1,1,1,2,3,3,3-Heptafluoropropane, also called heptafluoropropane, HFC-227ea (

ISO ISO is the most common abbreviation for the International Organization for Standardization. ISO or Iso may also refer to: Business and finance * Iso (supermarket), a chain of Danish supermarkets incorporated into the SuperBest chain in 2007 * Iso ...

name), HFC-227 or FM-200, as well as apaflurane (

INN Inns are generally establishments or buildings where travelers can seek lodging, and usually, food and drink. Inns are typically located in the country or along a highway; before the advent of motorized transportation they also provided accommo ...

), is a colourless, odourless gaseous halocarbon commonly used as a

gaseous fire suppression Gaseous fire suppression, also called clean agent fire suppression, is a term to describe the use of inert gases and chemical agents to extinguish a fire. These agents are governed by the National Fire Protection Association (NFPA) Standard for C ...

agent.

Chemistry

Its chemical formula is CF-CHF-CF, or CHF. With a boiling point of −16.4 °C, it is a gas at room temperature. It is slightly soluble in water (260 mg/L).

Use

HFC-227ea is used in

fire suppression system Fire suppression systems are used to extinguish, control, or in some cases, entirely prevent fires from spreading or occurring. Fire suppression systems have an incredibly large variety of applications, and as such, there are many different types ...

s that protect data processing and telecommunication facilities, and in fire suppression of many flammable liquids and gases. HFC-227ea is categorized as a Clean Agent and is governed by ''NFPA 2001 - Standard for Clean Agent Fire Extinguishing Systems''. Effective fire suppression requires introducing a concentration of the HFC-227ea agent between 6.25% and 9% depending on the hazard being suppressed. Its

NOAEL The no-observed-adverse-effect level (NOAEL) denotes the level of exposure of an organism, found by experiment or observation, at which there is no biologically or statistically significant increase in the frequency or severity of any adverse effec ...

for cardiac sensitization is 9%. The

United States Environmental Protection Agency The Environmental Protection Agency (EPA) is an independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it ...

allows concentration of 9% volume in occupied spaces without mandated egress time, or up to 10.5% for a limited time. Most fire suppression systems are designed to provide concentration of 6.25-9%. The HFC-227ea fire suppression agent was the first non-ozone-depleting replacement for

Halon 1301 Bromotrifluoromethane, commonly known as Halon 1301, R13B1, Halon 13B1 or BTM, is an organic halide with the chemical formula C Br F3. It is used for gaseous fire suppression as a far less toxic alternative to bromochloromethane. Table of phys ...

. In addition, HFC-227ea leaves no residue on valuable equipment after discharge. HFC-227ea contains no chlorine or bromine atoms, presenting no ozone depletion effect. Its atmospheric lifetime is approximated between 31 and 42 years. It leaves no residue or oily deposits and can be removed by ventilation of the affected space. As an aerosol propellant, HFC-227ea is used in pharmaceutical metered dose inhalers such as those used for dispensing

asthma Asthma is a long-term inflammatory disease of the airways of the lungs. It is characterized by variable and recurring symptoms, reversible airflow obstruction, and easily triggered bronchospasms. Symptoms include episodes of wheezing, co ...

medication.

Safety

At high temperatures, heptafluoropropane will decompose and produce hydrogen fluoride. The decomposition produces a sharp, pungent odour, which can be perceived in concentrations far below a dangerous level. Other decomposition products include

carbonyl fluoride Carbonyl fluoride is a chemical compound with the formula COF2. It is a carbon oxohalide. This gas, like its analog phosgene, is colourless and highly toxic. The molecule is planar with ''C''2v symmetry, bond lengths of 1.174 Å (C=O) and 1.312 ...

carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...

and

carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...

. Prior to re-entry of a room where HFC-227ea system has been activated to suppress a fire, the atmosphere should be tested. An Acid Scavenging Additive added to heptafluoropropane reduces the amount of hydrogen fluoride. Contact with liquid HFC-227ea may cause

frostbite Frostbite is a skin injury that occurs when exposed to extreme low temperatures, causing the freezing of the skin or other tissues, commonly affecting the fingers, toes, nose, ears, cheeks and chin areas. Most often, frostbite occurs in the ha ...

Climate change considerations

Heptafluoropropane (HFC-227ea) contributes to

climate change In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to ...

. It has a

global warming potential Global warming potential (GWP) is the heat absorbed by any greenhouse gas in the atmosphere, as a multiple of the heat that would be absorbed by the same mass of carbon dioxide (). GWP is 1 for . For other gases it depends on the gas and the time ...

(GWP) of 3,220 over 100 years. Due to its high GWP, the HFC-227ea has been included in the list of controlled substances of the

Montreal Protocol The Montreal Protocol is an international treaty designed to protect the ozone layer by phasing out the production of numerous substances that are responsible for ozone depletion. It was agreed on 16 September 1987, and entered into force o ...

(2016 Kigali amendment, in effect in January 2019). Under EU regulations, production, imports and sales of HFC-227ea in spray cans such as freeze sprays or dusters have been prohibited since 2014, as the GWP is over the limit of 150 for these applications.

Tradenames for HFC-227ea used as fire suppression agent

* FE-227 FM-200 (Dupont) (

(EPA) SNAP Listed) * FITECH - 227 (Fitech Engineers) * Solkaflam 227 (Solvay Fluor) * MH-227 (Shanghai Waysmos) (

(EPA) SNAP Listed) * Orient 227 (Orient Corporation) (

(EPA) SNAP Listed) * SR-200 (SRI) * NAF S 227(Safety High Tech)

References

Sinerji Fire Protection Product Page
2009-04-25)

External links

MSDS for heptafluoropropaneMSDS for heptafluoropropane

MSDS for heptafluoropropaneSDS for (LUKE 227) heptafluoropropaneSDS for Chemori 227
{{DEFAULTSORT:Heptafluoropropane, 1, 1, 1, 2, 3, 3, 3- Fluoroalkanes Fire suppression agents Aerosol propellants Refrigerants