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Cosmic ray spallation, also known as the x-process, is a set of naturally occurring nuclear reactions causing
nucleosynthesis Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons (protons and neutrons) and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in ...
; it refers to the formation of
chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
s from the impact of
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
s on an object. Cosmic rays are highly energetic charged
particles In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from s ...
from beyond
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
, ranging from
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s,
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...
s, and nuclei of many heavier elements. About 1% of cosmic rays also consist of free electrons. Cosmic rays cause spallation when a ray particle (e.g. a proton) impacts with
matter In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic partic ...
, including other cosmic rays. The result of the collision is the expulsion of particles (protons, neutrons, and
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...
s) from the object hit. This process goes on not only in deep space, but in Earth's upper atmosphere and crustal surface (typically the upper ten meters) due to the ongoing impact of cosmic rays.


The process

Cosmic ray spallation is thought to be responsible for the abundance in the universe of some light elements—
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ...
,
beryllium Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form mi ...
, and
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
—as well as the isotope
helium-3 Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is the ...
. This process (cosmogenic
nucleosynthesis Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons (protons and neutrons) and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in ...
) was discovered somewhat by accident during the 1970s: models of
Big Bang nucleosynthesis In physical cosmology, Big Bang nucleosynthesis (abbreviated BBN, also known as primordial nucleosynthesis) is the production of nuclei other than those of the lightest isotope of hydrogen (hydrogen-1, 1H, having a single proton as a nucleus) du ...
suggested that the amount of
deuterium Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two Stable isotope ratio, stable isotopes of hydrogen (the other being Hydrogen atom, protium, or hydrogen-1). The atomic nucleus, nucleus of a deuterium ato ...
was too large to be consistent with the expansion rate of the universe and there was therefore great interest in processes that could generate deuterium after the Big Bang nucleosynthesis. Cosmic ray spallation was investigated as a possible process to generate deuterium. As it turned out, spallation could not generate much deuterium, but the new studies of spallation showed that this process could generate lithium, beryllium and boron; indeed, isotopes of these elements are over-represented in cosmic ray nuclei, as compared with solar atmospheres (whereas hydrogen and helium are present in about primordial ratios in cosmic rays). An example of cosmic ray spallation is a neutron hitting a nitrogen-14 nucleus in the earth's atmosphere, yielding a proton, an alpha particle, and a
beryllium-10 Beryllium-10 (10Be) is a radioactive isotope of beryllium. It is formed in the Earth's atmosphere mainly by cosmic ray spallation of nitrogen and oxygen. Beryllium-10 has a half-life of 1.39 × 106 years, and decays by beta decay to stable boron- ...
nucleus, which eventually decays to boron-10. Or a proton can hit oxygen-16, yielding two protons, a neutron, and again an alpha particle and a beryllium-10 nucleus. Boron can also be created directly. The beryllium and boron are brought down to the ground by rain. See
Cosmogenic nuclide Cosmogenic nuclides (or cosmogenic isotopes) are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an '' in situ'' Solar System atom, causing nucleons (protons and neutrons) to be expelled from the atom ...
for a list of nuclides produced by cosmic ray spallation. The x-process in cosmic rays is the primary means of nucleosynthesis for the five stable isotopes of lithium, beryllium, and boron. As the proton–proton chain reaction cannot proceed beyond 4He due to the unbound nature of 5He and 5Li, and the
triple alpha process The triple-alpha process is a set of nuclear fusion reactions by which three helium-4 nuclei (alpha particles) are transformed into carbon. Triple-alpha process in stars Helium accumulates in the cores of stars as a result of the proton–pro ...
skips over all species between 4He and 12C, these elements are not produced in the main reactions of
stellar nucleosynthesis Stellar nucleosynthesis is the creation (nucleosynthesis) of chemical elements by nuclear fusion reactions within stars. Stellar nucleosynthesis has occurred since the original creation of hydrogen, helium and lithium during the Big Bang. As a ...
. In addition, nuclei of these elements (such as 7Li) are relatively weakly bound, resulting in their rapid destruction in stars and no significant accumulation, although new theory suggests that 7Li is generated primarily in novae erruptions. It was thus postulated that another nucleosynthesis process occurring outside stars was necessary to explain their existence in the universe. This process is now known to occur in cosmic rays, where lower temperature and particle density favor reactions leading to the synthesis of lithium, beryllium, and boron. In addition to the above light elements,
tritium Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus o ...
and
isotopes Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
of
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
,
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
(
carbon-14 Carbon-14, C-14, or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic materials is the basis of the radiocarbon dating method pioneered by Willard Libby and coll ...
),
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
(
phosphorus-32 Phosphorus-32 (32P) is a radioactive isotope of phosphorus. The nucleus of phosphorus-32 contains 15 protons and 17 neutrons, one more neutron than the most common isotope of phosphorus, phosphorus-31. Phosphorus-32 only exists in small quantiti ...
),
chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
,
iodine Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , and boils to a vi ...
and
neon Neon is a chemical element with the symbol Ne and atomic number 10. It is a noble gas. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with about two-thirds the density of air. It was discovered (along with krypton ...
are formed within solar system materials through cosmic ray spallation, and are termed
cosmogenic nuclide Cosmogenic nuclides (or cosmogenic isotopes) are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an '' in situ'' Solar System atom, causing nucleons (protons and neutrons) to be expelled from the atom ...
s. Since they remain trapped in the atmosphere or rock in which they formed, some can be very useful in the dating of materials by
cosmogenic radionuclide dating Surface exposure dating is a collection of geochronological techniques for estimating the length of time that a rock has been exposed at or near Earth's surface. Surface exposure dating is used to date glacial advances and retreats, erosion histo ...
, particularly in the geological field. In formation of a cosmogenic nuclide, a
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
interacts with the
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: *Atomic nucleus, the very dense central region of an atom * Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucl ...
of an ''
in situ ''In situ'' (; often not italicized in English) is a Latin phrase that translates literally to "on site" or "in position." It can mean "locally", "on site", "on the premises", or "in place" to describe where an event takes place and is used in ...
'' solar system
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and ...
, causing cosmic ray spallation. These isotopes are produced within earth materials such as
rock Rock most often refers to: * Rock (geology), a naturally occurring solid aggregate of minerals or mineraloids * Rock music, a genre of popular music Rock or Rocks may also refer to: Places United Kingdom * Rock, Caerphilly, a location in Wales ...
s or
soil Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
, in
Earth's atmosphere The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for ...
, and in extraterrestrial items such as
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
s. By measuring cosmogenic isotopes, scientists are able to gain insight into a range of
geological Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Eart ...
and
astronomical Astronomy () is a natural science that studies celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and evolution. Objects of interest include planets, moons, stars, nebulae, galaxies ...
processes. There are both
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
and
stable A stable is a building in which livestock, especially horses, are kept. It most commonly means a building that is divided into separate stalls for individual animals and livestock. There are many different types of stables in use today; the ...
cosmogenic isotopes. Some of the well-known naturally-occurring radioisotopes are
tritium Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus o ...
, carbon-14, and
phosphorus-32 Phosphorus-32 (32P) is a radioactive isotope of phosphorus. The nucleus of phosphorus-32 contains 15 protons and 17 neutrons, one more neutron than the most common isotope of phosphorus, phosphorus-31. Phosphorus-32 only exists in small quantiti ...
. The timing of their formation determines whether nuclides formed by cosmic ray spallation are termed primordial or are termed cosmogenic (a nuclide cannot belong to both classes). The stable nuclides of lithium, beryllium, and boron found on Earth are thought to have been formed by the same process as the cosmogenic nuclides but at an earlier time in cosmic ray spallation predominantly before the solar system's formation, and thus they are by definition
primordial nuclide In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
s and not cosmogenic. In contrast, the radioactive nuclide beryllium-7 falls into the same light element range but has a half-life too short for it to have been formed before the formation of the solar system, so that it cannot be a primordial nuclide. Since the cosmic ray spallation route is the most likely source of beryllium-7 in the environment, it is therefore cosmogenic.


