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Arsenate Minerals
The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, Double bond, double bonded to one oxygen atom and Single bond, single bonded to a further three oxygen atoms. The four oxygen atoms orient around the arsenic atom in a Tetrahedral molecular geometry, tetrahedral geometry. Resonance (chemistry), Resonance disperses the ion's −3 charge across all four oxygen atoms. Arsenate readily reacts with metals to form arsenate metal Arsenic compounds, compounds. Arsenate is a moderate Oxidant, oxidizer and an electron acceptor, with an electrode potential of +0.56 Volt, V for its Reduction potential, reduction to arsenite. Due to arsenic having the same Valence (chemistry), valency and similar Atomic radii of the elements (data page), atomic radius to phosphorus, arsenate shares similar Tetrahedral molecular geometry, geometry and Reactivity (chemistry), reactivity with phosphate. Arsenate can replace phosphate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arsenic Acid
Arsenic acid or arsoric acid is the chemical compound with the chemical formula, formula . More descriptively written as , this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized. Its hemihydrate form () does form stable crystals. Crystalline samples dehydrate with condensation at 100 °C. Properties It is a tetrahedral species of idealized symmetry group, symmetry ''C''3v with As–O bond lengths ranging from 1.66 to 1.71 Å. Being a triprotic acid, its acidity is described by three equilibria: :, p''K''a1 = 2.19 :, p''K''a2 = 6.94 :, p''K''a3 = 11.5 These acid dissociation constant, p''K''a values are close to those for phosphoric acid. The highly basic arsenate, arsenate ion () is the product of the third ionization. Unlike phosphoric acid, arsenic acid is an oxidizer, as illustrated by its ability to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Radii Of The Elements (data Page)
The atomic radius of a chemical element is the distance from the center of the nucleus to the outermost shell of an electron. Since the boundary is not a well-defined physical entity, there are various non-equivalent definitions of atomic radius. Depending on the definition, the term may apply only to isolated atoms, or also to atoms in condensed matter, covalently bound in molecules, or in ionized and excited states; and its value may be obtained through experimental measurements, or computed from theoretical models. Under some definitions, the value of the radius may depend on the atom's state and context. Atomic radii vary in a predictable and explicable manner across the periodic table. For instance, the radii generally decrease rightward along each period (row) of the table, from the alkali metals to the noble gases; and increase down each group (column). The radius increases sharply between the noble gas at the end of each period and the alkali metal at the beginnin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Annabergite
Annabergite is an arsenate mineral consisting of a hydrous nickel arsenate. It is considered a member of the vivianite group and known for its ability to form crystals in a characteristic apple-green color. History Annabergite has been known since the 18th century, although type localities were not published along initial descriptions. The first report of Annabergite by Axel Fredrik Cronstedt from 1758 erroneously identifies it as a nickel oxide mineral and assigned it the latinized name ''Ochra niccoli'', while Wallerius gave it the name ''nickel bloom'' in 1778. Annabergite was thoroughly described in 1852 by Brooke and Miller from specimens found in Annaberg in Saxony, which was proposed as namesake for the mineral. Properties Annabergite crystallizes in the monoclinic system and is isomorphous with vivianite and erythrite. It most commonly occurs as microcristalline coatings, soft earthy masses and encrustations. Well developed crystals are relatively rare ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alarsite
Alarsite (AlAsO4) is an aluminium arsenate mineral with its name derived from its composition: aluminium and arsenate. It occurs as brittle subhedral grains which exhibit trigonal symmetry. It has a Mohs hardness of 5-5.5 and a specific gravity of 3.32. It is semitransparent, colorless with pale yellow tints and shows a vitreous luster. It is optically uniaxial (+) with refractive indices of nω = 1.596 and nε = 1.608. It was reported from fumaroles in the Tolbachik Tolbachik () is a complex volcano, volcanic complex on the Kamchatka Peninsula in the far east of Russia. It consists of two volcanoes, Plosky (''flat'') Tolbachik (3,085 m) and Ostry (''sharp'') Tolbachik (3,672 m), which as the names suggest a ... volcano, Kamchatka, Far Eastern Region, Russia. It occurs in association with fedotovite, klyuchevskite, lammerite, nabokoite, atlasovite, langbeinite, hematite and tenorite. References Arsenate minerals Aluminium minerals Trigonal minerals Minerals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adamite
