Curran (material)
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Curran is a
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but the ...
nanocellulose Nanocellulose is a term referring to nano-structured cellulose. This may be either cellulose nanocrystal (CNC or NCC), cellulose nanofibers (CNF) also called nanofibrillated cellulose (NFC), or bacterial nanocellulose, which refers to nano-struc ...
fibre derived from the pulp of
root vegetables Root vegetables are underground plant parts eaten by humans as food. Although botany distinguishes true roots (such as taproots and tuberous roots) from non-roots (such as bulbs, corms, rhizomes, and tubers, although some contain both hypocotyl a ...
. It was developed by Scottish scientists David Hepworth and Eric Whale, with funding from the Scottish Government. The sources of root vegetable pulp used to manufacture Curran include
carrots The carrot (''Daucus carota'' subsp. ''sativus'') is a root vegetable, typically orange in color, though purple, black, red, white, and yellow cultivars exist, all of which are domesticated forms of the wild carrot, ''Daucus carota'', nativ ...
,
sugar beets Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose, fructose, and galactose. Compound sugars, also called disaccharides or double s ...
, and
turnips The turnip or white turnip (''Brassica rapa'' subsp. ''rapa'') is a root vegetable commonly grown in temperate climates worldwide for its white, fleshy taproot. The word ''turnip'' is a compound of ''turn'' as in turned/rounded on a lathe and '' ...
. It is named after ''curran'', the
Scottish Gaelic Scottish Gaelic ( gd, Gàidhlig ), also known as Scots Gaelic and Gaelic, is a Goidelic language (in the Celtic branch of the Indo-European language family) native to the Gaels of Scotland. As a Goidelic language, Scottish Gaelic, as well as ...
word for "carrot". The material was developed as a potential substitute for
carbon fibre Carbon fiber-reinforced polymers (American English), carbon-fibre-reinforced polymers (Commonwealth English), carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic (CFRP, CRP, CFRTP), also known as carbon fiber, carbon compo ...
and is often used in
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
composites. It has numerous industrial and technological applications, especially for the production of paints and sporting equipment.


