The elementary charge, usually denoted by is the
electric charge
Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respecti ...
carried by a single
proton or, equivalently, the magnitude of the negative electric charge carried by a single
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary partic ...
, which has charge −1 . This elementary charge is a fundamental
physical constant
A physical constant, sometimes fundamental physical constant or universal constant, is a physical quantity that is generally believed to be both universal in nature and have constant value in time. It is contrasted with a mathematical constant, ...
.
In the
SI system of units
The International System of Units, known by the international abbreviation SI in all languages and sometimes pleonastically as the SI system, is the modern form of the metric system and the world's most widely used system of measurement. E ...
, the value of the elementary charge is exactly defined as
=
coulomb
The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI).
In the present version of the SI it is equal to the electric charge delivered by a 1 ampere constant current in 1 second and to elementary ch ...
s, or 160.2176634
zepto
A metric prefix is a unit prefix that precedes a basic unit of measure to indicate a multiple or submultiple of the unit. All metric prefixes used today are decadic. Each prefix has a unique symbol that is prepended to any unit symbol. The pre ...
coulombs (zC).
Since the
2019 redefinition of SI base units
In 2019, four of the seven SI base units specified in the International System of Quantities were redefined in terms of natural physical constants, rather than human artifacts such as the standard kilogram.
Effective 20 May 2019, the 144th ...
, the seven
SI base unit
The SI base units are the standard units of measurement defined by the International System of Units (SI) for the seven base quantities of what is now known as the International System of Quantities: they are notably a basic set from which all ...
s are defined by seven fundamental physical constants, of which the elementary charge is one.
In the
centimetre–gram–second system of units
The centimetre–gram–second system of units (abbreviated CGS or cgs) is a variant of the metric system based on the centimetre as the unit of length, the gram as the unit of mass, and the second as the unit of time. All CGS mechanical un ...
(CGS), the corresponding quantity is .
Robert A. Millikan and
Harvey Fletcher's
oil drop experiment first directly measured the magnitude of the elementary charge in 1909, differing from the modern accepted value by just 0.6%. Under assumptions of the then-disputed
atomic theory
Atomic theory is the scientific theory that matter is composed of particles called atoms. Atomic theory traces its origins to an ancient philosophical tradition known as atomism. According to this idea, if one were to take a lump of matter ...
, the elementary charge had also been indirectly inferred to ~3% accuracy from
blackbody spectra by
Max Planck
Max Karl Ernst Ludwig Planck (, ; 23 April 1858 – 4 October 1947) was a German theoretical physicist whose discovery of energy quanta won him the Nobel Prize in Physics in 1918.
Planck made many substantial contributions to theoretical ...
in 1901
and (through the
Faraday constant
In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of S ...
) at order-of-magnitude accuracy by
Johann Loschmidt's measurement of
Avagadro's number in 1865.
As a unit
In some
natural unit
In physics, natural units are physical units of measurement in which only universal physical constants are used as defining constants, such that each of these constants acts as a coherent unit of a quantity. For example, the elementary charge ...
systems, such as the system of
atomic units
The Hartree atomic units are a system of natural units of measurement which is especially convenient for atomic physics and computational chemistry calculations. They are named after the physicist Douglas Hartree. By definition, the following fo ...
, ''e'' functions as the
unit
Unit may refer to:
Arts and entertainment
* UNIT, a fictional military organization in the science fiction television series ''Doctor Who''
* Unit of action, a discrete piece of action (or beat) in a theatrical presentation
Music
* ''Unit'' (a ...
of electric charge. The use of elementary charge as a unit was promoted by
George Johnstone Stoney
George Johnstone Stoney FRS (15 February 1826 – 5 July 1911) was an Irish physicist. He is most famous for introducing the term ''electron'' as the "fundamental unit quantity of electricity".
He had introduced the concept, though not the word ...
in 1874 for the first system of
natural units
In physics, natural units are physical units of measurement in which only universal physical constants are used as defining constants, such that each of these constants acts as a coherent unit of a quantity. For example, the elementary charge ...
