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Edward Armand Guggenheim FRS (11 August 1901 in Manchester – 9 August 1970) was an English
physical chemist Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical me ...
, noted for his contributions to
thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of the ...
.


Life

Guggenheim was born in
Manchester Manchester () is a city in Greater Manchester, England. It had a population of 552,000 in 2021. It is bordered by the Cheshire Plain to the south, the Pennines to the north and east, and the neighbouring city of Salford to the west. The t ...
11 August 1901, the son of Armand Guggenheim and Marguerite Bertha Simon. His father was
Swiss Swiss may refer to: * the adjectival form of Switzerland * Swiss people Places * Swiss, Missouri * Swiss, North Carolina *Swiss, West Virginia * Swiss, Wisconsin Other uses *Swiss-system tournament, in various games and sports *Swiss Internation ...
, a
naturalised Naturalization (or naturalisation) is the legal act or process by which a non-citizen of a country may acquire citizenship or nationality of that country. It may be done automatically by a statute, i.e., without any effort on the part of the i ...
British citizen British nationality law prescribes the conditions under which a person is recognised as being a national of the United Kingdom. The six different classes of British nationality each have varying degrees of civil and political rights, due to the ...
. Guggenheim married Simone Ganzin (died 1954), in 1934 and Ruth Helen Aitkin, born Clarke, widow, in 1955. They had no children. He died in
Reading, Berkshire Reading ( ) is a town and borough in Berkshire, Southeast England, southeast England. Located in the Thames Valley at the confluence of the rivers River Thames, Thames and River Kennet, Kennet, the Great Western Main Line railway and the M4 mot ...
9 August 1970.


Education

Guggenheim was educated at
Terra Nova School Terra Nova School is a prep school in Cheshire, England for children from two and a half to thirteen years of age. It began as a school for boys in 1897, and today educates boys and girls. Children aged two and a half to seven attend the pre-pr ...
,
Southport Southport is a seaside town in the Metropolitan Borough of Sefton in Merseyside, England. At the 2001 census, it had a population of 90,336, making it the eleventh most populous settlement in North West England. Southport lies on the Irish ...
,
Charterhouse School (God having given, I gave) , established = , closed = , type = Public school Independent day and boarding school , religion = Church of England , president ...
and
Gonville and Caius College, Cambridge Gonville and Caius College, often referred to simply as Caius ( ), is a constituent college of the University of Cambridge in Cambridge, England. Founded in 1348, it is the fourth-oldest of the University of Cambridge's 31 colleges and one of th ...
, where he obtained firsts in both the mathematics part 1 and chemistry part 2 triposes. Unable to gain a fellowship at the college, he went to
Denmark ) , song = ( en, "King Christian stood by the lofty mast") , song_type = National and royal anthem , image_map = EU-Denmark.svg , map_caption = , subdivision_type = Sovereign state , subdivision_name = Danish Realm, Kingdom of Denmark ...
where he studied under J. N. Brønsted at the
University of Copenhagen The University of Copenhagen ( da, Københavns Universitet, KU) is a prestigious public university, public research university in Copenhagen, Copenhagen, Denmark. Founded in 1479, the University of Copenhagen is the second-oldest university in ...
.


Career

Returning to England, he found a place at
University College In a number of countries, a university college is a college institution that provides tertiary education but does not have full or independent university status. A university college is often part of a larger university. The precise usage varies ...
, London where he wrote his first book, ''Modern Thermodynamics by the Methods of
Willard Gibbs Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American scientist who made significant theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynamics was instrumental in t ...
'' (1933), which "established his reputation and revolutionized the teaching of the subject". He was also a visiting professor of chemistry at
Stanford University Stanford University, officially Leland Stanford Junior University, is a private research university in Stanford, California. The campus occupies , among the largest in the United States, and enrolls over 17,000 students. Stanford is consider ...
, and later became a reader in the
chemical engineering Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials int ...
department at
Imperial College London Imperial College London (legally Imperial College of Science, Technology and Medicine) is a public research university in London, United Kingdom. Its history began with Prince Albert, consort of Queen Victoria, who developed his vision for a cu ...
. During
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
he worked on defence matters for the
navy A navy, naval force, or maritime force is the branch of a nation's armed forces principally designated for naval warfare, naval and amphibious warfare; namely, lake-borne, riverine, littoral zone, littoral, or ocean-borne combat operations and ...
. In 1946 he was appointed professor of chemistry and head of department at
Reading University The University of Reading is a public university in Reading, Berkshire, England. It was founded in 1892 as University College, Reading, a University of Oxford extension college. The institution received the power to grant its own degrees in 192 ...
, where he stayed until his retirement in 1966.


