Frankdicksonite is a
halide mineral
Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have polyatomic anions.
Examples include the following:
*Atacamite
* Avogadrite (K,Cs)BF
*Bararite (β)
*Bischofite
* Brüggenite ...
with the chemical formula
Ba F2 which corresponds to the chemical compound
barium fluoride
Barium fluoride (BaF2) is an inorganic compound with the formula BaF2. It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. Under standard conditions it adopts the fluorite structure and at high pressure the PbCl2 s ...
. It occurs in the Carlin gold deposit of
Eureka County, Nevada
Eureka County is a county in the U.S. state of Nevada. As of the 2020 census, the population was 1,855, making it the second-least populous county in Nevada. Its county seat is Eureka.
Eureka County is part of the Elko Micropolitan Statistic ...
as cubic crystals sized between 0.1 and 4 mm, and is of
hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
origin. Its only associated mineral is
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
and the frankdicksonite crystals are always completely encapsulated in it. Frankdicksonite has
fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
crystal structure with a cubic symmetry and the lattice constant ''a'' = 619.64 pm. Its
Vickers hardness
The Vickers hardness test was developed in 1921 by Robert L. Smith and George E. Sandland at Vickers Ltd as an alternative to the Brinell method to measure the hardness of materials. The Vickers test is often easier to use than other hardness t ...
on the cleavage crystal faces varies between 88 and 94 kg/mm
2 and is close to that of the synthetic barium fluoride (95 kg/mm
2). Its
refractive index
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
(1.475) is almost identical to that of BaF
2 (1.474). Under electron irradiation, it emits strong blue
cathodoluminescence
Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example is th ...
. The major impurity in frankdicksonite is
strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...
with concentrations up to 0.5% by weight. Also present are
silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...
(0.02%) and
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
(0.0015%); other impurities have concentrations below 0.0015%.
[
Although synthetic barium fluoride has been commonly known from at least 1846,] it had not been found in nature. The natural existence of barium fluoride was predicted by Michael Fleischer in 1970. Later in the same year, the mineral was discovered by Arthur S. Radtke and named after Frank W. Dickson (born 1922), professor of Geochemistry
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
at Stanford University
Stanford University, officially Leland Stanford Junior University, is a private research university in Stanford, California. The campus occupies , among the largest in the United States, and enrolls over 17,000 students. Stanford is consider ...
in recognition of his contributions to geology and geochemistry of low-temperature ore deposits. Frankdicksonite was officially recognized by the Commission of New Minerals and Mineral Names in 1974.
References
{{reflist
Barium minerals
Fluorine minerals
Cubic minerals
Minerals in space group 225