Frederick Soddy

Frederick Soddy FRS (2 September 1877 – 22 September 1956) was an English radiochemist who explained, with Ernest Rutherford, that radioactivity is due to the transmutation of elements, now known to involve nuclear reactions. He also proved the existence of isotopes of certain radioactive elements. In 1921 he received the Nobel Prize in Chemistry "for his contributions to our knowledge of the chemistry of radioactive substances, and his investigations into the origin and nature of isotopes". Soddy was a polymath who mastered chemistry, nuclear physics, statistical mechanics, finance and economics.

Biography

Soddy was born at 6 Bolton Road, Eastbourne, England, the son of Benjamin Soddy, corn merchant, and his wife Hannah Green. He went to school at Eastbourne College, before going on to study at University College of Wales at Aberystwyth and at Merton College, Oxford, where he graduated in 1898 with first class honours in chemistry. He was a researcher at Oxford from 1898 to 1900.

Scientific career

In 1900 he became a demonstrator in chemistry at McGill University in Montreal, Quebec, where he worked with Ernest Rutherford on radioactivity.
He and Rutherford realized that the anomalous behaviour of radioactive elements was because they decayed into other elements.
This decay also produced alpha, beta, and gamma radiation. When radioactivity was first discovered, no one was sure what the cause was. It needed careful work by Soddy and Rutherford to prove that atomic transmutation was in fact occurring.

In 1903, with Sir William Ramsay at University College London, Soddy showed that the decay of radium produced helium gas. In the experiment a sample of radium was enclosed in a thin-walled glass envelope sited within an evacuated glass bulb. After leaving the experiment running for a long period of time, a spectral analysis of the contents of the former evacuated space revealed the presence of helium. Later in 1907, Rutherford and Thomas Royds showed that the helium was first formed as positively charged nuclei of helium (He²⁺) which were identical to alpha particles, which could pass through the thin glass wall but were contained within the surrounding glass envelope.

From 1904 to 1914, Soddy was a lecturer at the University of Glasgow. Ruth Pirret worked as his research assistant during this time. In May 1910 Soddy was elected a Fellow of the Royal Society. In 1914 he was appointed to a chair at the University of Aberdeen, where he worked on research related to World War I.

In 1913, Soddy showed that an atom moves lower in atomic number by two places on alpha emission, higher by one place on beta emission. This was discovered at about the same time by Kazimierz Fajans, and is known as the radioactive displacement law of Fajans and Soddy, a fundamental step toward understanding the relationships among families of radioactive elements. In 1913 Soddy also described the phenomenon in which a radioactive element may have more than one atomic mass though the chemical properties are identical. He named this concept isotope meaning "same place". The word was initially suggested to him by Margaret Todd. Later, J. J. Thomson showed that non-radioactive elements can also have multiple isotopes.

The work that Soddy and his research assistant Ada Hitchins did at Glasgow and Aberdeen showed that uranium decays to radium.

Soddy published ''The Interpretation of Radium'' (1909) and ''Atomic Transmutation'' (1953).

In 1918 working with John Arnold Cranston, he announced the discovery of an isotope of the element later named protactinium. This slightly post-dated its discovery by the Germans Lise Meitner and Otto Hahn; however, it is said their discovery was actually made in 1915 but its announcement was delayed due to Cranston's notes being locked away whilst on active service in the First World War.

In 1919 he moved to the University of Oxford as the first Dr. Lee's Professor of Chemistry, where, in the period up till 1936, he reorganized the laboratories and the syllabus in chemistry. He received the 1921 Nobel Prize in chemistry for his research in radioactive decay and particularly for his formulation of the theory of isotopes.

His work and essays popularising the new understanding of radioactivity was the main inspiration for H. G. Wells