silicate mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually consid ...
s that have been used since the
Bronze Age
The Bronze Age is a historic period, lasting approximately from 3300 BC to 1200 BC, characterized by the use of bronze, the presence of writing in some areas, and other early features of urban civilization. The Bronze Age is the second pri ...
as
gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
s and
abrasive
An abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away by friction. While finishing a material often means polishing it to gain a smooth, reflec ...
s.
All species of garnets possess similar physical properties and crystal forms, but differ in
chemical composition
A chemical composition specifies the identity, arrangement, and ratio of the elements making up a compound.
Chemical formulas can be used to describe the relative amounts of elements present in a compound. For example, the chemical formula for ...
. The different species are
pyrope
The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek for ''fire'' and ''e ...
,
almandine
Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
,
spessartine
Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3.Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, This mineral is sometimes mistakenly referred to as ''spessartite''.
Spessartine's name is a ...
,
grossular
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from t ...
(varieties of which are
hessonite
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from t ...
or cinnamon-stone and
tsavorite
Tsavorite or tsavolite is a variety of the garnet group species grossular, a calcium-aluminium garnet with the formula Ca3 Al2 Si3 O12.Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, Trace amounts of vanadium or chromium prov ...
),
uvarovite
Uvarovite is a chromium-bearing garnet group species with the formula: Ca3 Cr2( Si O4)3. It was discovered in 1832 by Germain Henri Hess who named it after Count Sergei Semenovitch Uvarov (1765–1855), a Russian statesman and amateur mineral co ...
and
andradite
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Andradite includes three varieties:
* ''Melanite'': Black in color, referred to as "titanian andradite".solid solution
A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word ...
series: pyrope-almandine-spessartine (pyralspite), with the composition range ; and uvarovite-grossular-andradite (ugrandite), with the composition range .
Etymology
The word ''garnet'' comes from the 14th-century
Middle English
Middle English (abbreviated to ME) is a form of the English language that was spoken after the Norman conquest of 1066, until the late 15th century. The English language underwent distinct variations and developments following the Old English p ...
word ''gernet'', meaning 'dark red'. It is borrowed from Old French ''grenate'' from
Latin
Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the ...
''granatus,'' from ''granum'' ('grain, seed'). This is possibly a reference to ''mela granatum'' or even ''pomum granatum'' ('
pomegranate
The pomegranate (''Punica granatum'') is a fruit-bearing deciduous shrub in the family Lythraceae, subfamily Punicoideae, that grows between tall.
The pomegranate was originally described throughout the Mediterranean Basin, Mediterranean re ...
', ''Punica granatum''), a plant whose fruits contain abundant and vivid red seed covers (
aril
An aril (pronounced ), also called an arillus, is a specialized outgrowth from a seed that partly or completely covers the seed. An arillode or false aril is sometimes distinguished: whereas an aril grows from the attachment point of the see ...
s), which are similar in shape, size, and color to some garnet crystals.
Physical properties
Properties
Garnet species are found in every colour, with reddish shades most common. Blue garnets are the rarest and were first reported in the 1990s.
Garnet species' light transmission properties can range from the gemstone-quality transparent specimens to the opaque varieties used for industrial purposes as abrasives. The mineral's luster is categorized as
vitreous
Vitreous may refer to:
Materials
* Glass, an amorphous solid material
** Vitreous enamel, a material made by fusing powdered glass to a substrate by firing
* Vitreous lustre, a glassy luster or sheen on a mineral surface
Biology
* Vitreous body, ...
(glass-like) or resinous (amber-like).
Crystal structure
Garnets are
nesosilicates
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually consid ...
having the general formula ''X''3''Y''2()3. The ''X'' site is usually occupied by divalent cations ( Ca, Mg, Fe, Mn)2+ and the ''Y'' site by trivalent cations ( Al, Fe, Cr)3+ in an
octahedral
In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at ea ...
/
tetrahedral
In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the o ...
framework with 4">iO4sup>4− occupying the tetrahedra. Garnets are most often found in the
dodecahedral
In geometry, a dodecahedron (Greek , from ''dōdeka'' "twelve" + ''hédra'' "base", "seat" or "face") or duodecahedron is any polyhedron with twelve flat faces. The most familiar dodecahedron is the regular dodecahedron with regular pentagon ...
crystal habit
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities due to l ...
, but are also commonly found in the
trapezohedron
In geometry, an trapezohedron, -trapezohedron, -antidipyramid, -antibipyramid, or -deltohedron is the dual polyhedron of an antiprism. The faces of an are congruent and symmetrically staggered; they are called ''twisted kites''. With a high ...
habit as well as the hexoctahedral habit. They crystallize in the
cubic
Cubic may refer to:
Science and mathematics
* Cube (algebra), "cubic" measurement
* Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex
** Cubic crystal system, a crystal system w ...
system, having three axes that are all of equal length and perpendicular to each other, but are never actually cubic because, despite being isometric, the and families of planes are depleted. Garnets do not have any cleavage planes, so when they fracture under stress, sharp, irregular (
conchoidal
Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically sli ...
) pieces are formed.
File:Pyrope cp.jpg, Crystal structure of pyrope garnet. White spheres are oxygen; black, silicon; blue, aluminium; and red, magnesium.
