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Dynamite is an
explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
made of
nitroglycerin Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating g ...
, sorbents (such as powdered shells or clay), and stabilizers. It was invented by the
Swedish Swedish or ' may refer to: Anything from or related to Sweden, a country in Northern Europe. Or, specifically: * Swedish language, a North Germanic language spoken primarily in Sweden and Finland ** Swedish alphabet, the official alphabet used by ...
chemist and engineer
Alfred Nobel Alfred Bernhard Nobel ( , ; 21 October 1833 – 10 December 1896) was a Swedes, Swedish chemist, engineer, inventor, businessman, and Philanthropy, philanthropist. He is best known for having bequeathed his fortune to establish the Nobel ...
in Geesthacht, Northern Germany, and patented in 1867. It rapidly gained wide-scale use as a more robust alternative to
black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
.


History

Dynamite was invented by Swedish chemist
Alfred Nobel Alfred Bernhard Nobel ( , ; 21 October 1833 – 10 December 1896) was a Swedes, Swedish chemist, engineer, inventor, businessman, and Philanthropy, philanthropist. He is best known for having bequeathed his fortune to establish the Nobel ...
in the 1860s and was the first safely manageable explosive stronger than
black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
. Alfred Nobel's father,
Immanuel Nobel Immanuel Nobel the Younger ( , ; 24 March 1801 – 3 September 1872) was a Swedish engineer, architect, inventor and industrialist. He was the inventor of the rotary lathe used in plywood manufacturing. He was a member of the Nobel family and the ...
, was an industrialist, engineer, and inventor. He built bridges and buildings in Stockholm and founded Sweden's first rubber factory. His construction work inspired him to research new methods of blasting rock that were more effective than black powder. After some bad business deals in Sweden, in 1838 Immanuel moved
his family ''His Family'' is a novel by Ernest Poole published in 1917 about the life of a New York widower and his three daughters in the 1910s. It received the first Pulitzer Prize for the Novel in 1918. Plot introduction ''His Family'' tells the story of ...
to Saint Petersburg, where Alfred and his brothers were educated privately under Swedish and Russian tutors. At age 17, Alfred was sent abroad for two years; in the United States he met Swedish engineer
John Ericsson John Ericsson (born Johan Ericsson; July 31, 1803 – March 8, 1889) was a Swedish-American inventor. He was active in England and the United States. Ericsson collaborated on the design of the railroad steam locomotive ''Novelty'', which com ...
and in France studied under famed chemist Théophile-Jules Pelouze and his pupil
Ascanio Sobrero Ascanio Sobrero (12 October 1812 – 26 May 1888) was an Italian chemist, born in Casale Monferrato. He was studying under Théophile-Jules Pelouze at the University of Turin, who had worked with the explosive material guncotton. He studied me ...
, who had first synthesized
nitroglycerin Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating g ...
in 1847. In France Nobel encountered nitroglycerin, which Pelouze cautioned against using as a commercial explosive because of its great sensitivity to shock. In 1857, Nobel filed the first of several hundred patents, mostly concerning air pressure, gas and fluid gauges, but remained fascinated with nitroglycerin's potential as an explosive. Nobel, along with his father and brother
Emil Emil or Emile may refer to: Literature *''Emile, or On Education'' (1762), a treatise on education by Jean-Jacques Rousseau * ''Émile'' (novel) (1827), an autobiographical novel based on Émile de Girardin's early life *''Emil and the Detective ...
, experimented with various combinations of nitroglycerin and black powder. Nobel came up with a solution of how to safely detonate nitroglycerin by inventing the
detonator A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electri ...
, or blasting cap, that allowed a controlled explosion set off from a distance using a
fuse Fuse or FUSE may refer to: Devices * Fuse (electrical), a device used in electrical systems to protect against excessive current ** Fuse (automotive), a class of fuses for vehicles * Fuse (hydraulic), a device used in hydraulic systems to protect ...
. In 1863 Nobel performed his first successful detonation of pure nitroglycerin, using a blasting cap made of a copper percussion cap and mercury fulminate. In 1864, Alfred Nobel filed patents for both the blasting cap and his method of synthesizing nitroglycerin, using sulfuric acid, nitric acid and glycerin. On 3 September 1864, while experimenting with nitroglycerin, Emil and several others were killed in an explosion at the factory at Immanuel Nobel's estate at Heleneborg. After this, Alfred founded the company Nitroglycerin Aktiebolaget in Vinterviken to continue work in a more isolated area and the following year moved to Germany, where he founded another company,
Dynamit Nobel Dynamit Nobel AG is a German chemical and weapons company whose headquarters is in Troisdorf, Germany. It was founded in 1865 by Alfred Nobel. Creation After the death of his younger brother Emil in an 1864 nitroglycerin explosion at the famil ...
. Despite the invention of the blasting cap, the instability of nitroglycerin rendered it useless as a commercial explosive. To solve this problem, Nobel sought to combine it with another substance that would make it safe for transport and handling but would not reduce its effectiveness as an explosive. He tried combinations of cement, coal, and sawdust, but was unsuccessful. Finally, he tried
diatomaceous earth Diatomaceous earth (), diatomite (), or kieselgur/kieselguhr is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3  μm to le ...
, fossilized algae, that he brought from the Elbe River near his factory in Hamburg, which successfully stabilized the nitroglycerin into a portable explosive. Nobel obtained patents for his inventions in England on 7 May 1867 and in Sweden on 19 October 1867.Schück & Sohlman (1929), p. 101. After its introduction, dynamite rapidly gained wide-scale use as a safe alternative to black powder and nitroglycerin. Nobel tightly controlled the patents, and unlicensed duplicating companies were quickly shut down. A few American businessmen got around the patent by using absorbents other than diatomaceous earth, such as resin.US Patent 234489 issued to Morse 16 November 1880 Nobel originally sold dynamite as "Nobel's Blasting Powder" but decided to change the name to dynamite, from the Ancient Greek word ''dýnamis'' (), meaning "power".