History

The material was developed by Scottish material scientists David Hepworth and Eric Whale, who met while studying for their
PhDs A Doctor of Philosophy (PhD, Ph.D., or DPhil; Latin: or ') is the most common degree at the highest academic level awarded following a course of study. PhDs are awarded for programs across the whole breadth of academic fields. Because it is a ...
at
University of Reading The University of Reading is a public university in Reading, Berkshire, England. It was founded in 1892 as University College, Reading, a University of Oxford extension college. The institution received the power to grant its own degrees in 192 ...
. They began researching carrot-derived cellulose fibres in 2002. In 2004, they founded Cellucomp, Ltd. in
Fife Fife (, ; gd, Fìobha, ; sco, Fife) is a council area, historic county, registration county and lieutenancy area of Scotland. It is situated between the Firth of Tay and the Firth of Forth, with inland boundaries with Perth and Kinross (i ...
with funding from the Scottish government agency
Scottish Enterprise Scottish Enterprise is a non-departmental public body of the Scottish Government which encourages economic development, enterprise, innovation and investment in business. The body covers the eastern and central parts of Scotland whilst similar ...
. They hoped to develop a composite that could be a substitute for
carbon fibre Carbon fiber-reinforced polymers (American English), carbon-fibre-reinforced polymers (Commonwealth English), carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic (CFRP, CRP, CFRTP), also known as carbon fiber, carbon compo ...
. The word ''curran'' means "carrot" in
Scottish Gaelic Scottish Gaelic ( gd, Gàidhlig ), also known as Scots Gaelic and Gaelic, is a Goidelic language (in the Celtic branch of the Indo-European language family) native to the Gaels of Scotland. As a Goidelic language, Scottish Gaelic, as well as ...
, a reference to the fact that cellulose fibres from carrots were used to develop the material. Root vegetables were selected over wood or cotton, which are more widely used in the production of nanofibres, because root vegetables grow faster and are easier to process. During early development, Whale and Hepworth's team bought large quantities of carrots from local grocery stores, finding them a cheap and convenient source of cellulose. They would typically buy four
shopping trolley "Shopping Trolley" was a 2006 single by English songwriter Beth Orton. It was released as a 2 CD single set and 12 inch vinyl, and an early version of the title song can be purchased from iTunes. Track listing CD: EMI / CDEM 694 United ...
s full of carrots at a time, until their local stores could no longer keep up with the volume required and refused to sell them more carrots. After this, the scientists switched to purchasing
B-grade A B movie or B film is a low-budget commercial motion picture. In its original usage, during the Golden Age of Hollywood, the term more precisely identified films intended for distribution as the less-publicized bottom half of a double featur ...
carrots not fit for consumers directly from farmers. The development team later began using
sugar beet pulp Beet pulp is a byproduct from the processing of sugar beet which is used as fodder for horses and other livestock. Beet pulp is the fibrous material left over after the sugar is extracted from sugar beets. It is supplied either as dried flakes or ...
, an agricultural byproduct of
sugar production The sugar industry subsumes the production, processing and marketing of sugars (mostly sucrose and fructose). Globally, most sugar is extracted from sugar cane (~80% predominantly in the tropics) and sugar beet (~ 20%, mostly in temperate climate ...
, as their source of cellulose. Beet pulp was even more widely available than carrots due to the scale of the global sugar industry. The process can also be applied to other root vegetables, such as
turnips The turnip or white turnip (''Brassica rapa'' subsp. ''rapa'') is a root vegetable commonly grown in temperate climates worldwide for its white, fleshy taproot. The word ''turnip'' is a compound of ''turn'' as in turned/rounded on a lathe and '' ...
,
rutabaga Rutabaga (; North American English) or swede (British English and some Commonwealth English) is a root vegetable, a form of ''Brassica napus'' (which also includes rapeseed). Other names include Swedish turnip, neep (Scots), and turnip (Scott ...
, and
parsnips The parsnip ('' Pastinaca sativa'') is a root vegetable closely related to carrot and parsley, all belonging to the flowering plant family Apiaceae. It is a biennial plant usually grown as an annual. Its long taproot has cream-colored ski ...
. Hepworth and Whale received grant funding from the
European Union The European Union (EU) is a supranational political and economic union of member states that are located primarily in Europe. The union has a total area of and an estimated total population of about 447million. The EU has often been des ...
's
Framework Programmes for Research and Technological Development The Framework Programmes for Research and Technological Development, also called Framework Programmes or abbreviated FP1 to FP9, are funding programmes created by the European Union/European Commission to support and foster research in the Europea ...
which they used to hire researchers from
Swiss Federal Laboratories for Materials Science and Technology The Swiss Federal Laboratories for Materials Science and Technology (Empa, German acronym for ''Eidgenössische Materialprüfungs- und Forschungsanstalt'') is an interdisciplinary Swiss research institute for applied materials sciences and tech ...
(EMPA). The EMPA researchers applied a multi-perspective application selection (MPAS) method to determine whether Curran could be efficiently produced and marketed on a large scale. Cellucomp began producing Curran fibres for paint manufacturers in 2013 and moved to a new production facility that allowed them to increase production from 15 to 50 tons annually. In 2015, a new Cellucomp facility was unveiled in
Glenrothes Glenrothes (; , ; sco, Glenrothes; gd, Gleann Rathais) is a town situated in the heart of Fife, in east-central Scotland. It is about north of Edinburgh and south of Dundee. The town had a population of 39,277 in the 2011 census, making i ...
by Scottish
Minister for Youth and Women's Employment The Minister for Employability and Training was a member of the Scottish Government. The Minister reported to the Cabinet Secretary for Education and Skills and the Cabinet Secretary for Economy, Jobs and Fair Work, who split overall responsib ...
Annabelle Ewing Annabelle Janet Ewing (born 20 August 1960) is a Scottish politician and lawyer who has served as Deputy Presiding Officer of the Scottish Parliament, alongside Liam McArthur, since May 2021. A member of the Scottish National Party (SNP), sh ...
. The facility was reported to produce 400 tons of Curran per year, with plans to expand to 2000 tons per year. By 2015, Cellucomp had received £1 million in grants from the Scottish government, including Scottish Enterprise. The company's growth was part of larger efforts to expand Scotland's
biotechnology Biotechnology is the integration of natural sciences and engineering sciences in order to achieve the application of organisms, cells, parts thereof and molecular analogues for products and services. The term ''biotechnology'' was first used b ...
sector, per the country's National Plan for Industrial Biotechnology. The company also received £3 million of funding from private investors such as Claridge, Inc. and
Sofinnova Sofinnova is the name shared by two venture capital firms, Sofinnova Partners and Sofinnova Ventures. The name Sofinnova is a contraction of the French, "Société de Financement de l’Innovation" or, Innovation Venture Capital Company. Both fi ...
. As of 2019, the company had plans to begin building a €22.6 million commercial scale facility.


