El Laco (volcano)
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El Laco is a
volcanic complex A complex volcano, also called a compound volcano or a volcanic complex, is a mixed landform consisting of related volcanic centers and their associated lava flows and pyroclastic rock. They may form due to changes in eruptive habit or in t ...
in the Antofagasta Region of Chile. It is directly south of the Cordón de Puntas Negras volcanic chain. Part of the
Central Volcanic Zone The Andean Volcanic Belt is a major volcanic belt along the Andean cordillera in Argentina, Bolivia, Chile, Colombia, Ecuador, and Peru. It is formed as a result of subduction of the Nazca Plate and Antarctic Plate underneath the South Americ ...
of the Andes, it is a group of seven stratovolcanoes and a
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
. It is about two million years old. The main summit of the volcano is a
lava dome In volcanology, a lava dome is a circular mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruptions on ...
called Pico Laco, which is variously reported to be or high. The edifice has been affected by glaciation, and some reports indicate that it is still fumarolically active. The volcano is known for its magnetite-containing lava flows of enigmatic origin. In total, there are four lava flows and two dykes, as well as a formation of uncertain nature. In addition to lava flow structures,
pyroclastics Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyroc ...
containing iron oxide are also found within the complex. The magmas formed within a magma chamber with a volume of about ; whether the iron-rich lavas are native magnetite lavas or were formed by hydrothermal processes acting on regular rock is under debate. After their discovery in 1958, these iron deposits have been mined. Similar deposits of volcanic iron oxide exist in Australia, Chile, and Iran.


Geography

El Laco is part of the Cordón de Puntas Negras sector of the Central Volcanic Zone, directly south of that volcanic chain. It sits atop a quartzite and sandstone basement that was lifted from the seaground during the Acadian orogeny and is of Ordovician age. Later, Mesozoic and
Cenozoic The Cenozoic ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterised by the dominance of mammals, birds and flowering plants, a cooling and drying climate, and the current configura ...
sedimentation occurred, which was then buried by Tertiary rhyolites. Two major volcanic lineaments cross in the El Laco area, including the so-called Calama-Olacapato-El Toro lineament. El Hueso volcano to the north is - high and has a basement diameter of . It has a crater with a diameter of . The city of Antofagasta is located west of El Laco. Other close towns are Calama and San Pedro de Atacama. The international road through Sico Pass connecting
Salta Salta () is the capital and largest city in the Argentine province of the same name. With a population of 618,375 according to the 2010 census, it is also the 7th most-populous city in Argentina. The city serves as the cultural and economic ce ...
in Argentina with Calama in Chile runs close to El Laco. A number of tourist sites are found in the Atacama Desert adjacent to El Laco, and the dry climate also makes the area suitable for astronomy facilities.


