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Dye-Sublimation Printing (or dye-sub printing) is a digital
computer printing In computing, a printer is a peripheral machine which makes a persistent representation of graphics or text, usually on paper. While most output is human-readable, bar code printers are an example of an expanded use for printers. Differ ...
technique that uses heat to transfer dye onto materials such as plastic, card, paper, or fabric. The sublimation name was first applied because the dye was considered to make the transition between the solid and gas states without going through a liquid stage. This understanding of the process was later shown to be incorrect, as there is some liquefying of the dye. Since then, the proper name for the process has become known as dye-diffusion, though this technically correct term has not supplanted the original name. Chemical technology in Printing and Imaging Systems, ed. J A G Drake, 1993, pp 73-85 Many
consumer A consumer is a person or a group who intends to order, or uses purchased goods, products, or services primarily for personal, social, family, household and similar needs, who is not directly related to entrepreneurial or business activities. T ...
and
professional A professional is a member of a profession or any person who works in a specified professional activity. The term also describes the standards of education and training that prepare members of the profession with the particular knowledge and skil ...
dye-sublimation printers are designed and used for producing
photograph A photograph (also known as a photo, image, or picture) is an image created by light falling on a photosensitive surface, usually photographic film or an electronic image sensor, such as a CCD or a CMOS chip. Most photographs are now create ...
ic prints, ID cards, clothing, and more. These are not to be confused with 'dye sublimation heat transfer imprinting printers', which are inkjet printers that use special inks to create transfers designed to be imprinted on textiles, and in which the dyes do indeed sublimate. These are done at lower temperatures but higher pressures, particularly in
all-over print In streetwear fashion, an all over print (also known as all-over-print) is a print composed of a design that is repeated across the entire surface of a garment. The image is on both the front and back. Often, such prints are screen printed. Othe ...
processes. For ID card printing, text and bar codes are necessary, and they are printed by means of an additional black panel on the (YMCKO) ribbon. This extra panel works by
thermal transfer printing Thermal-transfer printing is a digital printing method in which material is applied to paper (or some other material) by melting a coating of ribbon so that it stays glued to the material on which the print is applied. It contrasts with direct the ...
instead of dye diffusion: a whole layer, instead of just some of the dye in the layer, transfers from the ribbon to the substrate at the pixels defined by the thermal head. This overall process is then sometimes called dye diffusion thermal transfer (D2T2).


Theory

Dye-sub printing is a
digital printing Digital printing is a method of printing from a digital-based image directly to a variety of media. It usually refers to professional printing where small-run jobs from desktop publishing and other digital sources are printed using large-format ...
technology using full-color artwork that works with
polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...
and
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
-coated substrates. Also referred to as digital sublimation, the process is commonly used for decorating apparel, signs, and banners, as well as novelty items such as cell phone covers, plaques, coffee mugs, and other items with sublimation-friendly surfaces. The process uses the science of sublimation, in which heat and pressure are applied to a solid, turning it into a gas through an
endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. p. ...
reaction without passing through the liquid phase. In sublimation printing, unique sublimation dyes are transferred to sheets of “transfer” paper via liquid gel ink through a
piezoelectric Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied Stress (mechanics), mechanical s ...
print head. The ink is deposited on these high-release inkjet papers, which are used for the next step of the sublimation printing process. After the digital design is printed onto sublimation transfer sheets, it is placed on a
heat press In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...
along with the substrate to be sublimated. In order to transfer the image from the paper to the substrate, it requires a heat press machine process that is a combination of time, temperature, and pressure - each at varying degrees, depending on the substrate. This application will transfer the sublimation dyes at the molecular level into the substrate. The most common dyes used for sublimation activate at 350 degrees Fahrenheit / 175 degrees Celsius. However, a range of 380 to 420 degrees Fahrenheit / 195 to 215 degrees Celsius is normally recommended for optimal color. The result of the sublimation process is a nearly permanent, high-resolution, full-color print. Because the dyes are infused into the substrate at the
molecular A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
level, rather than applied at a topical level (such as with
screen printing Screen printing is a printing technique where a mesh is used to transfer ink (or dye) onto a substrate, except in areas made impermeable to the ink by a blocking stencil. A blade or squeegee is moved across the screen to fill the open mes ...
and
direct to garment printing Direct-to-garment printing (DTG) is a process of printing on textiles using specialized aqueous ink jet technology. DTG printers typically have a platen designed to hold the garment in a fixed position, and the printer inks are jetted or sprayed o ...
), the prints will not crack, fade or peel from the substrate under normal conditions.