Production

During the production of Curran, vegetables are mechanically broken down to create a
slurry A slurry is a mixture of denser solids suspended in liquid, usually water. The most common use of slurry is as a means of transporting solids or separating minerals, the liquid being a carrier that is pumped on a device such as a centrifugal pu ...
of nanocellulose particles. The excess water is removed from the slurry, and the nanocellulose fibre is extracted. Whale described the processed fibres as being similar in consistency to
Play-Doh Play-Doh is a modeling compound for young children to make arts and crafts projects at home. The product was first manufactured in Cincinnati, Ohio, United States, as a wallpaper cleaner in the 1930s. Play-Doh was then reworked and marketed to Cin ...
. The fibres are then further processed by combining them with
resins In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on natu ...
. Resins used to create Curran biocomposites include
epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also coll ...
,
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethan ...
and
polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...
.
Thermoset In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening (" curing") a soft solid or viscous liquid prepolymer (resin). Curing is induced by heat or suitable radiation and ...
polymer-based Curran composites are strong and mouldable. Curran is sold in the form of a powder, granule or slurry for different applications and is typically sold in quantities of 15 kilograms. Unlike other methods of separating cellulose fibres from root vegetable pulp, Curran production does not require fossil fuel-based chemicals. Manufacturing Curran also does not produce
volatile organic compounds Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature Colloquially, "room temperature" is a range of air temperatures that most people prefer for indoor settings. It feels comfortable to a ...
.


Properties

Curran is based on
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but the ...
nanocellulose Nanocellulose is a term referring to nano-structured cellulose. This may be either cellulose nanocrystal (CNC or NCC), cellulose nanofibers (CNF) also called nanofibrillated cellulose (NFC), or bacterial nanocellulose, which refers to nano-struc ...
particles, with properties similar to both carbon fibre-based composites and
glass fibre Glass fiber ( or glass fibre) is a material consisting of numerous extremely fine fibers of glass. Glassmakers throughout history have experimented with glass fibers, but mass manufacture of glass fiber was only made possible with the inventio ...
composites. Its composition is around 80% root vegetable fibre and 20% oil. Its cellulose content is approximately 20%. Curran composites have a tensile strength of 5
gigapascal The pascal (symbol: Pa) is the unit of pressure in the International System of Units (SI), and is also used to quantify internal pressure, stress, Young's modulus, and ultimate tensile strength. The unit, named after Blaise Pascal, is defined as ...
s. Curran has a 5% strain to failure, and greater stiffness than glass composites. Because of its composition, it increases both the strength and viscosity of the products it is added to. The material is also
biodegradeable Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegradati ...
.


Applications

The material has applications for use in
composite materials A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...
and as a reinforcing additive in construction, paints and coatings,
drilling fluid In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also us ...
, cosmetics,
recycled paper The recycling of paper is the process by which waste paper is turned into new paper products. It has a number of important benefits: It saves waste paper from occupying homes of people and producing methane as it breaks down. Because paper fi ...
, and sustainable packaging. Its strength means that it has applications for use in automobile and aerospace parts.


Paints and coatings

Curran improves the
rheological Rheology (; ) is the study of the flow of matter, primarily in a fluid (liquid or gas) state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applie ...
properties of liquids such as plastics and paints. This increases the quality of paints, and can also prevent cracking. Curran is more ecologically friendly than many other alternatives used in paint manufacturing because of the lower energy costs involved in its production. However, it does not significantly impact the sustainability of paint since it makes up a small percentage of total ingredients.


