David Henry Solomon
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David Henry Solomon (born 19 November 1929 in Adelaide, South Australia) is an Australian polymer chemist. He is best known for his work in developing Living Radical Polymerization techniques, and
polymer banknote Polymer banknotes are banknotes made from a synthetic polymer such as biaxially oriented polypropylene (BOPP). Such notes incorporate many security features not available in paper banknotes, including the use of metameric inks. Polymer banknote ...
s.


Education

Solomon received an Associate of Sydney Technical College, (equivalent to a Diploma of Chemistry) in 1950 and went on to complete a Bachelor of Science (BSc (Hons)) in 1952 from the New South Wales University of Technology (now the
University of New South Wales The University of New South Wales (UNSW), also known as UNSW Sydney, is a public research university based in Sydney, New South Wales, Australia. It is one of the founding members of Group of Eight, a coalition of Australian research-intensiv ...
), a Master of Science (MSc) from the same university in 1955, and a PhD from the University of New South Wales in 1959 with a thesis entitled ''Studies on the Chemistry of Carbonyl Compounds''. In 1968 he was awarded a DSc from the University of New South Wales for his thesis ''Studies on the Chemistry of Coating Compounds''.University of Melbourne profile page
. Retrieved 10 June 2016.
He also received an
Honorary Doctorate An honorary degree is an academic degree for which a university (or other degree-awarding institution) has waived all of the usual requirements. It is also known by the Latin phrases ''honoris causa'' ("for the sake of the honour") or ''ad hon ...
in Applied Science from the
University of Melbourne The University of Melbourne is a public research university located in Melbourne, Australia. Founded in 1853, it is Australia's second oldest university and the oldest in Victoria. Its main campus is located in Parkville, an inner suburb no ...
in 2005, one of only seven awarded in the University's history.


Career

Solomon joined British Australian Lead Manufacturers Pty Ltd (BALM, which later became Dulux Australia Ltd) as a trainee chemist in 1946 at the age of 16. It was here that he developed his lifelong interest in polymers, and made important observations that the current theories on polymers did not match with what was actually happening in the industrial processes. Solomon's strong interest in polymer research drew him to join CSIRO as a senior research scientist in the Division of Applied Mineralogy in 1963. In 1970 Solomon transferred to the Division of Applied Chemistry where he established the Polymer Research Group, before going on to become chief of the Division of Applied Organic Chemistry during a reorganisation in 1974, a position he held for the next 17 years. In 1990 he accepted an invitation to become the ICI Australia – Masson Professor and head of the School of Chemistry at the University of Melbourne. Here he started the Polymer Science Group,Polymer Science Group website
his third internationally acclaimed polymer research group. After ‘retirement’ in 1995 David took up the position of honorary professorial fellow in the Department of Chemical and Biomolecular Engineering at the university, moving the Polymer Science Group, to which he still acts as senior advisor. In 2015 he was awarded the title of professor emeritus at the University of Melbourne. Solomon is often referred to as the father of polymer research in Australia, having established three internationally acclaimed polymer research groups in industry (Dulux, 1960), in Australia's peak scientific research organisation, CSIRO (1970) and at the University of Melbourne (1990).


Research achievements

Solomon is well known for several of his research achievements. In particular his work on free radical polymerization revolutionized the field through the development of the first
living free-radical polymerization Living free radical polymerization is a type of living polymerization where the active polymer chain end is a free radical. Several methods exist. IUPAC recommends to use the term " reversible-deactivation radical polymerization" instead of "liv ...
technique; Nitroxide Mediated Polymerization (NMP). He also led the team, and was principal inventor of the world's first
polymer banknote Polymer banknotes are banknotes made from a synthetic polymer such as biaxially oriented polypropylene (BOPP). Such notes incorporate many security features not available in paper banknotes, including the use of metameric inks. Polymer banknote ...
.


Free Radical Polymerization

Solomon's ground-breaking work on free radical polymerization was initiated through observations made in industry. For example, anomalies that were not explained by polymerization theory at the time, and the observation that during the production of polymer/mineral composites some batches underwent spontaneous combustion. This led to discoveries that had significant influence on the future directions of radical chemistry. It led to the development of Nitroxide Mediated Polymerization (NMP), the first example of a controlled, or living, radical polymerization technique. This research also produced early examples of what was to become known as RAFT, or
Reversible addition−fragmentation chain-transfer polymerization Reversible addition−fragmentation chain-transfer or RAFT polymerization is one of several kinds of reversible-deactivation radical polymerization. It makes use of a chain-transfer agent in the form of a thiocarbonylthio compound (or similar, fr ...
. Solomon's work rewrote the theory on
free radical polymerization In polymer chemistry, free-radical polymerization (FRP) is a method of polymerization by which a polymer forms by the successive addition of free-radical building blocks ( repeat units). Free radicals can be formed by a number of different mechani ...
, and he was co-author with Graeme Moad on the definitive reference book: The Chemistry of Radical Polymerization (Moad & Solomon, 2006). Previous theories attempted to explain
radical polymerization In polymer chemistry, free-radical polymerization (FRP) is a method of polymerization by which a polymer forms by the successive addition of free-radical building blocks ( repeat units). Free radicals can be formed by a number of different mechani ...
on the basis of thermodynamic stability controlling structure. Solomon's work showed that kinetics was the major factor in controlling the way polymer chains formed.