Operation

The most common process lays one color at a time, the dye being stored on a polyester ribbon that has each color on a separate panel. Each colored panel is the size of the medium that is being printed on; for example, a 6" by 4" dye sub-printer would have four 6" by 4" panels. During the printing cycle, the printer rollers will move the medium and one of the colored panels together under a thermal printing head, which is usually the same width as the shorter dimension of the print medium. Tiny heating elements on the head change temperature rapidly, laying different amounts of dye depending on the amount of heat applied. Some of the dye diffuses into the printing medium. After the printer finishes printing the medium in one color, it winds the ribbon onto the next color panel and partially ejects the medium from the printer to prepare for the next cycle. The entire process is repeated four or five times in total: the first three lay the colors onto the medium to form a complete image; there may or may not then be a black thermal transfer process; while the last one lays the laminate over top. This layer protects the dyes from UV light and moisture.


Comparison with inkjet printing

Traditionally, the advantage of dye-sublimation printing has been the fact that it is a continuous-tone technology, where each dot can be any color. In contrast, inkjet printers can vary the location and size of ink droplets, a process called
dithering Dither is an intentionally applied form of noise used to randomize quantization error, preventing large-scale patterns such as color banding in images. Dither is routinely used in processing of both digital audio and video data, and is often ...
, but each drop of ink is limited to the colors of the inks installed. Consequently, a dye-sublimation printer produces true continuous tones appearing much like a chemical photograph. An inkjet print is composed of droplets of ink layered and scattered to simulate continuous tones, but under magnification, the individual droplets can be seen. In the early days of inkjet printing, the large droplets and low resolution made inkjet prints significantly inferior to dye-sublimation, but some of today's inkjets produce extremely high-quality prints using microscopic droplets and supplementary ink colors, producing superior color fidelity to dye-sublimation. Dye sublimation offers some advantages over inkjet printing. For one, the prints are dry and ready to handle as soon as they exit the printer. Since the thermal head doesn't have to sweep back and forth over the print media, there are fewer moving parts that can break down. The whole printing cycle is extremely clean as there are no liquid inks to clean up. These factors make dye-sublimation generally a more reliable technology than inkjet printing. Dye-sublimation printers have some drawbacks compared to inkjet printers. Each of the colored panels of the ribbons, and the thermal head itself, must match the size of the media that is being printed on. Furthermore, only especially
coated paper Coated paper (also known as enamel paper, gloss paper, and thin paper) is paper that has been coated by a mixture of materials or a polymer to impart certain qualities to the paper, including weight, surface gloss, smoothness, or reduced ink absor ...
or specific plastics can accept the sublimated ink. This means that dye-sublimation printers cannot match the flexibility of inkjet printers in printing on a wide range of media. The dyes diffuse a small amount before being absorbed by the paper. Consequently, prints are not razor-sharp. For photographs, this produces very natural prints, but for other uses (such as graphic design) this slight blurriness is a disadvantage. The amount of wasted dye per page is also very high; most of the dye in the four panels may be wasted for a typical print. Once a panel has been used, even to just print a single dot, the remaining dye on that panel cannot be reused for another print without leaving a blank spot where the dye was used previously. Due to the single-roll design of most printers, four panels of colored dye must be used for every print, whether or not a panel is needed for the print. Printing in monochrome saves nothing, and the three unused color panels for that page cannot be recycled for a different single-color print. Inkjet printers can also suffer from 'dye wastage' as the ink cartridges are prone to drying up with low usage (without 'heavy use', the cartridge nozzles can become clogged with dried ink). Dye-sublimation media packs, (which contain both ribbon and paper), are rated for an exact number of prints which yields a fixed cost per print. This is in opposition to inkjet printers where inks are purchased by volume. For environments that print confidential or secret documents, a dye-sublimation printer is a potential security risk that must be handled carefully. Due to the mechanism of printing, a perfect color-separated negative image of the printed page is created on the supply roll color panels, and the "waste roll" of dye panels can be unrolled to see everything that has been printed with the printer. For such environments, the waste roll should be shredded or incinerated onsite rather than simply being discarded in the trash. Also, for home users, the waste roll from a photo printer can be similarly recovered from the garbage and used to see everything that has been printed. Since the supply roll is plastic, the lifespan of a used roll can be years or decades long, permitting image recovery long after disposal. Also, dye-sublimation papers and ribbons are sensitive to skin oils, which interfere with the dye's ability to sublimate from the ribbon to the paper. They must also be free of dust particles, which can lead to small colored blobs appearing on the prints. Most dye-sublimation printers have filters and/or cleaning rollers to reduce the likelihood of this happening, and a speck of dust can only affect one print as it becomes attached to the print during the printing process. Finally, dye-sublimation printers fall short when producing neutral and toned black-and-white prints with higher
density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
levels and virtually no metamerism or bronzing.


