The elementary charge, usually denoted by is the

electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respe ...

carried by a single

proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...

or, equivalently, the magnitude of the negative electric charge carried by a single

electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...

, which has charge −1 . This elementary charge is a fundamental

physical constant A physical constant, sometimes fundamental physical constant or universal constant, is a physical quantity that is generally believed to be both universal in nature and have constant value in time. It is contrasted with a mathematical constant, ...

. In the SI system of units, the value of the elementary charge is exactly defined as

e

coulomb The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI). In the present version of the SI it is equal to the electric charge delivered by a 1 ampere constant current in 1 second and to elementary char ...

s, or 160.2176634

zepto A metric prefix is a unit prefix that precedes a basic unit of measure to indicate a multiple or submultiple of the unit. All metric prefixes used today are decadic. Each prefix has a unique symbol that is prepended to any unit symbol. The pre ...

coulombs (zC). Since the

2019 redefinition of SI base units In 2019, four of the seven SI base units specified in the International System of Quantities were redefined in terms of natural physical constants, rather than human artifacts such as the standard kilogram. Effective 20 May 2019, the 144th ...

, the seven

SI base unit The SI base units are the standard units of measurement defined by the International System of Units (SI) for the seven base quantities of what is now known as the International System of Quantities: they are notably a basic set from which all ...

s are defined by seven fundamental physical constants, of which the elementary charge is one. In the

centimetre–gram–second system of units The centimetre–gram–second system of units (abbreviated CGS or cgs) is a variant of the metric system based on the centimetre as the unit of length, the gram as the unit of mass, and the second as the unit of time. All CGS mechanical units a ...

(CGS), the corresponding quantity is .

Robert A. Millikan Robert Andrews Millikan (March 22, 1868 – December 19, 1953) was an American experimental physicist honored with the Nobel Prize for Physics in 1923 for the measurement of the Elementary charge, elementary electric charge and for his work on ...

and

Harvey Fletcher Harvey Fletcher (September 11, 1884 – July 23, 1981) was an American physicist. Known as the "father of stereophonic sound", he is credited with the invention of the 2-A audiometer and an early electronic hearing aid. He was an investigator in ...

oil drop experiment The oil drop experiment was performed by Robert A. Millikan and Harvey Fletcher in 1909 to measure the elementary electric charge (the charge of the electron). The experiment took place in the Ryerson Physical Laboratory at the University of Chi ...

first directly measured the magnitude of the elementary charge in 1909, differing from the modern accepted value by just 0.6%. Under assumptions of the then-disputed

atomic theory Atomic theory is the scientific theory that matter is composed of particles called atoms. Atomic theory traces its origins to an ancient philosophical tradition known as atomism. According to this idea, if one were to take a lump of matter a ...

, the elementary charge had also been indirectly inferred to ~3% accuracy from blackbody spectra by

Max Planck Max Karl Ernst Ludwig Planck (, ; 23 April 1858 – 4 October 1947) was a German theoretical physicist whose discovery of energy quanta won him the Nobel Prize in Physics in 1918. Planck made many substantial contributions to theoretical p ...

in 1901 and (through the

Faraday constant In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of S ...

) at order-of-magnitude accuracy by Johann Loschmidt's measurement of

Avagadro's number The Avogadro constant, commonly denoted or , is the proportionality factor that relates the number of constituent particles (usually molecules, atoms or ions) in a sample with the amount of substance in that sample. It is an SI defining co ...

in 1865.

As a unit

In some

natural unit In physics, natural units are physical units of measurement in which only universal physical constants are used as defining constants, such that each of these constants acts as a coherent unit of a quantity. For example, the elementary charge may ...

systems, such as the system of

atomic units The Hartree atomic units are a system of natural units of measurement which is especially convenient for atomic physics and computational chemistry calculations. They are named after the physicist Douglas Hartree. By definition, the following f ...

