In
fire protection
Fire protection is the study and practice of mitigating the unwanted effects of potentially destructive fires. It involves the study of the behaviour, compartmentalisation, suppression and investigation of fire and its related emergencies, as we ...
, an accelerant is any substance or mixture that accelerates or speeds the development and escalation of
fire
Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various reaction Product (chemistry), products.
At a certain point in the combustion reaction, called the ignition ...
. Accelerants are often used to commit
arson
Arson is the crime of willfully and deliberately setting fire to or charring property. Although the act of arson typically involves buildings, the term can also refer to the intentional burning of other things, such as motor vehicles, wat ...
, and some accelerants may cause an
explosion
An explosion is a rapid expansion in volume associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Supersonic explosions created by high explosives are known ...
. Some fire investigators use the term "accelerant" to mean any substance that initiates and promotes a fire without implying intent or malice.
A fire is a self-sustaining,
exothermic
In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e ...
oxidation reaction that emits heat and light. When a fire is accelerated, it can produce more heat, consume the reactants more quickly, burn at a higher temperature, and increase the spread of the fire. An accelerated fire is said to have a higher "heat release rate," meaning it burns more quickly.
Fire investigation
Indicators of an incendiary fire or arson can lead fire investigators to look for the presence of accelerants in fire debris. Accelerants can leave behind evidence of their presence and use. Accelerants present in areas they should not be can indicate an incendiary fire or arson. Investigators often use special
dogs
The dog (''Canis familiaris'' or ''Canis lupus familiaris'') is a domesticated descendant of the wolf. Also called the domestic dog, it is derived from the extinct Pleistocene wolf, and the modern wolf is the dog's nearest living relative. Do ...
known as accelerant detection canines trained to smell ignitable liquids. The dog can pinpoint areas for the investigator to collect samples. Fire debris submitted to
forensic
Forensic science, also known as criminalistics, is the application of science to criminal and civil laws, mainly—on the criminal side—during criminal investigation, as governed by the legal standards of admissible evidence and criminal p ...
laboratories
A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratory services are provided in a variety of settings: physici ...
employ sensitive analytical instruments with
GC-MS capabilities for
forensic chemical analysis.
Types of accelerants
Many accelerants are
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
-based
fuel
A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but ...
s, sometimes referred to as
petroleum
Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
distillates
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heati ...
:
gasoline
Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic co ...
,
diesel fuel
Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and t ...
,
kerosene
Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning "wax", and was regi ...
,
turpentine
Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a special ...
,
butane
Butane () or ''n''-butane is an alkane with the formula C4H10. Butane is a gas at room temperature and atmospheric pressure. Butane is a highly flammable, colorless, easily liquefied gas that quickly vaporizes at room temperature. The name but ...
, and various other
flammable
A combustible material is something that can burn (i.e., ''combust'') in air. A combustible material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable mat ...
solvent
A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...
s. These accelerants are also known as ignitable liquids. Ignitable liquids can leave behind tell-tale marks in the fire debris. These irregular burn patterns can indicate the presence of an ignitable liquid in a fire.
The properties of some ignitable liquids make them dangerous accelerants. Many ignitable liquids have high
vapor pressure
Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases ...
s, low
flash point
The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1)
The fl ...
s and a relatively wide range between their upper and lower
explosive limit
Mixtures of dispersed combustible materials (such as gaseous or vaporised fuels, and some dusts) and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to a ...
. This allows ignitable liquids to
ignite
To ignite is the first step of firelighting.
Ignite may also refer to:
Music
*Ignite (band), a melodic hardcore band from Orange County, California
* ''Ignite'' (Econoline Crush album), 2007
* ''Ignite'' (Shihad album), 2010
* "Ignite" (Eir Aoi s ...
easily, and when mixed in a proper
air-fuel ratio, readily explode. Many arsonists who use generous amounts of gasoline have been seriously burned or killed igniting their fire.
Available combustibles
Common household items and objects can accelerate a fire. Wicker and foam have high surface to mass ratios and favorable chemical compositions and thus burn easily and readily. Arsonists who use large amounts of available
combustible
A combustible material is something that can burn (i.e., ''combust'') in air. A combustible material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable mat ...
material rather than ignitable liquids try to avoid detection. Using large fuel loads can increase the rate of fire growth as well as spread the fire over a larger area, thus increasing the amount of fire damage. Inappropriate amounts and types of fuel in a particular area can indicate
arson
Arson is the crime of willfully and deliberately setting fire to or charring property. Although the act of arson typically involves buildings, the term can also refer to the intentional burning of other things, such as motor vehicles, wat ...
. Whether available combustible materials constitute an accelerant depends on the intent of the person responsible for their use.
Sales of certain accelerants are limited to the particular group allowed to purchase them for trainings and fire demolitions (to train new firefighters).
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Firefighting
Arson