Manufacture


Form

Dynamite is usually sold in the form of cardboard cylinders about long and about in diameter, with a weight of about . A stick of dynamite thus produced contains roughly 1 MJ (
megajoule The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applied. ...
) of energy. Other sizes also exist, rated by either portion (Quarter-Stick or Half-Stick) or by weight. Dynamite is usually rated by "weight strength" (the amount of nitroglycerin it contains), usually from 20% to 60%. For example, ''40% dynamite'' is composed of 40% nitroglycerin and 60% "dope" (the absorbent storage medium mixed with the stabilizer and any additives).


Storage considerations

The maximum shelf life of nitroglycerin-based dynamite is recommended as one year from the date of manufacture under good storage conditions. Over time, regardless of the sorbent used, sticks of dynamite will "weep" or "sweat" nitroglycerin, which can then pool in the bottom of the box or storage area. For that reason, explosive manuals recommend the regular up-ending of boxes of dynamite in storage. Crystals will form on the outside of the sticks, causing them to be even more sensitive to shock, friction, and temperature. Therefore, while the risk of an explosion without the use of a blasting cap is minimal for fresh dynamite, old dynamite is dangerous. Modern packaging helps eliminate this by placing the dynamite into sealed plastic bags and using wax-coated cardboard. Dynamite is moderately sensitive to shock. Shock resistance tests are usually carried out with a drop-hammer: about 100 mg of explosive is placed on an anvil, upon which a weight of between is dropped from different heights until detonation is achieved. With a hammer of 2 kg, mercury fulminate detonates with a drop distance of 1 to 2 cm, nitroglycerin with 4 to 5 cm, dynamite with 15 to 30 cm, and ammoniacal explosives with 40 to 50 cm.