Sports equipment

In 2007, Cellucomp partnered with the American sports equipment company E21 to produce a fly fishing rod made out of Curran. The rod, marketed as Carrot Stix, was bright orange colored. Carrot Stix were made out of 70% Curran wrapped around a thin carbon core. It was noted to be strong and significantly lighter than solely carbon-based rods. The rods were a commercial success, selling over 500,000 units. It won "Best Freshwater Rod" and "Best of Show" at the 2007 International Convention of Allied Sportfishing Trades. Cellucomp also marketed a similar brand of rods called Just Cast in the United Kingdom. After introducing Carrot Stix, they planned to produce
snowboards Snowboards are boards where the user places both feet, usually secured, to the same board. The board itself is wider than most skis, with the ability to glide on snow."snowboarding." Dictionary.com Unabridged (v 1.1). Random House, Inc. 17 Mar ...
. EMPA's research found that out of possible applications, motorcycle helmets and
surfboards A surfboard is a narrow plank used in surfing. Surfboards are relatively light, but are strong enough to support an individual standing on them while riding an ocean wave. They were invented in ancient Hawaii, where they were known as ''papa he'e ...
were particularly likely applications for Curran due to the need for materials used in their construction to be lightweight and strong, and advised more development in this area.


Concrete

Curran has been used to strengthen
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
by increasing the amount of
calcium silicate hydrate Calcium silicate hydrate (or C-S-H) is the main product of the hydration of Portland cement and is primarily responsible for the strength in cement based materials (e.g. concrete). Preparation When water is added to cement, each of the compounds u ...
within the material. Research conducted at
Lancaster University Lancaster University (legally The University of Lancaster) is a public university, public research university in Lancaster, Lancashire, Lancaster, Lancashire, England. The university was established in 1964 by royal charter, as one of several pla ...
created a
nanocomposite Nanocomposite is a multiphase solid material where one of the phases has one, two or three dimensions of less than 100 nanometers (nm) or structures having nano-scale repeat distances between the different phases that make up the material. The id ...
concrete by combining Curran with
Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th c ...
. Their study found that concrete reinforced with Curran could be made with lower quantities of cement, thereby significantly reducing carbon emissions associated with cement production. Curran also made concrete more resistant to corrosion over time, as it increased the density of its microstructure. As of 2019, the Lancaster University research team, led by Mohamed Saafi, planned to conduct trials of Curran-enforced concrete in the United Kingdom by the end of 2020. The European Union's
Horizon 2020 The Framework Programmes for Research and Technological Development, also called Framework Programmes or abbreviated FP1 to FP9, are funding programmes created by the European Union/European Commission to support and foster research in the Europea ...
programme awarded £195,000 in funding to Saafi's team to continue their research.


Packaging

Nanocellulose can be used to manufacture biodegradeable packaging for the
food industry The food industry is a complex, global network of diverse businesses that supplies most of the food consumed by the world's population. The food industry today has become highly diversified, with manufacturing ranging from small, traditiona ...
, including paper and cardboard. In 2022, Cellucomp and the Danish Technological Institute partnered to produce sustainable paper-based food packaging based on Curran as an alternative to plastic.


Automotive and aerospace industry

In 2009, Curran was used to create part of the steering wheel of Worldfirst, a
Formula Three Formula Three, also called Formula 3, abbreviated as F3, is a third-tier class of open-wheel formula racing. The various championships held in Europe, Australia, South America and Asia form an important step for many prospective Formula One driv ...
automobile made entirely out of recycled and renewable materials. Researchers at
University of Warwick The University of Warwick ( ; abbreviated as ''Warw.'' in post-nominal letters) is a public research university on the outskirts of Coventry between the West Midlands (county), West Midlands and Warwickshire, England. The university was founded i ...
engineered the vehicle. It was test driven by professional driver Aaron Steele at
Brands Hatch Brands Hatch is a motor racing circuit in West Kingsdown, Kent, England, United Kingdom. Originally used as a grasstrack motorcycle circuit on farmland, it hosted 12 runnings of the British Grand Prix between 1964 and 1986 and currently host ...
.


See also

*
Biotechnology in the United Kingdom Biotechnology in the United Kingdom is the British industry regarding organisms that manufacture commercial products, whether the genes of the organism have been naturally procured or not (synthetic biology). The industry can be controversial, an ...


References

{{reflist


External links


Cellucomp website
Fiber plants Organic polymers Cellulose