File:Pyrope crystal structure.jpg, Same view, with ion sizes reduced to better show all ions
File:Pyrope si.jpg, Silicon ion size exaggerated to emphasize silica tetrahedra
Hardness
Because the chemical composition of garnet varies, the atomic bonds in some species are stronger than in others. As a result, this mineral group shows a range of hardness on the
Mohs scale
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by th ...
of about 6.0 to 7.5. The harder species like
almandine
Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
are often used for abrasive purposes.
Magnetics used in garnet series identification
For gem identification purposes, a pick-up response to a strong
neodymium magnet
A hard_disk_drive.html"_;"title="Nickel-plated_neodymium_magnet_on_a_bracket_from_a_hard_disk_drive">Nickel-plated_neodymium_magnet_on_a_bracket_from_a_hard_disk_drive_
file:Nd-magnet.jpg.html" ;"title="hard_disk_drive_.html" ;"title="hard_disk_d ...
separates garnet from all other natural transparent gemstones commonly used in the jewelry trade.
Magnetic susceptibility
In electromagnetism, the magnetic susceptibility (Latin: , "receptive"; denoted ) is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization (magnetic moment per unit volume) to the ap ...
measurements in conjunction with refractive index can be used to distinguish garnet species and varieties, and determine the composition of garnets in terms of percentages of end-member species within an individual gem.
Garnet group end member species
Pyralspite garnets – aluminium in ''Y'' site
*
Almandine
Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
: Fe3Al2(SiO4)3
*
Pyrope
The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek for ''fire'' and ''e ...
: Mg3Al2(SiO4)3
*
Spessartine
Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3.Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, This mineral is sometimes mistakenly referred to as ''spessartite''.
Spessartine's name is a ...
Almandine, sometimes incorrectly called almandite, is the modern gem known as
carbuncle
A carbuncle is a cluster of boils caused by bacterial infection, most commonly with ''Staphylococcus aureus'' or ''Streptococcus pyogenes''. The presence of a carbuncle is a sign that the immune system is active and fighting the infection. The ...
(though originally almost any red gemstone was known by this name). The term "carbuncle" is derived from the
Latin
Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the ...
meaning "live coal" or burning charcoal. The name ''Almandine'' is a corruption of
Alabanda
Alabanda ( grc, Ἀλάβανδα) or Antiochia of the Chrysaorians was a city of ancient Caria, Anatolia, the site of which is near Doğanyurt, Çine, Aydın Province, Turkey.
The city is located in the saddle between two heights. The area is ...
, a region in
Asia Minor
Anatolia, tr, Anadolu Yarımadası), and the Anatolian plateau, also known as Asia Minor, is a large peninsula in Western Asia and the westernmost protrusion of the Asian continent. It constitutes the major part of modern-day Turkey. The re ...
where these stones were cut in ancient times. Chemically, almandine is an iron-aluminium garnet with the formula Fe3Al2(SiO4)3; the deep red transparent stones are often called precious garnet and are used as gemstones (being the most common of the gem garnets). Almandine occurs in
metamorphic rock
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...
s like
mica
Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
schist
Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
s, associated with minerals such as
staurolite
Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc ...
,
kyanite
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally ...
,
andalusite
Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétehrie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the spe ...
, and others. Almandine has nicknames of Oriental garnet, almandine ruby, and carbuncle.
Pyrope
Pyrope (from the Greek ''pyrōpós'' meaning "firelike") is red in color and chemically an aluminium
silicate
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
with the formula Mg3Al2(SiO4)3, though the magnesium can be replaced in part by calcium and ferrous iron. The color of pyrope varies from deep red to black. Pyrope and spessartine gemstones have been recovered from the Sloan diamondiferous
kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
s in
Colorado
Colorado (, other variants) is a state in the Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the western edge of t ...
, from the Bishop Conglomerate and in a Tertiary age
lamprophyre
Lamprophyres () are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxid ...
at Cedar Mountain in
Wyoming
Wyoming () is a U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the south ...
North Carolina
North Carolina () is a state in the Southeastern region of the United States. The state is the 28th largest and 9th-most populous of the United States. It is bordered by Virginia to the north, the Atlantic Ocean to the east, Georgia and So ...
is a violet-red shade and has been called ''rhodolite'', Greek for "rose". In chemical composition it may be considered as essentially an isomorphous mixture of pyrope and almandine, in the proportion of two parts pyrope to one part almandine. Pyrope has tradenames some of which are
misnomer
A misnomer is a name that is incorrectly or unsuitably applied. Misnomers often arise because something was named long before its correct nature was known, or because an earlier form of something has been replaced by a later form to which the name ...
s; ''Cape ruby'', ''Arizona ruby'', ''California ruby'', ''Rocky Mountain ruby'', and ''Bohemian ruby'' from the
Czech Republic
The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
.
Pyrope
The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek for ''fire'' and ''e ...
is an indicator mineral for high-pressure rocks.
Mantle
A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that.
Mantle may refer to:
*Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear
**Mantle (vesture), an Eastern Orthodox ve ...
-derived rocks (
peridotite
Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
s and
eclogite
Eclogite () is a metamorphic rock containing garnet (almandine-pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisite, dol ...
s) commonly contain a pyrope variety.
