merchants who helped found the village. Weedsport is in the town of Brutus, west of Syracuse. ...
to finish high school.Family history submitted by Dr. Dana Coover, (granddaughter) He stayed in New York and received his
Bachelor of Science A Bachelor of Science (BS, BSc, SB, or ScB; from the Latin ') is a bachelor's degree awarded for programs that generally last three to five years. The first university to admit a student to the degree of Bachelor of Science was the University of ...
from Hobart College in chemistry before earning his
Master of Science A Master of Science ( la, Magisterii Scientiae; abbreviated MS, M.S., MSc, M.Sc., SM, S.M., ScM or Sc.M.) is a master's degree in the field of science awarded by universities in many countries or a person holding such a degree. In contrast to ...
and Ph. D. in organic chemistry from
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
. His dissertation was on commercial synthesis of vitamin B6. He intended to work with vitamin B6 until WWII hit and the process he developed was taken by the military for their use. Coover worked as a chemist for
Eastman Kodak The Eastman Kodak Company (referred to simply as Kodak ) is an American public company that produces various products related to its historic basis in analogue photography. The company is headquartered in Rochester, New York, and is incorpor ...
from 1944–1973 and as the Vice President of research and development for the company from 1973-1984. In 1951, Coover had moved to Eastman Kodak's chemical plant in Kingsport Tennessee. Coover was married to Muriel Zumbach Coover for over 60 years until her death in 2005. He is survived by his sons Harry Wesley Coover III, Dr. Stephen Rohm Coover, daughter Dr. Melinda Rohm Coover Paul, four grandchildren Brett Evan Coover, Dana Noelle Coover, Vincent Adam Paul, and Kirsten Rohm Paul Gilliam and 4 great grandchildren.Melinda Rohm Coover Paul, MD Coover died of natural causes at his home in Kingsport, Tennessee, on March 26, 2011


Super Glue

In 1942, while searching for materials to make clear plastic gun sights, cyanoacrylate was discovered. At this time they were deemed too sticky to be of use and were set aside. In 1951, (nine years later), Coover and his team at
Eastman Kodak The Eastman Kodak Company (referred to simply as Kodak ) is an American public company that produces various products related to its historic basis in analogue photography. The company is headquartered in Rochester, New York, and is incorpor ...
examined
cyanoacrylates Cyanoacrylates are a family of strong fast-acting adhesives with industrial, medical, and household uses. They are derived from ethyl cyanoacrylate and related esters. The cyanoacrylate group in the monomer rapidly polymerizes in the presenc ...
again. Coover was overseeing Kodak chemists investigating heat-resistant polymers for jet canopies when cyanoacrylates were once again tested and proved too sticky. When a chemist in the group informed Coover that he had permanently damaged an expensive refractometer by gluing it together, Coover recognized that he had discovered a unique adhesive. In 1958, the adhesive, marketed by Kodak as Eastman 910 and then as
Super Glue Cyanoacrylates are a family of strong fast-acting adhesives with industrial, medical, and household uses. They are derived from ethyl cyanoacrylate and related esters. The cyanoacrylate group in the monomer rapidly polymerizes in the presence ...
, was introduced for sale. Generally,
cyanoacrylate Cyanoacrylates are a family of strong fast-acting adhesives with industrial, medical, and household uses. They are derived from ethyl cyanoacrylate and related esters. The cyanoacrylate group in the monomer rapidly polymerizes in the presence ...
is an
acrylic Acrylic may refer to: Chemicals and materials * Acrylic acid, the simplest acrylic compound * Acrylate polymer, a group of polymers (plastics) noted for transparency and elasticity * Acrylic resin, a group of related thermoplastic or thermosett ...
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on natu ...
which rapidly
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
ises in the presence of water (specifically
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s), forming long, strong chains, joining the bonded surfaces together. Because the presence of moisture causes the glue to set, exposure to moisture in the air can cause a tube or bottle of glue to become unusable over time. To prevent an opened container of glue from setting before use, it must be stored in an airtight jar or bottle with a package of
silica gel Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other l ...
. Another convenient way is attaching a hypodermic needle on the opening of glue. After applying, residual glue soon clogs the needle, keeping moisture out. The clog is removed by heating the needle (e.g. by a lighter) before use. Cyanoacrylate is used as a
forensic Forensic science, also known as criminalistics, is the application of science to Criminal law, criminal and Civil law (legal system), civil laws, mainly—on the criminal side—during criminal investigation, as governed by the legal standard ...
tool to capture
latent fingerprint A fingerprint is an impression left by the friction ridges of a human finger. The recovery of partial fingerprints from a crime scene is an important method of forensic science. Moisture and grease on a finger result in fingerprints on surfac ...
s on non-porous surfaces like glass, plastic, etc. Cyanoacrylate is warmed to produce fumes which react with the invisible fingerprint residues and atmospheric moisture to form a white polymer (polycyanoacrylate) on the fingerprint ridges. The ridges can then be recorded. The developed fingerprints are, on most surfaces (except on white plastic or similar), visible to the naked eye. Invisible or poorly visible prints can be further enhanced by applying a luminescent or non-luminescent stain. While much attention was given to the glue's capacity to bond solid materials, Coover was also the first to recognize and patent cyanoacrylates as a tissue adhesive after his eldest son cut open his finger while making a model and glued the cut closed with the glue he had samples of from the lab, an early formulation of super glue. Super glue was first used in the
Vietnam War The Vietnam War (also known by #Names, other names) was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vie ...
in a spray form as a hemostatic agent to temporarily patch the internal organs of injured soldiers until conventional surgery could be performed. Tissue adhesives are now used worldwide for a variety of sutureless surgical applications in humans and animals. Coover said many times that he was most proud of the medical applications of cyanoacrylates, that they had saved many lives and would continue to do so.