Geology

The El Laco volcanic complex is formed by about seven minor
stratovolcano A stratovolcano, also known as a composite volcano, is a conical volcano built up by many layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with a summit crater and per ...
es and lava domes. The complex started its activity in the Miocene- Pliocene, when
porphyric Porphyry ( ) is a textural term for an igneous rock consisting of coarse-grained crystals such as feldspar or quartz dispersed in a fine-grained silicate-rich, generally aphanitic matrix or groundmass. The larger crystals are called phenocr ...
andesites formed a stratovolcano. During the Pliocene, ash and
pyroclastic Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyroc ...
eruptions formed a caldera with a diameter of , which also contains a central lava dome that formed 6.5 million years ago. Finally, probably during the Pleistocene, five iron-rich magmas were extruded, named Laco Sur, Laco Norte and Rodados Negros. Laquito and Cristales Grandes, two abyssal iron magma structures, date back to that era. The volcanic complex is located an altitude of and covers a surface area of with a minimum volume of of volcanic rock. The main summit, Pico Laco or Pitón El Laco, has an altitude of , although a maximum height of has also been reported. Pico Laco is an andesitic lava dome with a height of above the surrounding terrain. The dome, with dimensions of , has two summits: the higher eastern one and a western summit, and has also been described as a
volcanic plug A volcanic plug, also called a volcanic neck or lava neck, is a volcanic object created when magma hardens within a vent on an active volcano. When present, a plug can cause an extreme build-up of high gas pressure if rising volatile-charged mag ...
. Pico Laco has been described as a resurgent volcano within a
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
, that is surrounded by secondary vents. Other summits include the northwestern Hueso Chico, a cone with a height of above its surroundings and a crater wide. This cone is of dacitic composition. "Volcano 5009" is heavily eroded, and its core of lava and hyaloclastite has been exposed. It has a diameter of . Eruptive activity here probably coincided with glacier activity during the Pliocene, as evidenced by
moraine A moraine is any accumulation of unconsolidated debris (regolith and rock), sometimes referred to as glacial till, that occurs in both currently and formerly glaciated regions, and that has been previously carried along by a glacier or ice shee ...
s in the area. Ages of 10.5 to 1.6
mya Mya may refer to: Brands and product names * Mya (program), an intelligent personal assistant created by Motorola * Mya (TV channel), an Italian Television channel * Midwest Young Artists, a comprehensive youth music program Codes * Burmese ...
have been estimated via potassium-argon dating of the andesite lavas and subvolcanic rocks. An age of 5.3±1.9 mya on lavas in the northern part of the volcanic complex is the oldest obtained date. Other dating has resulted in ages of 3.9±1.3 mya for Pico Laco's dome, 3.8±0.9 mya for lavas beneath San Vicente Bayo, 3.7±0.9 mya for a lava front next to Laco Norte, 2.6±0.6 for Crystales Grandes, 2.1±0.4 for Hueso Chico, and 1.6±0.5 for "Volcano 5009". Cordon de Puntas Negras has younger dates. Another date from Pico Laco is 2.0±0.3 mya; one study suggested four separate episodes of volcano development. Volcanic activity continued after the emplacement of the magnetite bodies. Later alteration included hydrothermal alteration and glacial erosion; the former has left bleached rocks and exhalation deposits. Some minor metasomatic alteration occurred at the contact sites between andesites and iron-containing rocks. Hydrothermal alteration has also been described for lower portions of the volcanic pile and probably occurred because of gases escaping from intruded magma. Moraines found west of El Laco were generated by glaciation both on El Laco and Puntas Negras. Surface exposure dating has indicated ages of 226 and 287 ka for some ice-affected lavas and argon-argon dating produced a youngest age of about 120,000 years. Further, andesitic volcanism in neighbouring volcanoes has blanketed El Laco. Reports exist of continuing fumarolic activity and hot springs with the deposition of clay and other minerals.


Iron-rich deposits

On the flank of the volcano,
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...
,
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, and magnetite deposits are found at altitudes of . The volcano is mainly known for these flows, but such material is also found in the form of tephra. The deposits lie on top of flat lava flows of andesitic composition, concentrically around Pico Laco. They are named Laco Norte, Laco Sur, San Vicente Alto, and San Vicente Bajo. The deposits consist of dykes, hydrothermal deposits, lava flows, pyroclastics, and subvolcanic structures and were erupted from parasitic vents and fissures. The magnetite is classified as porphyry-like. Apatite is present as an accessory mineral in the lavas and is abundant in the intrusions. Iron-rich zones also formed in tuffs and lavas. Magnetite in the subvolcanic bodies exists in more massive crystals. The iron-containing rocks include lava flows, ash, and
lapilli Lapilli is a size classification of tephra, which is material that falls out of the air during a volcanic eruption or during some meteorite impacts. ''Lapilli'' (singular: ''lapillus'') is Latin for "little stones". By definition lapilli range f ...
, as well as ore breccias. The El Laco magnetite lava flows are unique in the world and formed during active subduction.


Individual deposits

Of these deposits, Laco Norte is the largest and was probably separated from neighbouring Laquito by erosion. It is thick and covers a surface area of . It was erupted from feeder dykes on its southern and eastern end and forms a table-shaped body on a spur, in the shape of a mesa. At Laco Norte, a structure of five layers is found: a basal andesite, ore in pyroclastic form, magnetite lava, pyroclastics which contain ore, and andesite at the top. Laco Sur has a similar morphology and dimensions of ; it has been mined. San Vicente Alto is a lava flow on the upper parts of the volcano (), and San Vicente Bajo is probably a lava dome (). Laquito ( long and wide) and Rodados Nortes () appear to be dykes, while Cristales Grandes ( long and up to wide) is more likely a vein and generally shows signs of hydrothermal formation. A magnetic layer of rock spreads north from the volcano, and a large magnetite body has been modelled beneath Pasos Blancos.