Spessartine
Spessartine or spessartite is manganese aluminium garnet, Mn3Al2(SiO4)3. Its name is derived from
Spessart
Spessart is a ''Mittelgebirge'', a range of low wooded mountains, in the States of Bavaria and Hesse in Germany. It is bordered by the Vogelsberg, Rhön and Odenwald. The highest elevation is the Geiersberg at 586 metres above sea level.
Etymo ...
in
Bavaria
Bavaria ( ; ), officially the Free State of Bavaria (german: Freistaat Bayern, link=no ), is a state in the south-east of Germany. With an area of , Bavaria is the largest German state by land area, comprising roughly a fifth of the total lan ...
. It occurs most often in
skarn
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals ...
s,
granite
Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
and allied rock types, and in certain low grade metamorphic
phyllite
Phyllite ( ) is a type of foliated metamorphic rock created from slate that is further metamorphosed so that very fine grained white mica achieves a preferred orientation.Stephen Marshak ''Essentials of Geology'', 3rd ed. It is primarily compo ...
s. Spessartine of an
orange
Orange most often refers to:
*Orange (fruit), the fruit of the tree species '' Citrus'' × ''sinensis''
** Orange blossom, its fragrant flower
*Orange (colour), from the color of an orange, occurs between red and yellow in the visible spectrum
* ...
-yellow is found in Madagascar. Violet-red spessartines are found in
rhyolite
Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
s in
Colorado
Colorado (, other variants) is a state in the Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the western edge of t ...
Pyrope–spessartine (blue garnet or color-change garnet)
Blue pyrope–spessartine garnets were discovered in the late 1990s in Bekily,
Madagascar
Madagascar (; mg, Madagasikara, ), officially the Republic of Madagascar ( mg, Repoblikan'i Madagasikara, links=no, ; french: République de Madagascar), is an island country in the Indian Ocean, approximately off the coast of East Africa ...
. This type has also been found in parts of the
United States
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
,
Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
,
Kenya
)
, national_anthem = "Ee Mungu Nguvu Yetu"()
, image_map =
, map_caption =
, image_map2 =
, capital = Nairobi
, coordinates =
, largest_city = Nairobi
, ...
,
Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
, and
Turkey
Turkey ( tr, Türkiye ), officially the Republic of Türkiye ( tr, Türkiye Cumhuriyeti, links=no ), is a list of transcontinental countries, transcontinental country located mainly on the Anatolia, Anatolian Peninsula in Western Asia, with ...
. It changes color from blue-green to purple depending on the
color temperature
Color temperature is the color of light emitted by an idealized opaque, non-reflective body at a particular temperature measured in kelvins. The color temperature scale is used to categorize the color of light emitted by other light sources ...
of viewing light, as a result of the relatively high amounts of
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
(about 1 wt.% V2O3).
Other varieties of color-changing garnets exist. In daylight, their color ranges from shades of green, beige, brown, gray, and blue, but in incandescent light, they appear a reddish or purplish/pink color.
This is the rarest type of garnet. Because of its color-changing quality, this kind of garnet resembles
alexandrite
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
.
Ugrandite group – calcium in ''X'' site
*
Andradite
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Andradite includes three varieties:
* ''Melanite'': Black in color, referred to as "titanian andradite".Grossular
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from t ...
: Ca3Al2(SiO4)3
*
Uvarovite
Uvarovite is a chromium-bearing garnet group species with the formula: Ca3 Cr2( Si O4)3. It was discovered in 1832 by Germain Henri Hess who named it after Count Sergei Semenovitch Uvarov (1765–1855), a Russian statesman and amateur mineral co ...
: Ca3Cr2(SiO4)3
Andradite
Andradite is a calcium-iron garnet, Ca3Fe2(SiO4)3, is of variable composition and may be red, yellow, brown, green or black. The recognized varieties are
demantoid
Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of Minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the dema ...
(green),
melanite
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Andradite includes three varieties:
* ''Melanite'': Black in color, referred to as "titanian andradite". and topazolite (yellow or green). Andradite is found in
skarn
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals ...
s and in deep-seated
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s like
syenite
Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proport ...
as well as serpentines and
greenschist
Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
s. Demantoid is one of the most prized of garnet varieties.
Grossular
Grossular is a calcium-aluminium garnet with the formula Ca3Al2(SiO4)3, though the calcium may in part be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the
botanical
Botany, also called , plant biology or phytology, is the science of plant life and a branch of biology. A botanist, plant scientist or phytologist is a scientist who specialises in this field. The term "botany" comes from the Ancient Greek wo ...
name for the
gooseberry
Gooseberry ( or (American and northern British) or (southern British)) is a common name for many species of ''Ribes'' (which also includes currants), as well as a large number of plants of similar appearance. The berries of those in the genu ...
, ''grossularia'', in reference to the green garnet of this composition that is found in
Siberia
Siberia ( ; rus, Сибирь, r=Sibir', p=sʲɪˈbʲirʲ, a=Ru-Сибирь.ogg) is an extensive geographical region, constituting all of North Asia, from the Ural Mountains in the west to the Pacific Ocean in the east. It has been a part of ...
. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Because of its inferior hardness to
zircon
Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the r ...
, which the yellow crystals resemble, they have also been called ''hessonite'' from the
Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
meaning inferior. Grossular is found in skarns, contact metamorphosed
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
s with
vesuvianite
Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within ...