, ''e'' functions as the

unit Unit may refer to: Arts and entertainment * UNIT, a fictional military organization in the science fiction television series ''Doctor Who'' * Unit of action, a discrete piece of action (or beat) in a theatrical presentation Music * ''Unit'' (alb ...

of electric charge. The use of elementary charge as a unit was promoted by

George Johnstone Stoney George Johnstone Stoney FRS (15 February 1826 – 5 July 1911) was an Irish people, Irish physicist. He is most famous for introducing the term ''electron'' as the "fundamental unit quantity of electricity". He had introduced the concept, thoug ...

in 1874 for the first system of

natural units In physics, natural units are physical units of measurement in which only universal physical constants are used as defining constants, such that each of these constants acts as a Coherence (units of measurement), coherent unit of a quantity. For e ...

, called Stoney units. Later, he proposed the name ''electron'' for this unit. At the time, the particle we now call the

was not yet discovered and the difference between the particle ''electron'' and the unit of charge ''electron'' was still blurred. Later, the name ''electron'' was assigned to the particle and the unit of charge ''e'' lost its name. However, the unit of energy

electronvolt In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defi ...

is a remnant of the fact that the elementary charge was once called ''electron''. In some other natural unit systems the unit of charge is defined as , with the result that , where ''α'' is the

fine-structure constant In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Greek letter ''alpha''), is a fundamental physical constant which quantifies the strength of the electromagnetic interaction between ele ...

, ''c'' is the

speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit ...

, ''ε''₀ is the

electric constant Vacuum permittivity, commonly denoted (pronounced "epsilon nought" or "epsilon zero"), is the value of the absolute dielectric permittivity of classical vacuum. It may also be referred to as the permittivity of free space, the electric consta ...

, and ''ħ'' is the

reduced Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivale ...

Quantization

''Charge quantization'' is the principle that the charge of any object is an

integer An integer is the number zero (), a positive natural number (, , , etc.) or a negative integer with a minus sign (−1, −2, −3, etc.). The negative numbers are the additive inverses of the corresponding positive numbers. In the language ...

multiple of the elementary charge. Thus, an object's charge can be exactly 0 ''e'', or exactly 1 ''e'', −1 ''e'', 2 ''e'', etc., but not ''e'', or −3.8 ''e'', etc. (There may be exceptions to this statement, depending on how "object" is defined; see below.) This is the reason for the terminology "elementary charge": it is meant to imply that it is an indivisible unit of charge.

Fractional elementary charge

There are two known sorts of exceptions to the indivisibility of the elementary charge:

quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly o ...

s and

quasiparticle In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For exam ...

s. *

Quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly o ...

s, first posited in the 1960s, have quantized charge, but the charge is quantized into multiples of . However, quarks cannot be isolated; they exist only in groupings, and stable groupings of quarks (such as a

, which consists of three quarks) all have charges that are integer multiples of ''e''. For this reason, either 1 ''e'' or can be justifiably considered to be "the

quantum In physics, a quantum (plural quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a physical property can be "quantized" is referred to as "the hypothesis of quantizati ...

of charge", depending on the context. This charge commensurability, "charge quantization", has partially motivated Grand unified Theories. *

Quasiparticle In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For exam ...

s are not particles as such, but rather an emergent entity in a complex material system that behaves like a particle. In 1982

Robert Laughlin Robert Betts Laughlin (born November 1, 1950) is the Anne T. and Robert M. Bass Professor of Physics and Applied Physics at Stanford University. Along with Horst L. Störmer of Columbia University and Daniel C. Tsui of Princeton Universi ...

explained the

fractional quantum Hall effect The fractional quantum Hall effect (FQHE) is a physical phenomenon in which the Hall conductance of 2-dimensional (2D) electrons shows precisely quantized plateaus at fractional values of e^2/h. It is a property of a collective state in which elec ...

by postulating the existence of fractionally charged

s. This theory is now widely accepted, but this is not considered to be a violation of the principle of charge quantization, since quasiparticles are not

elementary particles In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, antiqu ...