, called
Stoney units In physics the Stoney units form a system of units named after the Irish physicist George Johnstone Stoney, who first proposed them in 1881. They are the earliest example of natural units, i.e., a coherent set of units of measurement designed so th ...
. Later, he proposed the name ''electron'' for this unit. At the time, the particle we now call the
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary partic ...
was not yet discovered and the difference between the particle ''electron'' and the unit of charge ''electron'' was still blurred. Later, the name ''electron'' was assigned to the particle and the unit of charge ''e'' lost its name. However, the unit of energy
electronvolt
In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy gained by a single electron accelerating from rest through an electric potential difference of one volt in vacu ...
is a remnant of the fact that the elementary charge was once called ''electron''.
In some other natural unit systems the unit of charge is defined as , with the result that , where ''α'' is the
fine-structure constant
In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Greek letter ''alpha''), is a fundamental physical constant which quantifies the strength of the electromagnetic interaction between ele ...
, ''c'' is the
speed of light
The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit fo ...
, ''ε''
0 is the
electric constant, and ''ħ'' is the
reduced Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
.
Quantization
''Charge quantization'' is the principle that the charge of any object is an
integer
An integer is the number zero (), a positive natural number (, , , etc.) or a negative integer with a minus sign ( −1, −2, −3, etc.). The negative numbers are the additive inverses of the corresponding positive numbers. In the language ...
multiple of the elementary charge. Thus, an object's charge can be exactly 0 ''e'', or exactly 1 ''e'', −1 ''e'', 2 ''e'', etc., but not ''e'', or −3.8 ''e'', etc. (There may be exceptions to this statement, depending on how "object" is defined; see below.)
This is the reason for the terminology "elementary charge": it is meant to imply that it is an indivisible unit of charge.
Fractional elementary charge
There are two known sorts of exceptions to the indivisibility of the elementary charge:
quark
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All common ...
s and
quasiparticle
In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum.
For exa ...
s.
*
Quark
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All common ...
s, first posited in the 1960s, have quantized charge, but the charge is quantized into multiples of . However, quarks cannot be isolated; they exist only in groupings, and stable groupings of quarks (such as a
proton, which consists of three quarks) all have charges that are integer multiples of ''e''. For this reason, either 1 ''e'' or can be justifiably considered to be "the
quantum of charge", depending on the context. This charge commensurability, "charge quantization", has partially
motivated Grand unified Theories.
*
Quasiparticle
In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum.
For exa ...
s are not particles as such, but rather an
emergent
Emergent may refer to:
* ''Emergent'' (album), a 2003 album by Gordian Knot
* Emergent (software), Neural Simulation Software
* Emergent BioSolutions, a multinational biopharmaceutical company headquartered in Gaithersburg, Maryland, USA
* Emerg ...
entity in a complex material system that behaves like a particle. In 1982
Robert Laughlin explained the
fractional quantum Hall effect
The fractional quantum Hall effect (FQHE) is a physical phenomenon in which the Hall conductance of 2-dimensional (2D) electrons shows precisely quantized plateaus at fractional values of e^2/h. It is a property of a collective state in which elec ...
by postulating the existence of fractionally charged
quasiparticle
In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum.
For exa ...
s. This theory is now widely accepted, but this is not considered to be a violation of the principle of charge quantization, since quasiparticles are not
elementary particles
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, an ...
.
Quantum of charge
All known
elementary particle
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, antiq ...
s, including quarks, have charges that are integer multiples of ''e''. Therefore, the "
quantum of charge" is ''e''. In this case, one says that the "elementary charge" is three times as large as the "quantum of charge".
On the other hand, all ''isolatable'' particles have charges that are integer multiples of ''e''. (Quarks cannot be isolated: they exist only in collective states like protons that have total charges that are integer multiples of ''e''.) Therefore, the "quantum of charge" is ''e'', with the proviso that quarks are not to be included. In this case, "elementary charge" would be synonymous with the "quantum of charge".
