End-to-end Vector
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In the physical chemistry study of
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
s, the end-to-end vector is the
vector Vector most often refers to: *Euclidean vector, a quantity with a magnitude and a direction *Vector (epidemiology), an agent that carries and transmits an infectious pathogen into another living organism Vector may also refer to: Mathematic ...
that points from one end of a polymer to the other end. If each monomer unit in a polymer is represented by a point in space, the translation vectors \vec_i connect between these points. The end-to-end vector \vec is the sum of these translation vectors: :\vec = \sum_i \vec_i The norm of the end-to-end vector is called the end-to-end distance.


Relation to other quantities

The
quadratic mean In mathematics and its applications, the root mean square of a set of numbers x_i (abbreviated as RMS, or rms and denoted in formulas as either x_\mathrm or \mathrm_x) is defined as the square root of the mean square (the arithmetic mean of the ...
of the end-to-end distance \left\langle r^2 \right\rangle can be related to the quadratic mean of the
radius of gyration ''Radius of gyration'' or gyradius of a body about the axis of rotation is defined as the radial distance to a point which would have a moment of inertia the same as the body's actual distribution of mass, if the total mass of the body were concentr ...
\left\langle s^2 \right\rangle of a polymer by the relation:{{cite book, last1= Gedde , first1= Ulf W. , title= Polymer Physics , url= https://books.google.com/books?id=Iem3fC7XdnkC , year= 1995 , publisher= Springer , isbn= 0-412-62640-3 , page= 21 :\left\langle r^2 \right\rangle = 6 \left\langle s^2 \right\rangle


Notes


See also

* Freely Jointed Chain *
Worm-like chain The worm-like chain (WLC) model in polymer physics is used to describe the behavior of polymers that are semi-flexible: fairly stiff with successive segments pointing in roughly the same direction, and with persistence length within a few orders o ...
Polymers Polymer physics