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TNT
Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts. History TNT was first prepared in 1863 by German chemist Julius Wilbrand and originally used as a yellow dye. Its potential as an explosive was not recognized for three decades, mainly because it was too difficult to detonate because it was less sensitive than alternatives. Its explosive properties were first discovered in 1891 by another German chemist, Carl Häussermann. TNT can be safely poured when liquid into shell cases, and is so insensitive that in ...
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TNT Equivalent
TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. The is a unit of energy defined by that convention to be , which is the approximate energy released in the detonation of a metric ton (1,000 kilograms) of TNT. In other words, for each gram of TNT exploded, (or 4184 joules) of energy is released. This convention intends to compare the destructiveness of an event with that of conventional explosive materials, of which TNT is a typical example, although other conventional explosives such as dynamite contain more energy. Kiloton and megaton The "kiloton (of TNT)" is a unit of energy equal to 4.184 terajoules (). The "megaton (of TNT)" is a unit of energy equal to 4.184 petajoules (). The kiloton and megaton of TNT have traditionally been used to describe the energy output, and hence the destructive power, of a nuclear weapon. The TNT equivalent appears in various nuclear weapon control treaties, and has b ...
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Explosive Material
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosives may a ...
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Shell (projectile)
A shell, in a military context, is a projectile whose payload contains an explosive, incendiary, or other chemical filling. Originally it was called a bombshell, but "shell" has come to be unambiguous in a military context. Modern usage sometimes includes large solid kinetic projectiles that is properly termed shot. Solid shot may contain a pyrotechnic compound if a tracer or spotting charge is used. All explosive- and incendiary-filled projectiles, particularly for mortars, were originally called ''grenades'', derived from the French word for pomegranate, so called because of the similarity of shape and that the multi-seeded fruit resembles the powder-filled, fragmentizing bomb. Words cognate with ''grenade'' are still used for an artillery or mortar projectile in some European languages. Shells are usually large-caliber projectiles fired by artillery, armored fighting vehicles (e.g. tanks, assault guns, and mortar carriers), warships, and autocannons. The shape ...
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Picric Acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from el, πικρός (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye. History Picric acid was probably first mentioned in the alchemical writings of Johann Rudolf Glauber. Initially, it was made by nitrating substances such as animal horn, silk, indigo, and natural resin, the synthesis from indigo first being performed by Peter Woulfe during 1771. The German chemist Justus von Liebig had named picric acid (rendered in French as ). Picric acid was given that name by the French chemist Jean-Baptiste Dumas in 1841. Its synthesis from phenol, and the correct determination of its formula, were accomplished during 1841. I ...
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Picric Acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from el, πικρός (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye. History Picric acid was probably first mentioned in the alchemical writings of Johann Rudolf Glauber. Initially, it was made by nitrating substances such as animal horn, silk, indigo, and natural resin, the synthesis from indigo first being performed by Peter Woulfe during 1771. The German chemist Justus von Liebig had named picric acid (rendered in French as ). Picric acid was given that name by the French chemist Jean-Baptiste Dumas in 1841. Its synthesis from phenol, and the correct determination of its formula, were accomplished during 1841. I ...
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2,4-Dinitrotoluene
2,4-Dinitrotoluene (DNT) or dinitro is an organic compound with the formula C7H6N2O4. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene (TNT) but is mainly produced as a precursor to toluene diisocyanate. Isomers of dinitrotoluene Six positional isomers are possible for dinitrotoluene. The most common one is 2,4-dinitrotoluene. The nitration of toluene gives sequentially mononitrotoluene, DNT, and finally TNT. 2,4-DNT is the principal product from dinitration, the other main product being about 30% 1,3-DN2-T. The nitration of 4-nitrotoluene gives 2,4-DNT. Applications Most DNT is used in the production of toluene diisocyanate, which is used to produce flexible polyurethane foams. DNT is hydrogenated to produce 2,4-toluenediamine, which in turn is phosgenated to give toluene diisocyanate. In this way, about 1.4 billion kilograms are produced annually, as of the years 1999–2000. Other uses include the explosives industry. It is not used by itsel ...
