Decarburization (or decarbonization) is the process of decreasing

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...

content, which is the opposite of

carburization Carburising, carburizing (chiefly American English), or carburisation is a heat treatment process in which iron or steel absorbs carbon while the metal is heated in the presence of a carbon-bearing material, such as charcoal or carbon monoxide. ...

. The term is typically used in metallurgy, describing the decrease of the content of

metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...

s (usually

steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...

). Decarburization occurs when the metal is heated to temperatures of 700 °C or above when carbon in the metal reacts with gases containing

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...

. The removal of carbon removes hard

carbide In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece. Interstitial / Metallic carbides The carbides of the ...

phases resulting in a softening of the metal, primarily at the surfaces which are in contact with the decarburizing gas. Decarburization can be either advantageous or detrimental, depending on the application for which the metal will be used. It is thus both something that can be done intentionally as a step in a manufacturing process, or something that happens as a side effect of a process (such as

rolling Rolling is a type of motion that combines rotation (commonly, of an axially symmetric object) and translation of that object with respect to a surface (either one or the other moves), such that, if ideal conditions exist, the two are in contact ...

) and must be either prevented or later reversed (such as via a carburization step). The decarburization mechanism can be described as three distinct events: the reaction at the steel surface, the interstitial diffusion of carbon atoms and the dissolution of carbides within the steel.

Chemical reactions

The most common reactions are: :C + CO2 <=> 2CO also called the

Boudouard reaction The Boudouard reaction, named after Octave Leopold Boudouard, is the redox reaction of a chemical equilibrium mixture of carbon monoxide and carbon dioxide at a given temperature. It is the disproportionation of carbon monoxide into carbon dioxide ...

:C + H2O <=> CO + H2 :C + 2H2 <=> CH4 Other reactions are :C + 1/2O2 -> CO :C + O2 -> CO2 :C + FeO -> CO + Fe

Electrical steel

Electrical steel Electrical steel (E-steel, lamination steel, silicon electrical steel, silicon steel, relay steel, transformer steel) is an iron alloy tailored to produce specific magnetic properties: small hysteresis area resulting in low power loss per cycle ...

is one material that uses decarburization in its production. To prevent the atmospheric gases from reacting with the metal itself, electrical steel is annealed in an atmosphere of

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

, and

water vapor (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous pha ...

, where oxidation of the

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

is specifically prevented by the proportions of hydrogen and water vapor so that the only reacting substance is carbon being made into

carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...

Stainless steel

Stainless steel Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...

contains additives which are highly oxidizable, such as

chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardne ...

and

molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lea ...

. Such steels can only be decarburized by reacting with dry hydrogen, which has no water content, unlike wet hydrogen, which is produced in a way that includes some water and can otherwise be used for decarburization.

As a secondary effect

Incidental decarburization can be detrimental to surface properties in products (where carbon content is desirable) when done during

heat treatment Heat treating (or heat treatment) is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also ...

or after rolling or forging, because the material is only affected to a certain depth according to the temperature and duration of heating. This can be prevented by using an inert or reduced-pressure atmosphere, applying

resistive heating Joule heating, also known as resistive, resistance, or Ohmic heating, is the process by which the passage of an electric current through a conductor (material), conductor produces heat. Joule's first law (also just Joule's law), also known in c ...

for a short duration, by limiting the time that material is under high heat, as is done in a walking-beam furnace, or through restorative carburization, which uses a

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...

atmosphere to transfer carbon into the surface of the material during annealing. The decarburized surface material can also be removed by

grinding Grind is the cross-sectional shape of a blade. Grind, grinds, or grinding may also refer to: Grinding action * Grinding (abrasive cutting), a method of crafting * Grinding (dance), suggestive club dancing * Grinding (video gaming), repetitive and ...

References

External links