Flubber (named from the film ''
The Absent-Minded Professor
''The Absent-Minded Professor'' is a 1961 American science fiction comedy film produced by Walt Disney Productions and based on the short story "A Situation of Gravity" by Samuel W. Taylor, originally published in the May 22, 1943 issue of ''Li ...
''), Glorp, Glurch, or
Slime
Slime may refer to:
Biology
* Slime mold, a broad term often referring to roughly six groups of Eukaryotes
* Biofilm, an aggregate of microorganisms in which cells adhere to each other and/or to a surface
* Slimy (fish), also known as the pony ...
is a rubbery polymer formed by
cross-link
In chemistry and biology a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural ...
ing of
polyvinyl alcohol
Poly(vinyl alcohol) (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula H2CH(OH)sub>''n''. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) a ...
(PVA) with a
borate
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refe ...
compound. Slime can be made by combining
polyvinyl-acetate-based
adhesive
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advant ...
s with
borax
Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, ...
.
Reaction
The
gelation
In polymer chemistry, gelation (gel transition) is the formation of a gel from a system with polymers. Branched polymers can form links between the chains, which lead to progressively larger polymers. As the linking continues, larger branched p ...
process entails formation of a
borate ester
In organic chemistry, borate esters are organoboron compounds which are conveniently prepared by the stoichiometric condensation reaction of boric acid with alcohols. There are two main classes of borate esters: orthoborates, and metaborates, . ...
that crosslinks the chains of the PVA.
Borate esters form readily by condensation of
hydroxyl groups
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy ...
and the B-OH groups.
The individual polymer chains are bound together by
weak hydrogen bonds. The resulting polymer network is composed of strands of
polyvinyl alcohol
Poly(vinyl alcohol) (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula H2CH(OH)sub>''n''. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) a ...
held together side-by-side by the borate molecules. It is evident that this
cross linking
In chemistry and biology a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural ...
is weak because of the ease with which the slime flows and pulls apart. However, even though this
cross linking
In chemistry and biology a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural ...
is weak, it does alter the properties of the resulting polymer.
Properties
Flubber is a
non-Newtonian fluid
A non-Newtonian fluid is a fluid that does not follow Newton's law of viscosity, i.e., constant viscosity independent of stress. In non-Newtonian fluids, viscosity can change when under force to either more liquid or more solid. Ketchup, for exa ...
that flows under low stress, but breaks under higher stresses and pressures. This combination of fluid-like and solid-like properties makes it a
Maxwell fluid. Its behavior can also be described as being
viscoplastic
Viscoplasticity is a theory in continuum mechanics that describes the rate-dependent inelastic behavior of solids. Rate-dependence in this context means that the deformation of the material depends on the rate at which loads are applied. The in ...
or
gelatin
Gelatin or gelatine (from la, gelatus meaning "stiff" or "frozen") is a translucent, colorless, flavorless food ingredient, commonly derived from collagen taken from animal body parts. It is brittle when dry and rubbery when moist. It may also ...
ous.
See also
*
Silly Putty
Silly Putty is a toy based on silicone polymers that have unusual physical properties. It bounces, but it breaks when given a sharp blow, and it can also flow like a liquid. It contains a viscoelastic liquid silicone, a type of non-Newtonian f ...
*
Gunge
*
Nickelodeon compounds
*
Slime (toy)
Slime was a toy product manufactured by Mattel, sold in a plastic trash can and introduced in February 1976. It consisted of a non-toxic viscous, squishy and oozy green or other color material made primarily from guar gum. Different variation ...
References
{{Reflist
Chemistry experiments
Non-Newtonian fluids
Sensory toys