In fact, both terminologies are used. For this reason, phrases like "the quantum of charge" or "the indivisible unit of charge" can be ambiguous unless further specification is given. On the other hand, the term "elementary charge" is unambiguous: it refers to a quantity of charge equal to that of a proton.
Lack of fractional charges
Paul Dirac
Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Unive ...
argued in 1931 that if
magnetic monopole
In particle physics, a magnetic monopole is a hypothetical elementary particle that is an isolated magnet with only one magnetic pole (a north pole without a south pole or vice versa). A magnetic monopole would have a net north or south "magneti ...
s exist, then electric charge must be quantized; however, it is unknown whether magnetic monopoles actually exist. It is currently unknown why isolatable particles are restricted to integer charges; much of the
string theory landscape
The string theory landscape or landscape of vacua refers to the collection of possible false vacua in string theory,The number of metastable vacua is not known exactly, but commonly quoted estimates are of the order 10500. See M. Douglas, "The ...
appears to admit fractional charges.
Experimental measurements of the elementary charge
Before reading, it must be remembered that the elementary charge is exactly defined since 20 May 2019 by the
International System of Units.
In terms of the Avogadro constant and Faraday constant
If the
Avogadro constant
The Avogadro constant, commonly denoted or , is the proportionality factor that relates the number of constituent particles (usually molecules, atoms or ions) in a sample with the amount of substance in that sample. It is an SI defining con ...
''N''
A and the
Faraday constant
In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of S ...
''F'' are independently known, the value of the elementary charge can be deduced using the formula
:
(In other words, the charge of one
mole of electrons, divided by the number of electrons in a mole, equals the charge of a single electron.)
This method is ''not'' how the ''most accurate'' values are measured today. Nevertheless, it is a legitimate and still quite accurate method, and experimental methodologies are described below.
The value of the Avogadro constant ''N''
A was first approximated by
Johann Josef Loschmidt who, in 1865, estimated the average diameter of the molecules in air by a method that is equivalent to calculating the number of particles in a given volume of gas. Today the value of ''N''
A can be measured at very high accuracy by taking an extremely pure crystal (often
silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
), measuring how far apart the atoms are spaced using
X-ray diffraction or another method, and accurately measuring the density of the crystal. From this information, one can deduce the mass (''m'') of a single atom; and since the
molar mass
In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance which is the number of moles in that sample, measured in moles. The molar mass is a bulk, not molecula ...
(''M'') is known, the number of atoms in a mole can be calculated: ''N''
A = ''M''/''m''.
The value of ''F'' can be measured directly using
Faraday's laws of electrolysis. Faraday's laws of electrolysis are quantitative relationships based on the electrochemical researches published by
Michael Faraday
Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inductio ...
in 1834. In an
electrolysis experiment, there is a one-to-one correspondence between the electrons passing through the anode-to-cathode wire and the ions that plate onto or off of the anode or cathode. Measuring the mass change of the anode or cathode, and the total charge passing through the wire (which can be measured as the time-integral of
electric current
An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The movin ...
), and also taking into account the molar mass of the ions, one can deduce ''F''.
The limit to the precision of the method is the measurement of ''F'': the best experimental value has a relative uncertainty of 1.6 ppm, about thirty times higher than other modern methods of measuring or calculating the elementary charge.
Oil-drop experiment
A famous method for measuring ''e'' is Millikan's oil-drop experiment. A small drop of oil in an electric field would move at a rate that balanced the forces of
gravity
In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the str ...
,
viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inte ...
(of traveling through the air), and
electric force
Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventio ...
. The forces due to gravity and viscosity could be calculated based on the size and velocity of the oil drop, so electric force could be deduced. Since electric force, in turn, is the product of the electric charge and the known electric field, the electric charge of the oil drop could be accurately computed. By measuring the charges of many different oil drops, it can be seen that the charges are all integer multiples of a single small charge, namely ''e''.
The necessity of measuring the size of the oil droplets can be eliminated by using tiny plastic spheres of a uniform size. The force due to viscosity can be eliminated by adjusting the strength of the electric field so that the sphere hovers motionless.