Applications

Used dye panels retain a viewable image of the printed document, and an example of wasted dye that cannot be reused. Previously, the use of dye-sub printing was limited to industrial or high-end commercial printing. Dye-sub photo printing has been used in
medical imaging Medical imaging is the technique and process of imaging the interior of a body for clinical analysis and medical intervention, as well as visual representation of the function of some organs or tissues (physiology). Medical imaging seeks to rev ...
, graphic arts proofing, security, and broadcast-related applications. But nowadays, it is extremely popular in event photography and photo booths or kiosks that require high-speed, on-demand printing.
Alps Electric is a Japanese multinational corporation, headquartered in Tokyo, Japan, producing electronic devices, including switches, potentiometers, sensors, encoders and touchpads. The company was established in 1948 as Kataoka Electric Co., Ltd. and ch ...
produced the first quality dye-sub printers for home consumers in the $500–$1,000 price range, bringing dye-sublimation technology within the reach of a wider audience. Now there are many dye-sublimation printers on the market starting from as low as $100, especially
postcard A postcard or post card is a piece of thick paper or thin cardboard, typically rectangular, intended for writing and mailing without an envelope. Non-rectangular shapes may also be used but are rare. There are novelty exceptions, such as wood ...
-sized mobile
photo printer In computing, a printer is a peripheral machine which makes a persistent representation of graphics or text, usually on paper. While most output is human-readable, bar code printers are an example of an expanded use for printers. Differ ...
s. The ability to produce instant photo prints inexpensively from a small printer has led to dye sublimation solutions supplanting traditional instant photos in some applications, such as ID photography with a
card printer Card or The Card may refer to: * Various types of plastic cards: **By type ***Magnetic stripe card ***Chip card ***Digital card **By function ***Payment card ****Credit card ****Debit card ****EC-card ****Identity card ****European Health Insurance ...
. Several corporations market desktop-size units as stand-alone printers and for print kiosk and
photo booth A photo booth is a vending machine or modern kiosk that contains an automated, usually coin-operated, camera and film processor. Today, the vast majority of photo booths are digital. History The patent for the first automated photography ma ...
applications. Some of these units are based on generic printers. Some manufacturers, offer
software development kit A software development kit (SDK) is a collection of software development tools in one installable package. They facilitate the creation of applications by having a compiler, debugger and sometimes a software framework. They are normally specific to ...
s with their printers, suggesting that these companies hope to attract
system integrator A systems integrator (or system integrator) is a person or company that specializes in bringing together component subsystems into a whole and ensuring that those subsystems function together, a practice known as system integration. They also sol ...
s as a potential market. Desktop-size stand-alone dye-sub photo printers are also being applied by social photographers in event photography. The units' instant printability allows photographers to produce and sell lab-quality prints immediately during the event they are attending, with a minimal amount of hardware. Dye-sublimation can also be used as an indirect printing process. Standard black and white
laser printer Laser printing is an electrostatic digital printing process. It produces high-quality text and graphics (and moderate-quality photographs) by repeatedly passing a laser beam back and forth over a negatively-charged cylinder called a "drum" to d ...
s are capable of printing on plain paper using a special "transfer toner" containing sublimation dyes which can then be permanently heat transferred to
T-shirts A T-shirt (also spelled tee shirt), or tee, is a style of fabric shirt named after the T shape of its body and sleeves. Traditionally, it has short sleeves and a round neckline, known as a ''crew neck'', which lacks a collar. T-shirts are generall ...
,
hats A hat is a head covering which is worn for various reasons, including protection against weather conditions, ceremonial reasons such as university graduation, religious reasons, safety, or as a fashion accessory. Hats which incorporate mecha ...
, mugs, metals, puzzles, and other surfaces.


Textiles

The dye-sublimation printing process is used to print on
polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...
or other synthetic fabrics. It is used for applications such as
T-shirts A T-shirt (also spelled tee shirt), or tee, is a style of fabric shirt named after the T shape of its body and sleeves. Traditionally, it has short sleeves and a round neckline, known as a ''crew neck'', which lacks a collar. T-shirts are generall ...
, banners, table covers, id cards,
sportswear Sportswear or activewear is clothing, including footwear, worn for sport or physical exercise. Sport-specific clothing is worn for most sports and physical exercise, for practical, comfort or safety reasons. Typical sport-specific garments ...
, and flags. The original printers were an
electrostatic Electrostatics is a branch of physics that studies electric charges at rest (static electricity). Since classical times, it has been known that some materials, such as amber, attract lightweight particles after rubbing. The Greek word for amber ...
technology using toners but now are generally large format inkjet printers using specially formulated inks. The dye sublimation inks are dispersed dye suspended in a liquid
solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...
, like water. The images are initially printed on coated heat-resistant transfer paper as a reverse image of the final design, which is then transferred onto polyester fabric in a heat press operating at a temperature around . Under high
temperatures Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
and pressure, the dye turns into a gas and permeates the fabric, and then solidifies into its fibers. The fabric is permanently dyed so it can be washed without damaging the quality of the image. Advantages of dye-sublimation over other methods of textile printing: images are permanent and do not peel or fade, the dye does not build up on the fabric. *Colors can be extraordinarily brilliant due to the bonding of the dye to the transparent fibers of the synthetic fabric, truly continuous tones can be achieved that are equivalent to photographs, without the use of special techniques such as half-screen printing, and the image can be printed all over the entire item, with no difficulty in printing all the way to the edges.


