A desalter is a process unit in an
oil refinery
An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, lique ...
that removes salt from the
crude oil. The salt is dissolved in the water in the crude oil, not in the crude oil itself. The desalting is usually the first process in crude oil refining. The salt content after the desalter is usually measured in PTB – pounds of salt per thousand
barrels of crude oil. Another specification is
Basic sediment and water.
The term desalter may also refer to a
water desalination
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Salt ...
facility used to treat
brackish water
Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estuari ...
from
agricultural runoff
Agricultural pollution refers to biotic and abiotic byproducts of farming practices that result in contamination or degradation of the environment and surrounding ecosystems, and/or cause injury to humans and their economic interests. The pol ...
. This may be done either to produce
potable water for human or animal consumption, or to reduce the salinity of river water prior to its crossing an international border, usually to comply with the terms of a
treaty
A treaty is a formal, legally binding written agreement between actors in international law. It is usually made by and between sovereign states, but can include international organizations, individuals, business entities, and other legal pe ...
. Desalters are also used to treat
groundwater
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidated ...
reservoirs in areas impacted by cattle
feedlots and
dairies
A dairy is a business enterprise established for the harvesting or processing (or both) of animal milk – mostly from cows or buffaloes, but also from goats, sheep, horses, or camels – for human consumption. A dairy is typically located on ...
.
Desalting crude oil
The salts that are most frequently present in crude oil are calcium, sodium and magnesium chlorides. If these compounds are not removed from the oil several problems arise in the refining process. The high temperatures that occur downstream in the process could cause water
hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
Biological hydrolys ...
, which in turn allows the formation of corrosive hydrochloric acid. Sand, silts and salt cause deposits and foul heat exchangers or result in plugging. The need to supply heat to vaporize water reduces crude pre-heat capacity. Sodium, arsenic and other metals can poison catalysts. By removing the suspended solids, they are not carried into the burner and eventually flue gas, where they would cause problems with environmental compliance such as flue gas opacity norms.
Crude oil to be desalted is heated to a temperature of 100-150 °C and mixed with 4-10% fresh water, which dilutes the salt. The mixture is then pumped into a settling tank where the salt water separates from the oil and is drawn off. An electrostatic field is applied by electrodes in the settling tank, inducing polarization of the water droplets floating in the larger volume of oil. This results in the water droplets clumping together and settling to the bottom of the tank.
[https://m.tau.ac.il/~tsirel/dump/Static/knowino.org/wiki/Crude_oil_desalter.html Crude oil desalter]
See also
*
Brackish water
Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estuari ...
*
Water desalination
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Salt ...
References
External links
Desalting in refinery
{{Petroleum refining
Industrial equipment
Chemical equipment
Oil refineries