Shot noise
Any
electric current
An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The movin ...
will be associated with
noise
Noise is unwanted sound considered unpleasant, loud or disruptive to hearing. From a physics standpoint, there is no distinction between noise and desired sound, as both are vibrations through a medium, such as air or water. The difference aris ...
from a variety of sources, one of which is
shot noise
Shot noise or Poisson noise is a type of noise which can be modeled by a Poisson process.
In electronics shot noise originates from the discrete nature of electric charge. Shot noise also occurs in photon counting in optical devices, where shot ...
. Shot noise exists because a current is not a smooth continual flow; instead, a current is made up of discrete electrons that pass by one at a time. By carefully analyzing the noise of a current, the charge of an electron can be calculated. This method, first proposed by
Walter H. Schottky, can determine a value of ''e'' of which the accuracy is limited to a few percent. However, it was used in the first direct observation of
Laughlin quasiparticle
In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum.
For exa ...
s, implicated in the
fractional quantum Hall effect
The fractional quantum Hall effect (FQHE) is a physical phenomenon in which the Hall conductance of 2-dimensional (2D) electrons shows precisely quantized plateaus at fractional values of e^2/h. It is a property of a collective state in which elec ...
.
From the Josephson and von Klitzing constants
Another accurate method for measuring the elementary charge is by inferring it from measurements of two effects in
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
: The
Josephson effect
In physics, the Josephson effect is a phenomenon that occurs when two superconductors are placed in proximity, with some barrier or restriction between them. It is an example of a macroscopic quantum phenomenon, where the effects of quantum me ...
, voltage oscillations that arise in certain
superconducting
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
structures; and the
quantum Hall effect
The quantum Hall effect (or integer quantum Hall effect) is a quantized version of the Hall effect which is observed in two-dimensional electron systems subjected to low temperatures and strong magnetic fields, in which the Hall resistance exhib ...
, a quantum effect of electrons at low temperatures, strong magnetic fields, and confinement into two dimensions. The
Josephson constant is
:
where ''h'' is the
Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
. It can be measured directly using the
Josephson effect
In physics, the Josephson effect is a phenomenon that occurs when two superconductors are placed in proximity, with some barrier or restriction between them. It is an example of a macroscopic quantum phenomenon, where the effects of quantum me ...
.
The
von Klitzing constant is
:
It can be measured directly using the
quantum Hall effect
The quantum Hall effect (or integer quantum Hall effect) is a quantized version of the Hall effect which is observed in two-dimensional electron systems subjected to low temperatures and strong magnetic fields, in which the Hall resistance exhib ...
.
From these two constants, the elementary charge can be deduced:
:
CODATA method
The relation used by
CODATA
The Committee on Data of the International Science Council (CODATA) was established in 1966 as the Committee on Data for Science and Technology, originally part of the International Council of Scientific Unions, now part of the International ...
to determine elementary charge was:
:
where ''h'' is the
Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
, ''α'' is the
fine-structure constant
In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Greek letter ''alpha''), is a fundamental physical constant which quantifies the strength of the electromagnetic interaction between ele ...
, ''μ''
0 is the
magnetic constant
The vacuum magnetic permeability (variously ''vacuum permeability'', ''permeability of free space'', ''permeability of vacuum''), also known as the magnetic constant, is the magnetic permeability in a classical vacuum. It is a physical constant ...
, ''ε''
0 is the
electric constant, and ''c'' is the
speed of light
The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit fo ...
. Presently this equation reflects a relation between ''ε''
0 and ''α'', while all others are fixed values. Thus the relative standard uncertainties of both will be same.
Tests of the universality of elementary charge
See also
*
Committee on Data of the International Science Council
The Committee on Data of the International Science Council (CODATA) was established in 1966 as the Committee on Data for Science and Technology, originally part of the International Council of Scientific Unions, now part of the Internationa ...
References
Further reading
*''Fundamentals of Physics'', 7th Ed., Halliday, Robert Resnick, and Jearl Walker. Wiley, 2005
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Physical constants
Units of electrical charge
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