Print speed for dye sublimation thermal printers

As dye-sublimation thermal printers utilize heat to transfer the dye onto the print media, the printing speed is limited by the speed at which the elements on the thermal head can change temperature. Heating the elements is easy, as a strong electric current can raise the temperature of an element very quickly. However, cooling the elements down, when changing from a darker to a lighter color, is harder and usually involves having a fan/heatsink assembly attached to the print head. The use of multiple heads can also speed up this process since one head can cool down while another is printing. Although print times vary among different dye-sublimation printers, a typical cheap home-use dye-sub printer can print a 6" x 4" photo in 45 – 90 seconds. More heavy-duty printers can print much faster; for example, a Sinfonia Colorstream S2 dye-sublimation printer can print a 6" x 4" photo in as little as 6.8 seconds, and a Mitsubishi CP-D707DW is known to have a faster print of under 6 seconds for similar size. In all cases, the finished print is completely dry once it emerges from the printer.


Ink for piezo printers

A disassembled dye sublimation cartridge There are two types of dye sublimation inks for piezo dye sublimation printers available in the market. The most popular one is aqueous dye sublimation ink for use in both desktop and large format printers. The other is solvent dye sublimation ink that can be used in XAAR, Spectra, and some
Konica was a Japanese manufacturer of, among other products, film, film cameras, camera accessories, photographic and photo-processing equipment, photocopiers, fax machines and laser printers, founded in 1873. The company merged with Japanese peer Mino ...
printhead-wide format printers. Due to the fast development of digital textile printing, dye sublimation inks are becoming more and more popular in digital
inkjet Inkjet printing is a type of computer printing that recreates a digital image by propelling droplets of ink onto paper and plastic substrates. Inkjet printers were the most commonly used type of printer in 2008, and range from small inexpensi ...
printing on
fabrics Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...
. Print speeds for large-format piezo printers using aqueous dye sublimation ink continue to increase. Speeds range from 18 square meters per hour in a smaller 44" wide printer to over 3,000 square meters per hour in a high-speed industrial textile printer.


See also

*
Barcode printer A barcode printer is a computer peripheral for printing barcode labels or tags that can be attached to, or printed directly on, physical objects. Barcode printers are commonly used to label cartons before shipment, or to label retail items with ...
*
Card printer Card or The Card may refer to: * Various types of plastic cards: **By type ***Magnetic stripe card ***Chip card ***Digital card **By function ***Payment card ****Credit card ****Debit card ****EC-card ****Identity card ****European Health Insurance ...
* Daisy wheel printing *
Dot matrix printing Dot matrix printing, sometimes called impact matrix printing, is a computer printing process in which ink is applied to a surface using a relatively low-resolution dot matrix for layout. Dot matrix printers typically use a print head that moves ...
*
Label printer Brother P-Touch 540 label printer A label printer is a computer printer that prints on self-adhesive label material and/or card-stock (tags). A label printer with built-in keyboard and display for stand-alone use (not connected to a separate ...
*
Label printer applicator Label printer applicator applying a label to adjacent panels of a corrugated box Label printer applicator A label printer applicator is a basic robot that can automatically print and apply pressure-sensitive labels to various products. Some t ...
*
Line matrix printer A line matrix printer is a computer printer that is a compromise between a line printer and a dot matrix printer. A line matrix printer prints page-wide lines of dots, building up a line of text by printing lines of dots. Applications Line matri ...
*
Line printer A line printer prints one entire line of text before advancing to another line. Most early line printers were impact printers. Line printers are mostly associated with unit record equipment and the early days of digital computing, but the ...
*
List of art techniques A ''list'' is any set of items in a row. List or lists may also refer to: People * List (surname) Organizations * List College, an undergraduate division of the Jewish Theological Seminary of America * SC Germania List, German rugby union ...
*
Thermal transfer printing Thermal-transfer printing is a digital printing method in which material is applied to paper (or some other material) by melting a coating of ribbon so that it stays glued to the material on which the print is applied. It contrasts with direct the ...
*
ID card printer In computing, a printer is a peripheral machine which makes a persistent representation of graphics or text, usually on paper. While most output is human-readable, bar code printers are an example of an expanded use for printers. Differ ...


References

{{reflist Computer printers Non-impact printing