Major manufacturers


South Africa

For several decades beginning in the 1940s, the largest producer of dynamite in the world was the Union of South Africa. There the
De Beers De Beers Group is an international corporation that specializes in diamond mining, diamond exploitation, diamond retail, diamond trading and industrial diamond manufacturing sectors. The company is active in open-pit, large-scale alluvial and c ...
company established a factory in 1902 at Somerset West. The explosives factory was later operated by
AECI AECI Limited () is a South African chemicals group and is listed on the JSE Securities Exchange. History The company was registered as ''African Explosives and Industries '' (AE&I) in 1924, with its headquarters in Johannesburg. It was formed as ...
(African Explosives and Chemical Industries). The demand for the product came mainly from the country's vast gold mines, centered on the Witwatersrand. The factory at Somerset West was in operation in 1903 and by 1907 it was already producing 340,000 cases, each, annually. A rival factory at Modderfontein was producing another 200,000 cases per year. There were two large explosions at the Somerset West plant during the 1960s. Some workers died, but the loss of life was limited by the modular design of the factory and its earth works, and the planting of trees that directed the blasts upward. There were several other explosions at the Modderfontein factory. After 1985, pressure from trade unions forced AECI to phase out the production of dynamite. The factory then went on to produce ammonium nitrate emulsion-based explosives that are safer to manufacture and handle.


United States

Dynamite was first manufactured in the US by the Giant Powder Company of San Francisco, California, whose founder had obtained the exclusive rights from Nobel in 1867. Giant was eventually acquired by
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
, which produced dynamite under the Giant name until Giant was dissolved by DuPont in 1905. Thereafter, DuPont produced dynamite under its own name until 1911–12, when its explosives monopoly was broken up by the U.S. Circuit Court in the "Powder Case". Two new companies were formed upon the breakup, the
Hercules Powder Company Hercules, Inc. was a chemical and munitions manufacturing company based in Wilmington, Delaware, United States, incorporated in 1912 as the Hercules Powder Company following the breakup of the DuPont explosives monopoly by the U.S. Circuit ...
and the
Atlas Powder Company Atlas Powder Company was an American explosives and chemicals company. It was one of the two companies that emerged out of a court-ordered breakup of the explosives monopoly of Du Pont Powder Company, the explosives and gunpowder company founded ...
, which took up the manufacture of dynamite (in different formulations). Currently, only
Dyno Nobel Dyno Nobel is a manufacturer of explosives. It is a wholly owned subsidiary of Incitec Pivot Limited operating in Australia, Canada, the United States, Africa, Indonesia, Mexico, South America, Papua New Guinea and Turkey. They provide the expl ...
manufactures dynamite in the US. The only facility producing it is located in Carthage, Missouri, but the material is purchased from Dyno Nobel by other manufacturers who put their labels on the dynamite and boxes.


Non-dynamite explosives

Other explosives are often referred to or confused with dynamite:


