Erythrite or red cobalt is a secondary hydrated
cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
arsenate mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (v ...
with the formula . Erythrite and
annabergite
Annabergite is an arsenate mineral consisting of a hydrous nickel
arsenate, Ni3(AsO4)2·8H2O, crystallizing in the monoclinic system and isomorphous with vivianite and erythrite. Crystals are minute and capillary and rarely met with, the mineral ...
, chemical formula , or
nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...
arsenate form a complete series with the general formula .
Erythrite crystallizes in the
monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
system and forms prismatic crystals. The color is crimson to pink and occurs as a secondary coating known as ''cobalt bloom'' on cobalt arsenide minerals. Well-formed crystals are rare, with most of the mineral manifesting in crusts or small reniform aggregates.
Erythrite was first described in 1832 for an occurrence in Grube Daniel,
Schneeberg,
Saxony
Saxony (german: Sachsen ; Upper Saxon: ''Saggsn''; hsb, Sakska), officially the Free State of Saxony (german: Freistaat Sachsen, links=no ; Upper Saxon: ''Freischdaad Saggsn''; hsb, Swobodny stat Sakska, links=no), is a landlocked state of ...
,
[ and takes its name from the Greek έρυθρος (''erythros''), meaning red.][ Historically, erythrite itself has not been an economically important mineral, but the prospector may use it as a guide to associated ]cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
and native silver
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
.
Erythrite occurs as a secondary mineral in the oxide zone of Co–Ni–As bearing mineral deposits. It occurs in association with cobaltite
Cobaltite is a sulfide mineral composed of cobalt, arsenic, and sulfur, Co As S. Its impurities may contain up to 10% iron and variable amounts of nickel.Klein, Cornelus and Cornrlius Hurlbut, 1996, ''Manual of Mineralogy'', 20th ed., Wiley, p.2 ...
, skutterudite
Named after Skuterudåsen, a hill in Modum, Norway, skutterudite is a cobalt arsenide mineral containing variable amounts of nickel and iron substituting for cobalt with the ideal formula CoAs3. Some references give the arsenic a variable formula ...
, symplesite, roselite
Roselite is a rare arsenate mineral with chemical formula: . It was first described in 1825 for an occurrence in the Rappold mines of Schneeberg, Saxony, Schneeberg, Saxony, Germany and named by Armand Lévy (mineralogist), Armand Lévy after Ger ...
-beta, scorodite
Scorodite is a common hydrated iron arsenate mineral, with the chemical formula FeAsO4·2H2O. It is found in hydrothermal deposits and as a secondary mineral in gossans worldwide. Scorodite weathers to limonite.
Scorodite was discovered in the S ...
, pharmacosiderite
Pharmacosiderite is a hydrated basic ferric arsenate, with chemical formula K Fe4( As O4)3(O H)4·(6-7) H2O and a molecular weight of 873.38 g/mol. It consists of the elements arsenic, iron, hydrogen, potassium, sodium and oxygen. It has a M ...
, adamite, morenosite, retgersite, and malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures ...
.[
Notable localities are ]Cobalt, Ontario
Cobalt is a town in Timiskaming District, Ontario, Canada. It had a population of 1,118 at the 2016 Census.
In the early 1900s, the area was heavily mined for silver; the silver ore also contained cobalt. By 1910, the community was the fourth h ...
; La Cobaltera, Chile, Schneeberg, Saxony, Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
; Joachimsthal, Czech Republic
The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
; Cornwall
Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...
, England
England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...
; Bou Azzer, Morocco
Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to ...
; the Blackbird mine, Lemhi County, Idaho
Lemhi County is a county located in the U.S. state of Idaho. As of the 2020 census, the population was 7,974. The largest city and county seat is Salmon. The county was established in 1869, named after Fort Lemhi (or Limhi), a remote Mormon mis ...
; Sara Alicia mine, near Alamos, Sonora
Sonora (), officially Estado Libre y Soberano de Sonora ( en, Free and Sovereign State of Sonora), is one of the 31 states which, along with Mexico City, comprise the Administrative divisions of Mexico, Federal Entities of Mexico. The state is d ...
, Mexico
Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...
; Mt. Cobalt, Queensland
)
, nickname = Sunshine State
, image_map = Queensland in Australia.svg
, map_caption = Location of Queensland in Australia
, subdivision_type = Country
, subdivision_name = Australia
, established_title = Before federation
, established_ ...
and the Dome Rock copper mine, Mingary
Mingary Castle ( gd, Caisteal Mhìogharraidh), also known as Mingarry Castle, is a castle situated southeast of the small village of Kilchoan in Lochaber, Scotland. Nestled on ridge of rock overlooking the sea, it was considered a strategicall ...
, South Australia
South Australia (commonly abbreviated as SA) is a state in the southern central part of Australia. It covers some of the most arid parts of the country. With a total land area of , it is the fourth-largest of Australia's states and territories ...
.[
]
Other varieties
The nickel variety, annabergite, occurs as a light green ''nickel bloom'' on nickel arsenides. In addition iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
, magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
and zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
can also substitute for the cobalt position, creating three other minerals: parasymplesite (Fe), hörnesite (Mg) and köttigite
Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (18241892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the ...
(Zn).
References
Further reading
*Dana's Manual of Mineralogy
*Manual of Mineral Science, 22nd Ed. C. Klein.
*
{{Commons category, Erythrite, position=left
Cobalt minerals
Arsenate minerals
Monoclinic minerals
Minerals in space group 12
Vivianite group