Other inventions

Coover held 460 patents and Super Glue was just one of his many discoveries. He viewed "programmed innovation," a management methodology emphasizing research and development, among his most important work. Implemented at Kodak, programmed innovation resulted in the introduction of 320 new products and sales growth from $1.8 billion to $2.5 billion. Coover later formed an international management consulting practice, advising corporate clients around the world on programmed innovation methodology. Coover received the Southern Chemist Man of the Year Award for his outstanding accomplishments in individual innovation and creativity. He also held the Earle B. Barnes Award for Leadership in Chemical Research Management, the
Maurice Holland Award ''Research-Technology Management'' (''RTM'') is a journal published by the Industrial Research Institute (IRI). It publishes Peer review, peer-reviewed, research-based articles and personal perspective pieces written by and for Research and develop ...
, the
IRI Achievement Award The IRI Achievement Award, established by the Industrial Research Institute (IRI) in 1973, is awarded "to honor outstanding accomplishment in individual creativity and innovation that contributes broadly to the development of industry and to the be ...
, and was a
medalist A medalist (or medallist) is an artist who designs medals, plaquettes, badges, metal medallions, coins and similar small works in relief in metal. Historically, medalists were typically also involved in producing their designs, and were usually e ...
for the
Industrial Research Institute Innovation Research Interchange (IRI) is a division of the National Association of Manufacturers, a nonprofit association based in Washington, D. C., United States. IRI was founded as a private non-profit in 1938 and merged with the NAM in 2022. IR ...
. In 1983, Coover was elected to the
National Academy of Engineering The National Academy of Engineering (NAE) is an American nonprofit, non-governmental organization. The National Academy of Engineering is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy ...
. In 2004, Coover was inducted into the
National Inventor's Hall of Fame The National Inventors Hall of Fame (NIHF) is an American not-for-profit organization, founded in 1973, which recognizes individual engineers and inventors who hold a U.S. patent of significant technology. Besides the Hall of Fame, it also opera ...
. In 2010, Coover received the
National Medal of Technology and Innovation The National Medal of Technology and Innovation (formerly the National Medal of Technology) is an honor granted by the President of the United States to American inventors and innovators who have made significant contributions to the development ...
.


References

{{DEFAULTSORT:Coover, Harry 1917 births 2011 deaths People from Newark, Delaware People from Kingsport, Tennessee Cornell University alumni 20th-century American inventors Kodak people Hobart and William Smith Colleges alumni Inventors from Delaware