,
diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
,
wollastonite
Wollastonite is a calcium inosilicate mineral ( Ca Si O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature a ...
and
wernerite
The scapolites (Gr. σκάπος, rod, and λίθος, stone) are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite () and marialit ...
.
Grossular garnet from
Kenya
)
, national_anthem = "Ee Mungu Nguvu Yetu"()
, image_map =
, map_caption =
, image_map2 =
, capital = Nairobi
, coordinates =
, largest_city = Nairobi
, ...
and
Tanzania
Tanzania (; ), officially the United Republic of Tanzania ( sw, Jamhuri ya Muungano wa Tanzania), is a country in East Africa within the African Great Lakes region. It borders Uganda to the north; Kenya to the northeast; Comoro Islands and ...
has been called tsavorite. Tsavorite was first described in the 1960s in the
Tsavo
Tsavo is a region of Kenya located at the crossing of the Uganda Railway over the Tsavo River, close to where it meets the Athi-Galana-Sabaki River. Two national parks, Tsavo East and Tsavo West are located in the area.
The meaning of the wor ...
area of Kenya, from which the gem takes its name.
Uvarovite
Uvarovite is a calcium chromium garnet with the formula Ca3Cr2(SiO4)3. This is a rather rare garnet, bright green in color, usually found as small crystals associated with
chromite
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can s ...
in
peridotite
Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
,
serpentinite
Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...
, and kimberlites. It is found in crystalline
marble
Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the ...
s and schists in the
Ural mountains
The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through western ...
of Russia and
Outokumpu, Finland
Outokumpu is a town and municipality of Finland. It is located in the North Karelia region, west of Joensuu and east of Kuopio. The municipality has a population of () and covers an area of of which is water. The population density is . The ...
. Uvarovite is named for Count Uvaro, a Russian imperial statesman.
Less common species
*Calcium in ''X'' site
**
Goldmanite
Goldmanite is a green or greenish-brown silicate mineral of the garnet group with a chemical formula of .
Discovery
It was first described in 1964 for an occurrence in the Laguna District, Cibola County, New Mexico and is named after Marcus Isaa ...
:
**Kimzeyite:
**Morimotoite:
**Schorlomite:
*Hydroxide bearing – calcium in ''X'' site
**
Hydrogrossular
Hydrogrossular is a calcium aluminium garnet series (formula: Ca3Al2(SiO4)3−''x''(OH)4''x'', with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (grossular, hibschite, and katoite) depend on the deg ...
:
***Hibschite: (where x is between 0.2 and 1.5)
***Katoite: (where x is greater than 1.5)
*Magnesium or manganese in ''X'' site
**
Knorringite
Knorringite is a mineral species belonging to the garnet group, and forms a series with the species pyrope. It was discovered in 1968 in the Kao kimberlite pipe in the Butha-Buthe District of Lesotho and is named after Oleg Von Knorring, a profess ...
:
**
Majorite
Majorite is a type of garnet mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is distinguished from other garnets in having Si in octahedral as well as tetrahedral coordination. Majorite was first described ...
:
**
Calderite
Calderite is a mineral in the garnet group with the chemical formula ( Mn2+, Ca)3( Fe3+, Al)2( Si O4)3.
It is dark reddish brown to dark yellowish in color and generally granular massive in form.
It was named for geologist James Calder who w ...
:
Knorringite
Knorringite is a magnesium-chromium garnet species with the formula Mg3Cr2(SiO4)3. Pure
endmember
An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of ...
knorringite never occurs in nature. Pyrope rich in the knorringite component is only formed under high pressure and is often found in
kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
s. It is used as an indicator mineral in the search for
diamond
Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
s.
Garnet structural group
*Formula: X3Z2(TO4)3 (X = Ca, Fe, etc., Z = Al, Cr, etc., T = Si, As, V, Fe, Al)
**All are cubic or strongly pseudocubic.
*IMA/CNMNC – Nickel-Strunz – Mineral subclass: 09.A Nesosilicate
** Nickel-Strunz classification: 09.AD.25
*References:
Mindat.org
Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ...
; mineral name, chemical formula and space group (American Mineralogist Crystal Structure Database) of the IMA Database of Mineral Properties/ RRUFF Project, Univ. of Arizona, was preferred most of the time. Minor components in formulae have been left out to highlight the dominant chemical endmember that defines each species.
Synthetic garnets
Also known as rare-earth garnets.
The crystallographic structure of garnets has been expanded from the prototype to include chemicals with the general formula ''A''3''B''2(''C''O4)3. Besides silicon, a large number of elements have been put on the ''C'' site, including
germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
,
gallium
Gallium is a chemical element with the symbol Ga and atomic number 31. Discovered by French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in group 13 of the periodic table and is similar to the other metals of the group (aluminiu ...
,
aluminum
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has ...
,
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
and
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
.
Yttrium aluminium garnet
Yttrium aluminium garnet (YAG, Y3 Al5 O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and ...