Structure and appearance

The magnetite lavas are primarily aa lava, but other surface features are also found, including pahoehoe features. Columnar morphologies are found on the magnetite, implying that they cooled quickly. There is only one other place in the world where columnar magnetite has been found – Kiirunavaara, in
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
. Large tubes coated on the inside by magnetite were formed in the lava by escaping gas. Both before and after the magnetite lavas, layers of magnetite-containing pyroclastics were erupted. A aureole separates the magnetite rocks from the host rocks. The magnetite lava flows are thick, the pyroclastics and respectively. The pyroclastic-like deposits are porous and fragile and show traces of stratification. The pyroclastics at Laco Sur contain spherules of magnetite. An age of 2.1±0.1 million years has been found for ore by fission track dating. The lavas contain veins likely generated by hydrothermal activity.


Origin

Temperatures estimated for the erupted rocks cover a wide range, with some exceeding . These rocks are of enigmatic origin, which may be geothermal or magmatic, with the presence of lava bombs of magnetite lava and other evidence supporting the magmatic origin theory. The magma would have separated from a precursor magma due to immiscibility effects. Other viewpoints consider the texture and chemical composition of the rocks as evidence that metasomatism of andesitic rocks formed the magnetite "lavas". A third hypothesis envisages the crystallization of magnetite within a silicic magma and its subsequent extraction through volatile bubbles. The role of a post-magmatic fluid phase, which was inferred from inclusions in crystals, or of a combination of magmatic and hydrothermal mechanisms has also been suggested. Some magnetite was oxidized to hematite, probably under the influence of rainwater as indicated by isotope analysis. Only a minor amount of hematite is primary. Isotope data indicate that the formation of this magnetite magma was accompanied by the segregation of plagioclase. This plagioclase may have generated the rhyodacite lava dome. An iron-phosphate-rich magma generated the magnetite lava flows after release of volatile substances. The magma was probably bordering on forming a two-phase melt containing
nelsonite Nelsonite is an igneous rock primarily constituted of ilmenite and apatite, with anatase, chlorite, phosphosiderite, talc and/or wavellite appearing as minor components. Rocks are equigranular with a grain size around 2 - 3 mm. The black ilme ...
and
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
. A favourable tectonic context associated with the compression of the magma chamber and the presence of faults helped with the eruption of the magnetite. The magma formation probably occurred in a magma chamber. During the cooling of the magma, the ores formed. This process was probably not directed by water-rich phases, and the segregation occurred at a shallow depth. High phosphorus and volatile content may have lowered the melting point of the magma and facilitated its eruption, as well as overcoming density-based constraints on the eruption of iron-rich magmas; the magma would later have forcefully degassed within the volcano. Suggestions that anatexis of iron-rich sediments generated the iron-rich magmas appear implausible. The ultimate origin of the El Laco iron may be subducted metal-containing sediment.


Human history and exploitation

These iron oxide deposits were found in 1958. Mining in Laco Sur removed about two million tons of magnetite between the 1970s and 1990s, leaving an open pit exposing of rock. In 2009, these mineral reserves were mined by Cia Minera del Pacifico S.A. It is estimated that the deposit contains 733.9 million tons of ore, consisting of 50% iron. The geological interest in these kinds of mineral deposits is enhanced by their frequent association with other minerals, as has been noted at Olympic Dam,
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
. Other magnetite-apatite ore deposits in the Andes are Incahuasi (10.3±0.8 mya), south of El Laco, and Magnetita Pedernales (Tertiary), about south-southwest of Laco.


