Crystallinity refers to the degree of structural order in a

solid Solid is a state of matter where molecules are closely packed and can not slide past each other. Solids resist compression, expansion, or external forces that would alter its shape, with the degree to which they are resisted dependent upon the ...

. In a

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

, the atoms or molecules are arranged in a regular, periodic manner. The degree of crystallinity has a large influence on

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...

density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...

, transparency and

diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...

. In an

ideal gas An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is ...

, the relative positions of the atoms or molecules are completely random. Amorphous materials, such as

liquids Liquid is a state of matter with a definite volume but no fixed shape. Liquids adapt to the shape of their container and are nearly incompressible, maintaining their volume even under pressure. The density of a liquid is usually close to th ...

and

glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...

es, represent an intermediate case, having order over short distances (a few atomic or molecular spacings) but not over longer distances. Many materials, such as

glass-ceramic Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses t ...

s and some

polymer A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their br ...

s, can be prepared in such a way as to produce a mixture of crystalline and

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymousl ...

regions. In such cases, crystallinity is usually specified as a percentage of the volume of the material that is crystalline. Even within materials that are completely crystalline, however, the degree of structural perfection can vary. For instance, most metallic

alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...

s are crystalline, but they usually comprise many independent crystalline regions (grains or

crystallite A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains. Bacillite is a type of crystallite. It is rodlike with parallel Wikt:longulite ...

s) in various orientations separated by

grain boundaries In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional crystallographic defect, defects in the crystal structure, and tend to decrease the ...

; furthermore, they contain other

crystallographic defect A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in Crystal, crystalline solids. The positions and orientations of particles, which are repeating at fixed distances determined by the Crysta ...

s (notably

dislocation In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to sli ...

s) that reduce the degree of structural perfection. The most highly perfect crystals are silicon boules produced for semiconductor electronics; these are large

single crystal In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no Grain boundary, grain bound ...

s (so they have no grain boundaries), are nearly free of dislocations, and have precisely controlled concentrations of defect atoms. Crystallinity can be measured using

x-ray diffraction X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...

, but calorimetric techniques are also commonly used. In geochemistry, mineral crystallinity plays a pivotal role in regulating water-rock interactions, particularly during the early stages of mineral crystallization. For example, in the case of goethite, dissolved lithium can be taken up by poorly crystallized goethite, whereas little sorption occurs in well-crystallized goethite. Additionally, lithium isotope fractionation during low-temperature water-rock interactions is controlled by reactions occurring at defect sites in poorly crystallized minerals, such as hectorite and goethite.

Rock crystallinity

Geologists describe four qualitative levels of crystallinity: * holocrystalline rocks are completely crystalline; * hypocrystalline rocks are partially crystalline, with crystals embedded in an amorphous or glassy matrix; * hypohyaline rocks are partially glassy; * holohyaline rocks (such as

obsidian Obsidian ( ) is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Produced from felsic lava, obsidian is rich in the lighter element ...

) are completely glassy.

References

*'' Oxford dictionary of science'', 1999, {{ISBN, 0-19-280098-1. Crystals Physical quantities Phases of matter