(YAG), Y3Al2(AlO4)3, is used for
synthetic Synthetic things are composed of multiple parts, often with the implication that they are artificial. In particular, 'synthetic' may refer to:
Science
* Synthetic chemical or compound, produced by the process of chemical synthesis
* Synthetic o ...
gemstones. Due to its fairly high refractive index, YAG was used as a diamond simulant in the 1970s until the methods of producing the more advanced simulant
cubic zirconia
Cubic zirconia (CZ) is the cubic crystalline form of zirconium dioxide (ZrO2). The synthesized material is hard and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zirconi ...
in commercial quantities were developed. When doped with
neodymium
Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes i ...
(Nd3+), YAG may be used as the
lasing medium
The active laser medium (also called gain medium or lasing medium) is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from a ...
erbium
Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element
...
, it can be used as the lasing medium in Er:YAG lasers. When doped with
gadolinium
Gadolinium is a chemical element with the symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is only slightly malleable and is a ductile rare-earth element. Gadolinium reacts with atmospheric oxygen ...
, it can be used as the lasing medium in Gd:YAG lasers. These doped YAG lasers are used in medical procedures including
laser skin resurfacing
Photorejuvenation is a skin treatment that uses lasers, intense pulsed light, or photodynamic therapy to treat skin conditions and remove effects of photoaging such as wrinkles, spots, and textures. The process induces controlled wounds to the ski ...
, dentistry, and ophthalmology.
Interesting magnetic properties arise when the appropriate elements are used. In
yttrium iron garnet
Yttrium iron garnet (YIG) is a kind of synthetic garnet, with chemical composition , or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 560 K. YIG may also be known as yttrium ferrite garnet, or as iron yttrium oxide or ...
(YIG), Y3Fe2(FeO4)3, the five iron(III) ions occupy two
octahedral
In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at ea ...
and three
tetrahedral
In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the o ...
sites, with the yttrium(III) ions coordinated by eight oxygen ions in an irregular cube. The iron ions in the two coordination sites exhibit different
spins
The spins (as in having "the spins")Diane Marie Leiva. ''The Florida State University College of Education''Women's Voices on College Drinking: The First-Year College Experience"/ref> is an adverse reaction of intoxication that causes a state of v ...
, resulting in
magnetic
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particle ...
behavior. YIG is a
ferrimagnetic
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when t ...
material having a
Curie temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...
YIG sphere
Yttrium iron garnet spheres (YIG spheres) serve as magnetically tunable filters and resonators for microwave frequencies. YIG filters are used for their high Q factors, typically between 100 and 200. A sphere made from a single crystal of synth ...
s, which serve as magnetically tunable
filters
Filter, filtering or filters may refer to:
Science and technology
Computing
* Filter (higher-order function), in functional programming
* Filter (software), a computer program to process a data stream
* Filter (video), a software component tha ...
and
resonators
A resonator is a device or system that exhibits resonance or resonant behavior. That is, it naturally oscillates with greater amplitude at some frequencies, called resonant frequencies, than at other frequencies. The oscillations in a resonator ...
for
microwave
Microwave is a form of electromagnetic radiation with wavelengths ranging from about one meter to one millimeter corresponding to frequencies between 300 MHz and 300 GHz respectively. Different sources define different frequency ran ...
frequencies.
Lutetium aluminium garnet (LuAG), , is an inorganic compound with a unique crystal structure primarily known for its use in high-efficiency laser devices. LuAG is also useful in the synthesis of
transparent ceramics
Many ceramic materials, both glassy and crystalline, have found use as optically transparent materials in various forms from bulk solid-state components to high surface area forms such as thin films, coatings, and fibers. Such devices have found ...
. LuAG is particularly favored over other crystals for its high density and thermal conductivity; it has a relatively small
lattice constant
A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has o ...
in comparison to the other
rare-earth
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
garnets, which results in a higher density producing a crystal field with narrower linewidths and greater energy level splitting in absorption and emission.
Terbium gallium garnet (TGG), , is a
Faraday rotator
A Faraday rotator is a polarization rotator based on the Faraday effect, a magneto-optic effect involving transmission of light through a material when a longitudinal static magnetic field is present. The state of polarization (such as the axis of ...
material with excellent transparency properties and is very resistant to laser damage. TGG can be used in
optical isolator
An optical isolator, or optical diode, is an optical component which allows the transmission of light in only one direction. It is typically used to prevent unwanted feedback into an optical oscillator, such as a laser cavity.
The operation of ...
s for laser systems, in
optical circulator
An optical circulator is a three- or four-port optical device designed such that light entering any port exits from the next. This means that if light enters port 1 it is emitted from port 2, but if some of the emitted light is reflected back to t ...
s for fiber optic systems, in
optical modulator
An optical modulator is a device which is used to modulate a beam of light. The beam may be carried over free space, or propagated through an optical waveguide ( optical fibre). Depending on the parameter of a light beam which is manipulated, mod ...
s, and in current and
magnetic field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
sensors.
Another example is gadolinium gallium garnet (GGG), which is synthesized for use as a substrate for liquid-phase epitaxy of magnetic garnet films for
bubble memory
Bubble memory is a type of non-volatile computer memory that uses a thin film of a magnetic material to hold small magnetized areas, known as ''bubbles'' or ''domains'', each storing one bit of data. The material is arranged to form a series o ...
and
magneto-optical
A magneto-optical drive is a kind of optical disc drive capable of writing and rewriting data upon a magneto-optical disc. Both 130 mm (5.25 in) and 90 mm (3.5 in) form factors exist. In 1983, just a year after the introduc ...
applications.
