Gaspéite, a very rare

nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...

carbonate mineral Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Sider ...

, with the formula , is named for the place it was first described, in the

Gaspé Peninsula The Gaspé Peninsula, also known as Gaspesia (; ), is a peninsula along the south shore of the Saint Lawrence River that extends from the Matapedia Valley in Quebec, Canada, into the Gulf of Saint Lawrence. It is separated from New Brunswick o ...

, Québec,

Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...

. Gaspéite is the nickel rich member of the

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

group. A

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word ...

series exists between all members of this group with

divalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an ...

cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

s readily exchanged within the common crystal structure. It forms massive to reniform papillary

aggregate Aggregate or aggregates may refer to: Computing and mathematics * collection of objects that are bound together by a root entity, otherwise known as an aggregate root. The aggregate root guarantees the consistency of changes being made within the ...

s in fractures, botryoidal concretions in

laterite Laterite is both a soil and a rock type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by ...

or fracture infill. It is also present as stains and patinas on iron oxide boxworks of

gossan Gossan (eiserner hut or eisenhut) is intensely oxidized, weathered or decomposed rock, usually the upper and exposed part of an ore deposit or mineral vein. In the ''classic'' gossan or iron cap all that remains is iron oxides and quartz, often i ...

ous material.

Paragenesis

Gaspéite is formed in the

regolith Regolith () is a blanket of unconsolidated, loose, heterogeneous superficial deposits covering solid rock. It includes dust, broken rocks, and other related materials and is present on Earth, the Moon, Mars, some asteroids, and other terrestria ...

as a

supergene A supergene is a chromosomal region encompassing multiple neighboring genes that are inherited together because of close genetic linkage, i.e. much less recombination than would normally be expected. This mode of inheritance can be due to genomic ...

enrichment mineral of hypogene nickel sulfide minerals, generally in arid or semi-arid environments which produce conditions amenable to concentration of calcareous or carbonate minerals in the weathering profile. Gaspéite from Widgiemooltha is associated with

talc carbonate Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks. The term refers to the two most common end-member minerals found within ultramafic rocks which have undergone talc-carbonation or carbonation rea ...

komatiite Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...

-associated nickel sulfide

s and is probably formed by substitution of nickel into carbonates such as

magnesite Magnesite is a mineral with the chemical formula (magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts. Occurrence Magnesite occurs as veins in and an alteration product of ultramafic ro ...

which are formed by oxidation of the talc-carbonate lithology, and of primary and supergene nickel sulfide minerals. Gaspéite is formed from a similar process to the

weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...

of other sulfide minerals to form carbonate minerals. The sulfide minerals which are weathered to produce gaspéite are

pentlandite Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...

violarite Violarite ( Fe2+ Ni23+ S4) is a supergene sulfide mineral associated with the weathering and oxidation of primary pentlandite nickel sulfide ore minerals. Violarite crystallises in the isometric system, with a hardness of 4.5 to 5.5 and a specif ...

millerite Millerite is a nickel sulfide mineral, Ni S. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general l ...

and rarely

nickeline Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly. Small quantities of s ...

Occurrence

Gaspéite is known from a handful of locations worldwide. Aside from its type locality in Canada, gaspéite is found in the nickeliferous gossans of

Kambalda type komatiitic nickel ore deposits Kambalda type komatiitic nickel ore deposits are a class of magmatic iron-nickel-copper-platinum-group element ore deposit in which the physical processes of komatiite volcanology serve to deposit, concentrate and enrich a Fe-Ni-Cu-(PGE) sulfide ...

Kambalda Kambalda is a small mining town about from the mining city of Kalgoorlie in Western Australia, within the Goldfields. It is split into two townsites apart, Kambalda East and Kambalda West; and is located on the western edge of a giant salt ...

, and nearby Widgie Townsite, Widgiemooltha, both south of

Kalgoorlie Kalgoorlie is a city in the Goldfields–Esperance region of Western Australia, located east-northeast of Perth at the end of the Great Eastern Highway. It is sometimes referred to as Kalgoorlie–Boulder, as the surrounding urban area includ ...

, Western Australia, in both locations also associated with

garnierite Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the ...

and

kambaldaite Kambaldaite, NaNi4(CO3)3(OH)3·3H2O, is an extremely rare hydrated sodium nickel carbonate mineral described from gossanous material associated with Kambalda type komatiitic nickel ore deposits at Kambalda, Western Australia, and Widgie Townsite n ...

. Nickel carbonate, though not conclusively proven to be gaspéite, is also reported in hydrothermally altered ultramafic rocks in New South Wales, Australia, associated with

serpentinite Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...

bodies and lode gold deposits. Gaspéite is reported from the Lord Brassey Mine, Tasmania, in association with

hellyerite {{infobox mineral , name = Hellyerite , image = Hellyerite-Heazlewoodite-Zaratite-255032.jpg , imagesize = 260px , alt = , caption = Zaratite (emerald-green coating), hellyerite (powder-blue) and heazlewoodite (light b ...

Uses

Gaspéite presence in the geologic environment may be used as an ore mining indicator of nickel rich minerals nearby. Gaspéite stones are used for carving ornamental objects and animal figurines, and are also cut and polished into attractive apple green color (often veined)

cabochon A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...

s for jewelry use.

References

* * * {{Cite journal , last1=Thornber , first1=M. R. , last2=Nickel , first2=E. H. , year=1976 , title=Supergene alteration of sulphides, III. The composition of associated carbonates , journal=Chemical Geology , volume=17 , pages=45–72 , authorlink2=Ernest Henry Nickel , doi = 10.1016/0009-2541(76)90021-8 , bibcode=1976ChGeo..17...45T Nickel minerals Carbonate minerals Trigonal minerals Minerals in space group 167