See also

*
Cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
*
Cosmogenic nuclide Cosmogenic nuclides (or cosmogenic isotopes) are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an '' in situ'' Solar System atom, causing nucleons (protons and neutrons) to be expelled from the atom ...
*
Nuclear fission Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radio ...
*
Nucleosynthesis Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons (protons and neutrons) and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in ...
*
Astrophysics Astrophysics is a science that employs the methods and principles of physics and chemistry in the study of astronomical objects and phenomena. As one of the founders of the discipline said, Astrophysics "seeks to ascertain the nature of the h ...
*
Spall Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ba ...
, or spalling * Spallation *
Spallation Neutron Source The Spallation Neutron Source (SNS) is an accelerator-based neutron source facility in the U.S. that provides the most intense pulsed neutron beams in the world for scientific research and industrial development.In 2007, SNS was entered into thG ...
*
ISIS neutron source The ISIS Neutron and Muon Source is a pulsed neutron and muon source, established 1984 at the Rutherford Appleton Laboratory of the Science and Technology Facilities Council, on the Harwell Science and Innovation Campus in Oxfordshire, U ...
* PSI Spallation Neutron Source (SINQ)


References

*


Further reading

*


External links


Ray Isotope Spectrometer

University of Leeds paper
proceedings of the 26th
ICRC The International Committee of the Red Cross (ICRC; french: Comité international de la Croix-Rouge) is a humanitarian organization which is based in Geneva, Switzerland, and it is also a three-time Nobel Prize Laureate. State parties (signator ...
.(Link down, Jan 2011)
Heavy Cosmic Ray propagation Using New Spallation Cross-Section Expressions
{dead link, date=January 2018 , bot=InternetArchiveBot , fix-attempted=yes , proceedings of the 26th
ICRC The International Committee of the Red Cross (ICRC; french: Comité international de la Croix-Rouge) is a humanitarian organization which is based in Geneva, Switzerland, and it is also a three-time Nobel Prize Laureate. State parties (signator ...
.(Link down, Jan 2011)
Evidence for cosmic ray spallation production of helium and neon found in volcanoes
Cosmic rays Nucleosynthesis