Geological importance
The mineral garnet is commonly found in metamorphic and to a lesser extent, igneous rocks. Most natural garnets are compositionally zoned and contain inclusions. Its crystal lattice structure is stable at high pressures and temperatures and is thus found in green-schist facies metamorphic rocks including
gneiss
Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures an ...
, hornblende
schist
Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
, and mica schist. The composition that is stable at the pressure and temperature conditions of Earth's mantle is pyrope, which is often found in
peridotites
Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
and
kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
s, as well as the serpentines that form from them. Garnets are unique in that they can record the pressures and temperatures of peak metamorphism and are used as geobarometers and geothermometers in the study of
geothermobarometry
Geothermobarometry is the science of measuring the previous pressure and temperature history of a metamorphic or intrusive igneous rocks. Geothermobarometry is a combination of ''geobarometry'', where a pressure of mineral formation is resolved, an ...
which determines "P-T Paths", Pressure-Temperature Paths. Garnets are used as an index mineral in the delineation of
isograd
__NOTOC__
An isograd is a concept used in the study of metamorphic rocks. The metamorphic grade of such a rock is a rough measure of the degree of metamorphism it has undergone, as characterised by the presence of certain index minerals. An isograd ...
s in metamorphic rocks. Compositional zoning and inclusions can mark the change from growth of the crystals at low temperatures to higher temperatures. Garnets that are not compositionally zoned more than likely experienced ultra high temperatures (above 700 °C) that led to diffusion of major elements within the crystal lattice, effectively homogenizing the crystal or they were never zoned. Garnets can also form metamorphic textures that can help interpret structural histories.
In addition to being used to devolve conditions of metamorphism, garnets can be used to date certain geologic events. Garnet has been developed as a U-Pb geochronometer, to date the age of crystallization as well as a thermochronometer in the (U-Th)/He system to date timing of cooling below a
closure temperature
In radiometric dating, closure temperature or blocking temperature refers to the temperature of a system, such as a mineral, at the time given by its radiometric date. In physical terms, the closure temperature is the temperature at which a syste ...
.
Garnets can be chemically altered and most often alter to serpentine,
talc
Talc, or talcum, is a Clay minerals, clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thi ...
, and
chlorite
The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
.
Uses
Gemstones
Red garnets were the most commonly used gemstones in the
Late Antique
Late antiquity is the time of transition from classical antiquity to the Middle Ages, generally spanning the 3rd–7th century in Europe and adjacent areas bordering the Mediterranean Basin. The popularization of this periodization in English has ...
Roman
Roman or Romans most often refers to:
*Rome, the capital city of Italy
*Ancient Rome, Roman civilization from 8th century BC to 5th century AD
*Roman people, the people of ancient Rome
*''Epistle to the Romans'', shortened to ''Romans'', a letter ...
world, and the
Migration Period art
Migration Period art denotes the artwork of the Germanic peoples during the Migration period (c. 300 – 900). It includes the Migration art of the Germanic tribes on the continent, as well the start of the Insular art or Hiberno-Saxon art of th ...
of the "
barbarian
A barbarian (or savage) is someone who is perceived to be either Civilization, uncivilized or primitive. The designation is usually applied as a generalization based on a popular stereotype; barbarians can be members of any nation judged by som ...
" peoples who took over the territory of the
Western Roman Empire
The Western Roman Empire comprised the western provinces of the Roman Empire at any time during which they were administered by a separate independent Imperial court; in particular, this term is used in historiography to describe the period fr ...
. They were especially used inlaid in gold cells in the
cloisonné
Cloisonné () is an ancient technique for decorating metalwork objects with colored material held in place or separated by metal strips or wire, normally of gold. In recent centuries, vitreous enamel has been used, but inlays of cut gemstones, ...
technique, a style often just called garnet cloisonné, found from
Anglo-Saxon
The Anglo-Saxons were a Cultural identity, cultural group who inhabited England in the Early Middle Ages. They traced their origins to settlers who came to Britain from mainland Europe in the 5th century. However, the ethnogenesis of the Anglo- ...
England, as at
Sutton Hoo
Sutton Hoo is the site of two early medieval cemeteries dating from the 6th to 7th centuries near the English town of Woodbridge. Archaeologists have been excavating the area since 1938, when a previously undisturbed ship burial containing a ...
, to the
Black Sea
The Black Sea is a marginal mediterranean sea of the Atlantic Ocean lying between Europe and Asia, east of the Balkans, south of the East European Plain, west of the Caucasus, and north of Anatolia. It is bounded by Bulgaria, Georgia, Roma ...
. Thousands of Tamraparniyan gold, silver and red garnet shipments were made in the
old world
The "Old World" is a term for Afro-Eurasia that originated in Europe , after Europeans became aware of the existence of the Americas. It is used to contrast the continents of Africa, Europe, and Asia, which were previously thought of by the ...
, including to Rome, Greece, the Middle East,
Serica
Serica (, grc, Σηρικά) was one of the easternmost countries of Asia known to the Ancient Greek and Roman geographers. It is generally taken as referring to North China
North China, or Huabei () is a List of regions of China, geogr ...
and Anglo Saxons; recent findings such as the Staffordshire Hoard and the pendant of the
Winfarthing
Winfarthing is a village and civil parish in the English county of Norfolk. It is located 6 km north of the town of Diss, 20 km east of the town of Thetford, and 30 km south of the city of Norwich.