TNT

TNT is most commonly assumed to be the same as (or confused for) dynamite, largely due to the ubiquity of both explosives during the 20th century and the civilian practice of preparing dynamite charges in "sticks" wrapped in red waxed paper and shaped to fit the cylindrical boreholes drilled in the rock face. This incorrect connection between TNT and dynamite was enhanced by Bugs Bunny cartoons where animators started labeling ''any'' kind of cartoon bomb (ranging from sticks of dynamite to kegs of
black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
) as "TNT" because the acronym was shorter and more memorable and did not require literacy to recognize "TNT" meant "bomb" (similar to the use of XXX markings on whiskey bottles and barrels in cartoons). This eventually led to the general perception that TNT and dynamite were one and the same. In actuality, aside from both being high explosives, TNT and dynamite have very little in common: TNT, or trinitrotoluene, is a second generation castable explosive adopted by the military. The German armed forces adopted it as a filling for artillery shells in 1902, some 40 years after the invention of dynamite, which is a first generation
phlegmatized explosive A phlegmatized explosive is an explosive that has had an agent (a phlegmatizer) added to stabilize or desensitize it. Phlegmatizing usually improves the handling properties of an explosive (e.g. when munitions are filled in factories. Alfred ...
primarily intended for civilian earthmoving. TNT has never been popular or widespread in civilian earthmoving, as it is considerably more expensive and less powerful by weight than dynamite,J. Köhler, R. Meyer, A. Homburg: ''Explosivstoffe''. Zehnte, vollständig überarbeitete Auflage. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2008, . as well as being slower to mix and pack into cylindrical boreholes; for its part, dynamite has never been popular in warfare because it degenerates quickly under severe conditions and can be detonated by either fire or a wayward bullet. TNT's primary asset is its remarkable insensitivity and stability: it is waterproof and incapable of detonating without the extreme shock and heat provided by a blasting cap (or a sympathetic detonation); this conveniently also allows it to be melted at , poured into high explosive shells and allowed to re-solidify with no extra danger or change in the TNT's characteristics. Accordingly, more than 90% of the TNT produced in America was always for the military market, with most filling shells, hand grenades and aerial bombs and the remainder being packaged in brown "bricks" (not red cylinders) for use as
demolition charges Demolition (also known as razing, cartage, and wrecking) is the science and engineering in safely and efficiently tearing down of buildings and other artificial structures. Demolition contrasts with deconstruction, which involves taking a bu ...
by combat engineers.


"Extra" dynamite

In the United States, in 1885, the chemist Russell S. Penniman invented "ammonium dynamite", a form of explosive that used ammonium nitrate as a substitute for the more costly nitroglycerin. Ammonium nitrate has only 85% of the
chemical energy Chemical energy is the energy of chemical substances that is released when they undergo a chemical reaction and transform into other substances. Some examples of storage media of chemical energy include batteries, Schmidt-Rohr, K. (2018). "How ...
of nitroglycerin. It is rated by either "weight strength" (the amount of ammonium nitrate in the medium) or "cartridge strength" (the potential explosive strength generated by an amount of explosive of a certain density and grain size used in comparison to the explosive strength generated by an equivalent density and grain size of a standard explosive). For example, high-explosive ''65% Extra dynamite'' has a weight strength of 65% ammonium nitrate and 35% "dope" (the absorbent medium mixed with the stabilizers and additives). Its "cartridge strength" would be its weight in pounds times its strength in relation to an equal amount of ANFO (the civilian baseline standard) or TNT (the military baseline standard). For example, 65% ammonium dynamite with a 20% cartridge strength would mean the stick was equal to an equivalent weight strength of 20% ANFO.


"Military dynamite"

"Military dynamite" is a dynamite substitute, formulated without nitroglycerin. It contains 75%
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...
, 15% TNT, 5% SAE 10 motor oil, and 5% cornstarch, but is much safer to store and handle for long periods than Nobel's dynamite. Military dynamite substitutes much more stable chemicals for nitroglycerin.


Regulation

Various countries around the world have enacted explosives laws and require licenses to manufacture, distribute, store, use, and possess explosives or ingredients.


See also

* Blast fishing *
Blasting machine A blasting machine or shot exploder is a portable source of electric current to reliably fire a blasting cap to trigger a main explosive charge. It is mostly used in mining and demolition. The use of the term "machine" dates from early designs ...
* Dynamite gun * Nobel Prize * Relative effectiveness factor


References


Further reading

* Cartwright, A. P. (1964). ''The dynamite Company: The Story of African Explosives and Chemical Industries Limited''. Cape Town: Purnell & Sons (S.A.) (Pty) Ltd. * * Schück, H. and Sohlman, R. (1929). ''The Life of Alfred Nobel''. London: William Heinemann Ltd.


External links


Alfred Nobel’s dynamite companies

Oregon State Police – Arson and Explosives Section (Handling instructions and photos)
* * Improved process of producing an explosive compound

at '' The Periodic Table of Videos'' (University of Nottingham) {{Authority control Alfred Nobel Explosives Swedish inventions 1867 introductions 19th-century inventions