Adamite is a zinc arsenate hydroxide mineral, Zn2 As O4O H. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called ''cuproadamite''. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. tarbuttite is an analogous zinc phosphate. Occurrence Adamite occurs as a secondary mineral in the oxidized zone of zinc- and arsenic-bearing hydrothermal mineral deposits. It occurs in association with smithsonite, hemimorphite, scorodite, olivenite, calcite, quartz and i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The Geology, geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock (geology), rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral or may be an aggregate (geology), aggregate of two or more different types of minerals, spaci ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anhydrous
A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achieve perfect dryness; anhydrous compounds gradually absorb water from the atmosphere so they must be stored carefully. Solids Many salts and solids can be dried using heat, or under vacuum. Desiccators can also be used to store reagents in dry conditions. Common desiccants include phosphorus pentoxide and silica gel. Chemists may also require dry glassware for sensitive reactions. This can be achieved by drying glassware in an oven, by flame, or under vacuum. Dry solids can be produced by freeze-drying, which is also known as lyophilization. Liquids or solvents In many cases, the presence of water can prevent a reaction from happening, or cause undesirable products to form. To prevent this, anhydrous solvents must be used when perform ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrate
In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understood. Chemical nature Inorganic chemistry Hydrates are not inorganic salts "containing water molecules combined in a definite ratio as an integral part of the crystal" that are either bound to a metal center or that have crystallized with the metal complex. Such hydrates are also said to contain '' water of crystallization'' or ''water of hydration''. If the water is heavy water in which the constituent hydrogen is the isotope deuterium, then the term ''deuterate'' may be used in place of ''hydrate''. A colorful example is cobalt(II) chloride, which turns from blue to red upon hydration, and can therefore be used as a water indicator. The notation "''hydrated compound''⋅''n''", where ''n'' is the number of water molecules per form ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organism
An organism is any life, living thing that functions as an individual. Such a definition raises more problems than it solves, not least because the concept of an individual is also difficult. Many criteria, few of them widely accepted, have been proposed to define what an organism is. Among the most common is that an organism has autonomous reproduction, Cell growth, growth, and metabolism. This would exclude viruses, despite the fact that they evolution, evolve like organisms. Other problematic cases include colonial organisms; a colony of eusocial insects is organised adaptively, and has Germ-Soma Differentiation, germ-soma specialisation, with some insects reproducing, others not, like cells in an animal's body. The body of a siphonophore, a jelly-like marine animal, is composed of organism-like zooids, but the whole structure looks and functions much like an animal such as a jellyfish, the parts collaborating to provide the functions of the colonial organism. The evolutiona ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Toxicity
Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacteria, bacterium, or plant, as well as the effect on a substructure of the organism, such as a cell (biology), cell (cytotoxicity) or an organ such as the liver (hepatotoxicity). Sometimes the word is more or less synonymous with poison#Poisoning, poisoning in everyday usage. A central concept of toxicology is that the effects of a toxicant are Dose (biochemistry), dose-dependent; even water can lead to water intoxication when taken in too high a dose, whereas for even a very toxic substance such as snake venom there is a dose below which there is no detectable toxic effect. Toxicity is species-specific, making cross-species analysis problematic. Newer paradigms and metrics are evolving to bypass animal testing, while maintaining the concept of toxicity endpoints. Etymology In Ancient G ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biochemistry
Biochemistry, or biological chemistry, is the study of chemical processes within and relating to living organisms. A sub-discipline of both chemistry and biology, biochemistry may be divided into three fields: structural biology, enzymology, and metabolism. Over the last decades of the 20th century, biochemistry has become successful at explaining living processes through these three disciplines. Almost all List of life sciences, areas of the life sciences are being uncovered and developed through biochemical methodology and research.#Voet, Voet (2005), p. 3. Biochemistry focuses on understanding the chemical basis that allows biomolecule, biological molecules to give rise to the processes that occur within living Cell (biology), cells and between cells,#Karp, Karp (2009), p. 2. in turn relating greatly to the understanding of tissue (biology), tissues and organ (anatomy), organs as well as organism structure and function.#Miller, Miller (2012). p. 62. Biochemistry is closely ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