The civil parish has an area of and in the ...
Woman skeleton of
Norfolk
Norfolk () is a ceremonial and non-metropolitan county in East Anglia in England. It borders Lincolnshire to the north-west, Cambridgeshire to the west and south-west, and Suffolk to the south. Its northern and eastern boundaries are the No ...
confirm an established gem trade route with
South India
South India, also known as Dakshina Bharata or Peninsular India, consists of the peninsular southern part of India. It encompasses the Indian states of Andhra Pradesh, Karnataka, Kerala, Tamil Nadu, and Telangana, as well as the union territo ...
and
Tamraparni
Tamraparni (Sanskrit for "with copper leaves" or "red-leaved") is an older name for multiple distinct places, including Sri Lanka, Tirunelveli in India, and the Thamirabarani River that flows through Tirunelveli.
As a name for Sri Lanka
The r ...
(ancient
Sri Lanka
Sri Lanka (, ; si, ශ්රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
), known from antiquity for its production of gemstones.
Pure crystals of garnet are still used as gemstones. The gemstone varieties occur in shades of green, red, yellow, and orange. In the US it is known as the
birthstone
A birthstone is a gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
for January.
Gemological Institute of America
The Gemological Institute of America (GIA) is a nonprofit institute based in Carlsbad, California. It is dedicated to research and education in the field of gemology and the jewelry arts. Founded in 1931, GIA's mission is to protect buyers and ...
, ''GIA Gem Reference Guide'' 1995, The garnet family is one of the most complex in the gem world. It is not a single species, but is composed of multiple species and varieties. It is the
state mineral
Leaders of states in the U.S. which have significant mineral deposits often create a state mineral, rock, stone or gemstone to promote interest in their natural resources, history, tourism, etc. Not every state has an official state mineral, rock, ...
of
Connecticut
Connecticut () is the southernmost state in the New England region of the Northeastern United States. It is bordered by Rhode Island to the east, Massachusetts to the north, New York to the west, and Long Island Sound to the south. Its cap ...
, New York's gemstone, and star garnet (garnet with
rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
asterisms) is the state gemstone of
Idaho
Idaho ( ) is a state in the Pacific Northwest region of the Western United States. To the north, it shares a small portion of the Canada–United States border with the province of British Columbia. It borders the states of Montana and Wyom ...
.
Industrial uses
Garnet sand is a good
abrasive
An abrasive is a material, often a mineral, that is used to shape or finish a workpiece through rubbing which leads to part of the workpiece being worn away by friction. While finishing a material often means polishing it to gain a smooth, reflec ...
, and a common replacement for silica sand in sand blasting. Alluvial garnet grains which are rounder are more suitable for such blasting treatments. Mixed with very high pressure water, garnet is used to cut
steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
and other materials in water jets. For water jet cutting, garnet extracted from hard rock is suitable since it is more angular in form, therefore more efficient in cutting.
Garnet paper is favored by cabinetmakers for finishing bare wood.
Garnet sand is also used for
water filtration
A water filter removes impurities by lowering contamination of water using a fine physical barrier, a chemical process, or a biological process. Filters cleanse water to different extents, for purposes such as: providing agricultural irrigation ...
media.
As an abrasive, garnet can be broadly divided into two categories; blasting grade and water jet grade. The garnet, as it is mined and collected, is crushed to finer grains; all pieces which are larger than 60 mesh (250 micrometers) are normally used for sand blasting. The pieces between 60 mesh (250 micrometers) and 200 mesh (74 micrometers) are normally used for water jet cutting. The remaining garnet pieces that are finer than 200 mesh (74 micrometers) are used for glass polishing and lapping. Regardless of the application, the larger grain sizes are used for faster work and the smaller ones are used for finer finishes.
There are different kinds of abrasive garnets which can be divided based on their origin. The largest source of abrasive garnet today is garnet-rich beach sand which is quite abundant on
India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
n and
Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
n coasts and the main producers today are Australia and India.
This material is particularly popular due to its consistent supplies, huge quantities and clean material. The common problems with this material are the presence of ilmenite and chloride compounds. Since the material has been naturally crushed and ground on the beaches for past centuries, the material is normally available in fine sizes only. Most of the garnet at the
Tuticorin
Thoothukudi (formerly Tuticorin) is a port city, a municipal corporation and an industrial city in Thoothukudi district in the Indian state of Tamil Nadu. The city lies in the Coromandel Coast of Bay of Bengal. Thoothukudi is the capital and he ...
beach in south India is 80 mesh, and ranges from 56 mesh to 100 mesh size.
''River garnet'' is particularly abundant in Australia. The river sand garnet occurs as a
placer deposit
In geology, a placer deposit or placer is an accumulation of valuable minerals formed by gravity separation from a specific source rock during sedimentary processes. The name is from the Spanish word ''placer'', meaning "alluvial sand". Placer min ...
.