Polymer banknotes

Following a major forgery of Australia's newly introduced $10 notes in 1967, Solomon was invited to a meeting about how to make more secure bank notes. Given his background in polymer science Solomon's idea was to print the notes on a
plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...
substrate rather than the traditional paper, and incorporate
optically variable devices An optical variable device or optically variable device (OVD) is an iridescent or non-iridescent security feature that exhibits different information, such as movement or colour changes, depending on the viewing and/or lighting conditions. The par ...
– defined as a device that changes its appearance when something external is done to the note. Solomon went on to lead the research team and was the principal inventor of the world's first polymer banknote, with the first note issued into circulation in 1988: the Australian bicentennial $10. He has chronicled the history of the development of polymer banknotes in ''The Plastic Banknote: From Concept to Reality'', co-authored with Tom Spurling (published in 2014).''The Plastic Banknote: From Concept to Reality'', David Solomon & Tom Spurling, CSIRO Publishing, 2014,


Selected honours

Solomon has been the recipient of numerous prestigious awards throughout his career. A selected list is outlined below. * 2016
Companion of the Order of Australia The Order of Australia is an honour that recognises Australian citizens and other persons for outstanding achievement and service. It was established on 14 February 1975 by Elizabeth II, Queen of Australia, on the advice of the Australian Gove ...
. * 2011 Prime Minister's Prize for Science, awarded jointly with Dr Ezio Rizzardo. * 2006 Victoria Prize. * 2001 Centenary Medal. * 1994 Clunies Ross National Science and Technology Award. * 1990
Member of the Order of Australia The Order of Australia is an Order (distinction), honour that recognises Australian citizens and other persons for outstanding achievement and service. It was established on 14 February 1975 by Elizabeth II, Monarchy of Australia, Queen of Aus ...
. * 1989 Ian William Wark Medal and Lecture.


Professional societies

Solomon's considerable contributions to science have been recognised by his peers through election to the following Academies: * Fellow of the Institution of Chemical Engineers (FIChemE, 2007) * Fellow of the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
( FRS, 2004). * Foundation Fellow of the Australian Academy of Technological Sciences and Engineering ( FTSE, 1976). * Fellow of the
Australian Academy of Science The Australian Academy of Science was founded in 1954 by a group of distinguished Australians, including Australian Fellows of the Royal Society of London. The first president was Sir Mark Oliphant. The academy is modelled after the Royal Soc ...
(
FAA The Federal Aviation Administration (FAA) is the largest transportation agency of the U.S. government and regulates all aspects of civil aviation in the country as well as over surrounding international waters. Its powers include air traffic m ...
, 1975). * Fellow of the
Royal Australian Chemical Institute The Royal Australian Chemical Institute (RACI) is both the qualifying body in Australia for professional chemists and a learned society promoting the science and practice of chemistry in all its branches. The RACI hosts conferences, seminars and ...
(FRACI, 1966) Solomon has always been active in these societies, in particular the Royal Australian Chemical Institute (RACI). In 2001 the RACI established the Solomon Lecture Series in recognition of his contribution to the field and to the RACI. A biennial series presented by an invited leading international polymer researcher, this Lecture Series recognizes the importance of promoting the exchange of ideas and expertise and to expose young scientists to the best in their field internationally.


Publications

Solomon is co-author of nine books including an historical account of the development of plastic banknotes (The Plastic Banknote: From Concept to Reality) and several text books (incl: The Chemistry of Radical Polymerization).''The Chemistry of Radical Polymerization'', Second Edition, G. Moad & D.H. Solomon, Elsevier, 2006 He is also co-author of over 250 journal papers and 45 patents.


References

{{DEFAULTSORT:Solomon, David Henry 1929 births Polymer chemistry Living people Australian chemists Members of the Order of Australia Companions of the Order of Australia Fellows of the Royal Society Fellows of the Australian Academy of Science Fellows of the Australian Academy of Technological Sciences and Engineering Recipients of the Centenary Medal