Quantum of charge

All known

elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, an ...

s, including quarks, have charges that are integer multiples of ''e''. Therefore, the "

of charge" is ''e''. In this case, one says that the "elementary charge" is three times as large as the "quantum of charge". On the other hand, all ''isolatable'' particles have charges that are integer multiples of ''e''. (Quarks cannot be isolated: they exist only in collective states like protons that have total charges that are integer multiples of ''e''.) Therefore, the "quantum of charge" is ''e'', with the proviso that quarks are not to be included. In this case, "elementary charge" would be synonymous with the "quantum of charge". In fact, both terminologies are used. For this reason, phrases like "the quantum of charge" or "the indivisible unit of charge" can be ambiguous unless further specification is given. On the other hand, the term "elementary charge" is unambiguous: it refers to a quantity of charge equal to that of a proton.

Lack of fractional charges

Paul Dirac Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...

argued in 1931 that if

magnetic monopole In particle physics, a magnetic monopole is a hypothetical elementary particle that is an isolated magnet with only one magnetic pole (a north pole without a south pole or vice versa). A magnetic monopole would have a net north or south "magneti ...

s exist, then electric charge must be quantized; however, it is unknown whether magnetic monopoles actually exist. It is currently unknown why isolatable particles are restricted to integer charges; much of the

string theory landscape The string theory landscape or landscape of vacua refers to the collection of possible false vacua in string theory,The number of metastable vacua is not known exactly, but commonly quoted estimates are of the order 10500. See M. Douglas, "The ...

appears to admit fractional charges.

Experimental measurements of the elementary charge

Before reading, it must be remembered that the elementary charge is exactly defined since 20 May 2019 by the

International System of Units The International System of Units, known by the international abbreviation SI in all languages and sometimes pleonastically as the SI system, is the modern form of the metric system and the world's most widely used system of measurement. E ...

In terms of the Avogadro constant and Faraday constant

If the

Avogadro constant The Avogadro constant, commonly denoted or , is the proportionality factor that relates the number of constituent particles (usually molecules, atoms or ions) in a sample with the amount of substance in that sample. It is an SI defining con ...

''N''_A and the

''F'' are independently known, the value of the elementary charge can be deduced using the formula :

e = \frac.

(In other words, the charge of one

mole Mole (or Molé) may refer to: Animals * Mole (animal) or "true mole", mammals in the family Talpidae, found in Eurasia and North America * Golden moles, southern African mammals in the family Chrysochloridae, similar to but unrelated to Talpida ...

of electrons, divided by the number of electrons in a mole, equals the charge of a single electron.) This method is ''not'' how the ''most accurate'' values are measured today. Nevertheless, it is a legitimate and still quite accurate method, and experimental methodologies are described below. The value of the Avogadro constant ''N''_A was first approximated by

Johann Josef Loschmidt Johann Josef Loschmidt (15 March 1821 – 8 July 1895), who referred to himself mostly as Josef Loschmidt (omitting his first name), was a notable Austrian scientist who performed ground-breaking work in chemistry, physics (thermodynamics, optics, ...

who, in 1865, estimated the average diameter of the molecules in air by a method that is equivalent to calculating the number of particles in a given volume of gas. Today the value of ''N''_A can be measured at very high accuracy by taking an extremely pure crystal (often

silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...

), measuring how far apart the atoms are spaced using

X-ray diffraction X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...

or another method, and accurately measuring the density of the crystal. From this information, one can deduce the mass (''m'') of a single atom; and since the

molar mass In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance which is the number of moles in that sample, measured in moles. The molar mass is a bulk, not molecular, p ...

(''M'') is known, the number of atoms in a mole can be calculated: ''N''_A = ''M''/''m''. The value of ''F'' can be measured directly using

Faraday's laws of electrolysis Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass (m) of elements deposited at an electrode is directly pro ...

. Faraday's laws of electrolysis are quantitative relationships based on the electrochemical researches published by

Michael Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inducti ...

in 1834. In an

electrolysis In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from n ...

experiment, there is a one-to-one correspondence between the electrons passing through the anode-to-cathode wire and the ions that plate onto or off of the anode or cathode. Measuring the mass change of the anode or cathode, and the total charge passing through the wire (which can be measured as the time-integral of

electric current An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving pa ...

), and also taking into account the molar mass of the ions, one can deduce ''F''. The limit to the precision of the method is the measurement of ''F'': the best experimental value has a relative uncertainty of 1.6 ppm, about thirty times higher than other modern methods of measuring or calculating the elementary charge.

