Germanium(IV) Nitride
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Germanium(IV) nitride is an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
with the chemical formula Ge3N4. It can be produced through the reaction of
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
: :3 Ge + 4 NH3 → Ge3N4 + 6 H2


Structure

In its pure state, germanium(IV) nitride is a colorless, inert solid that crystallizes in many polymorphs, of which the most stable is the trigonal β-form (space group ''P''31''c''). In this structure, the germanium atoms are tetrahedrally coordinated while the nitrogen atoms are trigonal planar. The γ-form, which forms under high pressure, has a spinel structure.


References

{{Nitrides Germanium(IV) compounds Nitrides