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Julius Wilbrand
Julius Bernhard Friedrich Adolph Wilbrand (22 August 1839 – 22 June 1906)''Familienarchiv Familie Wilbrand'' O13, Nr. 139, Hessisches Landesmuseum Darmstadt. was a German chemist. Born in Gießen to Franz Joseph Julius Wilbrand and Albertine Knapp, he discovered trinitrotoluene in 1863,G. Carlton Smith: ''TNT. Trinitrotoluenes and Mono- and Dinitrotoluenes, Their Manufacture and Properties'', New York 1918, S. 17-18. but the compound's use as an explosive was not developed until later. Wilbrand obtained trinitrotoluene or TNT by the nitration of toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) a .... References 1839 births 1906 deaths 19th-century German chemists People from Giessen University of Giessen alumni {{Germany-chemist-stub ...
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Bomb
A bomb is an explosive weapon that uses the Exothermic process, exothermic reaction of an explosive material to provide an extremely sudden and violent release of energy. Detonations inflict damage principally through ground- and atmosphere-transmitted mechanical stress (mechanics), stress, the impact and penetration of pressure-driven projectiles, pressure damage, and explosion-generated effects. Bombs have been utilized since the 11th century starting in East Asia. The term bomb is not usually applied to explosive devices used for civilian purposes such as construction or mining, although the people using the devices may sometimes refer to them as a "bomb". The military use of the term "bomb", or more specifically aerial bomb action, typically refers to airdropped, unpowered explosive weapons most commonly used by air forces and naval aviation. Other military explosive weapons not classified as "bombs" include shell (projectile), shells, depth charges (used in water), or lan ...
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Armour-piercing
Armour-piercing ammunition (AP) is a type of projectile designed to penetrate either body armour or vehicle armour. From the 1860s to 1950s, a major application of armour-piercing projectiles was to defeat the thick armour carried on many warships and cause damage to their lightly-armoured interiors. From the 1920s onwards, armour-piercing weapons were required for anti-tank warfare. AP rounds smaller than 20 mm are intended for lightly-armoured targets such as body armour, bulletproof glass, and lightly-armoured vehicles. As tank armour improved during World War II, anti-vehicle rounds began to use a smaller but dense penetrating body within a larger shell, firing at very high muzzle velocity. Modern penetrators are long rods of dense material like tungsten or depleted uranium (DU) that further improve the terminal ballistics. History The late 1850s saw the development of the ironclad warship, which carried wrought iron armour of considerable thickness. This armour ...
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Explosive D
Dunnite, also known as Explosive D or systematically as ammonium picrate, is an explosive developed in 1906 by US Army Major Beverly W. Dunn, who later served as the chief inspector of the Bureau of Transportation Explosives. Ammonium picrate is a salt formed by reacting picric acid and ammonia. It is chemically related to the more stable explosive trinitrotoluene (TNT). History It was the first explosive used in an aerial bombing operation in military history, performed by Italian pilots in Libya in 1911. It was used extensively by the United States Navy during World War I. Though Dunnite was generally considered an insensitive substance, by 1911 the United States Army had abandoned its use in favor of other alternatives. The Navy, however, used it in armor-piercing artillery shells and projectiles, and in coastal defense. Dunnite typically did not detonate on striking heavy armor. Rather, the encasing shell would penetrate the armor, after which the charge would be triggere ...
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Hexanitrobenzene
Hexanitrobenzene, also known as HNB, is a high-density explosive compound with chemical formula , obtained by oxidizing the amine group of pentanitroaniline with hydrogen peroxide in sulfuric acid. Properties HNB has the undesirable property of being moderately sensitive to light and, therefore, hard to utilize safely. As of 2021, it is not used in any production explosives applications, though it is used as a precursor chemical in one method of production of TATB, another explosive. HNB was experimentally used as a gas source for explosively pumped gas dynamic laser.Condensed explosive gas dynamic laser
United States Patent 4099142 In this application, HNB and are preferred ...
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Acetone
Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscible with water and serves as an important organic solvent in its own right, in industry, home, and laboratory. About 6.7 million tonnes were produced worldwide in 2010, mainly for use as a solvent and production of methyl methacrylate (and from that PMMA) as well as bisphenol A.Acetone
World Petrochemicals report, January 2010
Stylianos Sifniades, Alan B. Levy, "Acetone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. It is a common building block in