Publications

Guggenheim produced eleven books and more than 100 papers. His first book,''Modern Thermodynamics by the Methods of Willard Gibbs'' (1933), was a 206-page, detailed study, with text, figures, index, and preface by F. G. Donnan, showing how the analytical thermodynamic methods developed by
Willard Gibbs Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American scientist who made significant theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynamics was instrumental in t ...
leads in a straightforward manner to relations such as phases, constants, solution, systems, and laws, that are unambiguous and exact. This book, together with Gilbert N. Lewis and
Merle Randall Merle Randall (January 29, 1888 – March 17, 1950) was an American physical chemist famous for his work with Gilbert N. Lewis, over a period of 25 years, in measuring reaction heat of chemical compounds and determining their corresponding free ...
's 1923 textbook ''Thermodynamics and the Free Energy of Chemical Substances'', are said to be responsible for the inception of the modern science of
chemical thermodynamics Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurement ...
. Other books included ''Statistical Thermodynamics'' with Ralph Fowler (1939), and ''Thermodynamics – an Advanced Treatment for Chemists and Physicists'' . In the preface to this book, he states that no thermodynamics book written before 1929 even attempts an account of any of the following matters: # The modern definition of heat given by
Max Born Max Born (; 11 December 1882 – 5 January 1970) was a German physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a n ...
in 1921. # The quantal theory of the
entropy Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynam ...
of gases and its experimental verification. #
Peter Debye Peter Joseph William Debye (; ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born Petrus Josephus Wilhelmus Debije in Maastricht, Netherlands, D ...
's formulae for the
activity coefficient In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or ...
s of
electrolytes An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon di ...
. # The use of
electrochemical potential In electrochemistry, the electrochemical potential (ECP), ', is a thermodynamic measure of chemical potential that does not omit the energy contribution of electrostatics. Electrochemical potential is expressed in the unit of J/ mol. Introductio ...
s of ions # The application of thermodynamics to dielectrics and to paramagnetic substances.


Honours and awards

Guggenheim was elected a Fellow of the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
in 1946. His nomination reads In 1972, the E. A. Guggenheim Memorial Fund was established by friends and colleagues. The income from the fund is used to (a) award an annual prize and (b) to provide a biennial or triennial memorial lecture on some topic of chemistry or physics appropriate to the interests of Guggenheim.E. A. Guggenheim Memorial Fund
– established in 1972
The Guggenheim Medal was introduced in 2014 by the
Institution of Chemical Engineers The Institution of Chemical Engineers (IChemE) is a global professional engineering institution with over 33,000 members worldwide. It was founded in 1922 and awarded a Royal Charter in 1957. It has offices in Rugby, London, Melbourne, Wellingto ...
for significant contributions to research in thermodynamics and / or complex fluids. The first recipient (in 2015) was Professor George Jackson of
Imperial College London Imperial College London (legally Imperial College of Science, Technology and Medicine) is a public research university in London, United Kingdom. Its history began with Prince Albert, consort of Queen Victoria, who developed his vision for a cu ...
.www.icheme.org
George Jackson receives first Guggenheim medal
''The Chemical Engineer'', March 2015 p 52 "Winners of 2014 medals announced"


See also

* Guggenheim scheme * Stavermann–Guggenheim equation *
Bromley equation The Bromley equation was developed in 1973 by Leroy A. Bromley with the objective of calculating activity coefficients for aqueous electrolyte solutions whose concentrations are above the range of validity of the Debye–Hückel equation. This equ ...
*
Entropy (energy dispersal) The interpretation of entropy as a measure of energy dispersal has been exercised against the background of the traditional view, introduced by Ludwig Boltzmann, of entropy as a quantitative measure of disorder. The energy dispersal approach avoids ...
*
Non-random two-liquid model The non-random two-liquid model (abbreviated NRTL model) is an activity coefficient model that correlates the activity coefficients \gamma_i of a compound with its mole fractions x_i in the liquid phase concerned. It is frequently applied in the f ...
*
Specific ion interaction theory In theoretical chemistry, Specific ion Interaction Theory (SIT theory) is a theory used to estimate single-ion activity coefficients in electrolyte solutions at relatively high concentrations. It does so by taking into consideration ''interaction ...
*
Thermodynamic activity In chemical thermodynamics, activity (symbol ) is a measure of the "effective concentration" of a species in a mixture, in the sense that the species' chemical potential depends on the activity of a real solution in the same way that it would depen ...


References

{{DEFAULTSORT:Guggenheim, Edward A 1901 births 1970 deaths People educated at Charterhouse School Alumni of Gonville and Caius College, Cambridge English chemists Thermodynamicists Academics of the University of Reading Fellows of the Royal Society