Oil-drop experiment

A famous method for measuring ''e'' is Millikan's oil-drop experiment. A small drop of oil in an electric field would move at a rate that balanced the forces of

gravity In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the stro ...

viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...

(of traveling through the air), and

electric force Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is convention ...

. The forces due to gravity and viscosity could be calculated based on the size and velocity of the oil drop, so electric force could be deduced. Since electric force, in turn, is the product of the electric charge and the known electric field, the electric charge of the oil drop could be accurately computed. By measuring the charges of many different oil drops, it can be seen that the charges are all integer multiples of a single small charge, namely ''e''. The necessity of measuring the size of the oil droplets can be eliminated by using tiny plastic spheres of a uniform size. The force due to viscosity can be eliminated by adjusting the strength of the electric field so that the sphere hovers motionless.

Shot noise

Any

will be associated with

noise Noise is unwanted sound considered unpleasant, loud or disruptive to hearing. From a physics standpoint, there is no distinction between noise and desired sound, as both are vibrations through a medium, such as air or water. The difference arise ...

from a variety of sources, one of which is

shot noise Shot noise or Poisson noise is a type of noise which can be modeled by a Poisson process. In electronics shot noise originates from the discrete nature of electric charge. Shot noise also occurs in photon counting in optical devices, where shot ...

. Shot noise exists because a current is not a smooth continual flow; instead, a current is made up of discrete electrons that pass by one at a time. By carefully analyzing the noise of a current, the charge of an electron can be calculated. This method, first proposed by

Walter H. Schottky Walter Hans Schottky (23 July 1886 – 4 March 1976) was a German physicist who played a major early role in developing the theory of electron and ion emission phenomena, invented the screen-grid vacuum tube in 1915 while working at Siemens ...

, can determine a value of ''e'' of which the accuracy is limited to a few percent. However, it was used in the first direct observation of Laughlin

s, implicated in the

From the Josephson and von Klitzing constants

Another accurate method for measuring the elementary charge is by inferring it from measurements of two effects in

quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...

: The

Josephson effect In physics, the Josephson effect is a phenomenon that occurs when two superconductors are placed in proximity, with some barrier or restriction between them. It is an example of a macroscopic quantum phenomenon, where the effects of quantum mech ...

, voltage oscillations that arise in certain

superconducting Superconductivity is a set of physical properties observed in certain materials where Electrical resistance and conductance, electrical resistance vanishes and magnetic field, magnetic flux fields are expelled from the material. Any material e ...

structures; and the

quantum Hall effect The quantum Hall effect (or integer quantum Hall effect) is a quantized version of the Hall effect which is observed in two-dimensional electron systems subjected to low temperatures and strong magnetic fields, in which the Hall resistance exh ...

, a quantum effect of electrons at low temperatures, strong magnetic fields, and confinement into two dimensions. The

Josephson constant The magnetic flux, represented by the symbol , threading some contour or loop is defined as the magnetic field multiplied by the loop area , i.e. . Both and can be arbitrary, meaning can be as well. However, if one deals with the superconducti ...

is :

K_\text = \frac,

where ''h'' is the

Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivale ...

. It can be measured directly using the

. The

von Klitzing constant The quantum Hall effect (or integer quantum Hall effect) is a quantized version of the Hall effect which is observed in two-dimensional electron systems subjected to low temperatures and strong magnetic fields, in which the Hall resistance exhi ...

is :

R_\text = \frac.

It can be measured directly using the

. From these two constants, the elementary charge can be deduced: :

e = \frac.

CODATA method

The relation used by CODATA to determine elementary charge was: :

e^2 = \frac = 2h \alpha \varepsilon_0 c,

where ''h'' is the

, ''α'' is the

, ''μ''₀ is the

magnetic constant The vacuum magnetic permeability (variously ''vacuum permeability'', ''permeability of free space'', ''permeability of vacuum''), also known as the magnetic constant, is the magnetic permeability in a classical vacuum. It is a physical constant, ...

, ''ε''₀ is the

, and ''c'' is the

. Presently this equation reflects a relation between ''ε''₀ and ''α'', while all others are fixed values. Thus the relative standard uncertainties of both will be same.