''Rock garnet'' is perhaps the garnet type used for the longest period of time. This type of garnet is produced in America, China and western India. These crystals are crushed in mills and then purified by wind blowing, magnetic separation, sieving and, if required, washing. Being freshly crushed, this garnet has the sharpest edges and therefore performs far better than other kinds of garnet. Both the river and the beach garnet suffer from the tumbling effect of hundreds of thousands of years which rounds off the edges.
Gore Mountain Garnet
Gore Mountain Garnet, found in the Adirondack Mountains in New York, contains the world's largest garnets. The rock that holds these garnets, garnet amphibolite, is sometimes referred to as 'black ore' or 'dark ore.' This rock formation formed d ...
from
Warren County, New York
Warren County is a county in the U.S. state of New York. As of the 2020 census, the population was 65,737. The county seat is Queensbury. The county is named in honor of General Joseph Warren, an American Revolutionary War hero of the Battl ...
, USA is a significant source of rock garnet for use as an industrial abrasive.
Cultural significance
Garnet is the
birthstone
A birthstone is a gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
of January. It is also the birthstone of
Aquarius
Aquarius may refer to:
Astrology
* Aquarius (astrology), an astrological sign
* Age of Aquarius, a time period in the cycle of astrological ages
Astronomy
* Aquarius (constellation)
* Aquarius in Chinese astronomy
Arts and entertainment ...
tropical astrology
The tropics are the regions of Earth surrounding the Equator. They are defined in latitude by the Tropic of Cancer in the Northern Hemisphere at N and the Tropic of Capricorn in
the Southern Hemisphere at S. The tropics are also referred to ...
.
In Persia this birth gem was considered a talisman from nature's forces like storm and lightning. It was widely accepted that garnet could signal approaching danger by turning pale.
Connecticut
Connecticut () is the southernmost state in the New England region of the Northeastern United States. It is bordered by Rhode Island to the east, Massachusetts to the north, New York to the west, and Long Island Sound to the south. Its cap ...
has
almandine
Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
garnet as its state gemstone,
Idaho
Idaho ( ) is a state in the Pacific Northwest region of the Western United States. To the north, it shares a small portion of the Canada–United States border with the province of British Columbia. It borders the states of Montana and Wyom ...
has star garnet as its state gemstone, and
Vermont
Vermont () is a state in the northeast New England region of the United States. Vermont is bordered by the states of Massachusetts to the south, New Hampshire to the east, and New York to the west, and the Canadian province of Quebec to ...
has
grossular
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from t ...
garnet as its state gemstone.
Since 2003 New York State has ranked first in industrial garnet-production in the United States. Since there are just a few companies that account for all U.S. industrial garnet production, published detailed production statistics for New York State are not available. However, generally speaking, Barton Mines in Warren County is the largest U.S. garnet producer.
Collections
The New York State Museum in Albany, NY houses specimens from significant sites across the state, including 93 mineral species from the Balmat-Edwards mining district in St. Lawrence, super garnets from the Barton Mine in the Adirondack Mountains, and Herkimer diamonds from Herkimer County, New York
Oldest garnet mine
The largest garnet mine in the world is located Near North Creek New York and is operated by Barton Mines Corporation who supplies about 90% of the world's garnet.
Barton Mines Corporation is the first and oldest industrial garnet mining operation in the world and the second oldest continuous mining operation in the United States under the same management and mining the same product throughout its history. The Gore Mountain Mine of the Barton Mines Corporation was first mined under the direction of H. H. Barton, Sr. in 1878 to produce garnet as the primary product.
Largest garnet crystal
The open-pit Barton Garnet Mine, located at Gore Mountain in the Adirondack Highlands, yields the world's largest single crystals of garnet; diameters range from 5 to 35 cm and commonly average 10–18 cm.
Gore Mountain garnets are unique in many respects, and considerable effort has been made to determine the timing of garnet growth. The first dating was that of Basu et al. (1989), who used plagioclase-hornblende-garnet to produce a Sm/Nd isochron that yielded an age of 1059 ± 19 Ma. Mezger et al. (1992) conducted their own Sm/Nd investigation using hornblende and the drilled core of a 50 cm garnet to produce an isochron age of 1051 ± 4 Ma. Connelly (2006) utilized 7 different fractions of a Gore Mountain garnet to obtain a Lu-Hf isochron age of 1046.6 ± 6 Ma. We therefore conclude with confidence that the garnets formed at 1049 ± 5 Ma, the average of the three determinations. This is also the local age of peak metamorphism in the 1090–1040 Ma Ottawan phase of the Grenvillian orogeny and serves as a critical data point in ascertaining the evolution of the megacrystic garnet deposits.
See also
*
Abrasive blasting
Sandblasting, sometimes known as abrasive blasting, is the operation of forcibly propelling a stream of abrasive material against a surface under high pressure to smooth a rough surface, roughen a smooth surface, shape a surface or remove su ...
References
Further reading
* Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., Wiley,
* ''Color Encyclopedia of Gemstones'',
External links
*http://www.gemstonemagnetism.com contains a comprehensive section about garnets and garnet magnetism. USGS Garnet locations – USA *http://gemstone.org/education/gem-by-gem/154-garnet
*http://www.mindat.org/min-10272.html
Blog post on garnets on the
Law Library of Congress
The Law Library of Congress is the law library of the United States Congress. The Law Library of Congress holds the single most comprehensive and authoritative collection of domestic, foreign, and international legal materials in the world. Est ...