Comparable deposits

The Kiruna magnetites in Sweden resemble the El Laco ones in terms of manganese and
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
content, and their titanium content is comparably low. The deposits at Kiruna and El Laco have been classified as "Iron oxide-apatite" ore deposits, and El Laco is the best preserved and youngest such deposit on Earth. Other deposits of volcanic iron ore are the
Chilean Iron Belt The Chilean Iron Belt is a geological province rich in iron ore deposits in northern Chile. It extends as a north-south beld along the western part of the Chilean regions of Coquimbo and Atacama, chiefly between the cities of La Serena and Talta ...
, the Tertiary Cerro el Mercado deposit in Mexico, the Eocambrian Bafq district in Iran, and the
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided ...
Kiruna field in Sweden. Of these, Sierra Bandera in the Chilean iron belt may be another example of surface volcanic iron ore rather than subvolcanic ore as is commonly assumed of these deposits.


Petrology

The main rocks of the volcano are andesite and dacite, which contain
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...
and
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
as well as blebs containing
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
. The iron-containing rocks are a less important component. The whole rock falls into the calc-alkaline class of volcanic rocks, similar to these erupted by the neighbouring volcanoes Lascar and Llullaillaco. The andesites contain plagioclase clinopyroxene,
orthopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
, and phenocrysts of magnetite. Magnetite, and in lesser measure hematite, are the most abundant iron minerals; anhydrite, diopside, goethite,
limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, maghemite, pyrite, scapolite and
diadochite Diadochite is a phospho-sulfate mineral. It is a secondary mineral formed by the weathering and hydration of other minerals. Its formula is Fe2(PO4)(SO4)OH·5H2O. Well crystallized forms are referred to as ''destinezite'', which has been given of ...
are also found. Erupted magma was probably gas-rich, as the magnetite lavas would otherwise have melting points of over . The lavas lost most of their
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
and phosphorus after their eruption. High oxygen-18 amounts in the Laco magmas indicate either crustal contamination or isotopic effects during
fractional crystallization Fractional crystallization may refer to: * Fractional crystallization (chemistry), a process to separate different solutes from a solution * Fractional crystallization (geology) Fractional crystallization, or crystal fractionation, is one of the ...
. Some
atmospheric water An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...
influence has been inferred from isotope data as well. Hydrothermal alteration of the central lava dome and iron-bearing deposits has generated
alunite Alunite is a hydroxylated aluminium potassium sulfate mineral, formula K Al3( S O4)2(O H)6. It was first observed in the 15th century at Tolfa, near Rome, where it was mined for the manufacture of alum. First called ''aluminilite'' by J.C. Del ...
, anatase, bassanite,
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
, copper veinlets, gypsum, illite, jarosite,
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
, labradorite, quartz, rutile, sanidine, smectite, sulfur and tridymite. Some of these minerals forms veins inside the rock. Silification is prominent and has formed cristobalite and tridymite. Elemental sulfur is also found. Vast regions of the volcano have been altered hydrothermally at temperatures of , giving the rock a clear appearance. Minor exhalation deposits are also found in the form of sulfates that sometimes conserve conduits. Red-coloured alteration halos occur in andesites adjacent to iron deposits, probably due to iron input. It is possible that the formation of the iron-rich magma was accompanied by the production of large amounts of hydrothermal fluids which then triggered the hydrothermal alteration.


Environment

The vegetation in the area is primarily low
bushland In Australia, bushland is a blanket term for land which supports remnant vegetation or land which is disturbed but still retains a predominance of the original floristics and structure. Human survival in bushland has a whole mythology evolving ...
.
Short-tailed chinchilla The short-tailed chinchilla (''Chinchilla chinchilla)'' is a small rodent part of the Chinchillidae family and is classified as an endangered species by the IUCN. Originating in South America, the chinchilla is part of the genus ''Chinchilla'', whic ...
s can be found at El Laco, one of the few occurrences of this threatened species in Chile. El Laco has a classical cold mountain climate at the line between the dry Altiplano with summer precipitation and the hyper-arid Atacama Desert climate. A nearby weather station () at altitude showed an average temperature of in 1991, with strong short-term variability. The majority of precipitation falls during southern hemisphere summer; winter snowfall has been recorded. Air humidity recorded in 1991 was 10–30%.


References


External links


El Laco field excursion
{{Authority control Iron ore mines in Chile Pleistocene stratovolcanoes Pliocene stratovolcanoes Miocene stratovolcanoes Volcanoes of Antofagasta Region Mines in Antofagasta Region