Iron(II) sulfate (

British English British English (BrE, en-GB, or BE) is, according to Lexico, Oxford Dictionaries, "English language, English as used in Great Britain, as distinct from that used elsewhere". More narrowly, it can refer specifically to the English language in ...

: iron(II) sulphate) or ferrous sulfate denotes a range of

salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...

s with the formula Fe SO₄·''x''H₂O. These compounds exist most commonly as the hepta

hydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...

(''x'' = 7) but several values for x are known. The hydrated form is used medically to treat

iron deficiency Iron deficiency, or sideropenia, is the state in which a body lacks enough iron to supply its needs. Iron is present in all cells in the human body and has several vital functions, such as carrying oxygen to the tissues from the lungs as a key ...

, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for

sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...

), the blue-green heptahydrate (

with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same

aquo complex In chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species in aqueous solutions of many metal salts, such as metal nitrates, sulfates, and perchlorat ...

e(H₂O)₆sup>2+, which has

octahedral molecular geometry In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The oc ...

and is

paramagnetic Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, d ...

. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas. It is on the

World Health Organization's List of Essential Medicines The WHO Model List of Essential Medicines (aka Essential Medicines List or EML), published by the World Health Organization (WHO), contains the medications considered to be most effective and safe to meet the most important needs in a health ...

. In 2020, it was the 116th most commonly prescribed medication in the United States, with more than 5million prescriptions.

Uses

Industrially, ferrous sulfate is mainly used as a precursor to other iron compounds. It is a

reducing agent In chemistry, a reducing agent (also known as a reductant, reducer, or electron donor) is a chemical species that "donates" an electron to an (called the , , , or ). Examples of substances that are commonly reducing agents include the Earth meta ...

, and as such is useful for the reduction of chromate in

cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mix ...

to less toxic Cr(III) compounds. Historically ferrous sulfate was used in the textile industry for centuries as a

dye fixative A mordant or dye fixative is a substance used to set (i.e. bind) dyes on fabrics by forming a coordination complex with the dye, which then attaches to the fabric (or tissue). It may be used for dyeing fabrics or for intensifying stains in ...

. It is used historically to blacken leather and as a constituent of

iron gall ink Iron gall ink (also known as common ink, standard ink, oak gall ink or iron gall nut ink) is a purple-black or brown-black ink made from iron salts and tannic acids from vegetable sources. It was the standard ink formulation used in Europe for t ...

. The preparation of

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...

('oil of vitriol') by the distillation of green vitriol (Iron(II) sulfate) has been known for at least 700 years.

Medical use

Plant growth

Iron(II) sulfate is sold as ferrous sulfate, a soil amendment for lowering the pH of a high alkaline soil so that plants can access the soil's nutrients. In

horticulture Horticulture is the branch of agriculture that deals with the art, science, technology, and business of plant cultivation. It includes the cultivation of fruits, vegetables, nuts, seeds, herbs, sprouts, mushrooms, algae, flowers, seaweeds and no ...

it is used for treating iron

chlorosis In botany, chlorosis is a condition in which leaves produce insufficient chlorophyll. As chlorophyll is responsible for the green color of leaves, chlorotic leaves are pale, yellow, or yellow-white. The affected plant has little or no ability to ...

. Although not as rapid-acting as ferric EDTA, its effects are longer-lasting. It can be mixed with compost and dug into the soil to create a store which can last for years. Ferrous sulfate can be used as a

lawn A lawn is an area of soil-covered land planted with grasses and other durable plants such as clover which are maintained at a short height with a lawnmower (or sometimes grazing animals) and used for aesthetic and recreational purposes. L ...

conditioner. It can also be used to eliminate silvery thread moss in golf course putting greens.

Pigment and craft

Ferrous sulfate can be used to stain concrete and some limestones and sandstones a yellowish rust color.How To Stain Concrete with Iron Sulfate
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Woodworker Woodworking is the skill of making items from wood, and includes cabinet making (cabinetry and furniture), wood carving, joinery, carpentry, and woodturning. History Along with stone, clay and animal parts, wood was one of the first materials ...

s use ferrous sulfate solutions to color

maple ''Acer'' () is a genus of trees and shrubs commonly known as maples. The genus is placed in the family Sapindaceae.Stevens, P. F. (2001 onwards). Angiosperm Phylogeny Website. Version 9, June 2008 nd more or less continuously updated since http ...

wood a silvery hue. Green vitriol is also a useful reagent in the identification of mushrooms.

Historical uses

Ferrous sulfate was used in the manufacture of

ink Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thicker ...

s, most notably

, which was used from the

middle ages In the history of Europe, the Middle Ages or medieval period lasted approximately from the late 5th to the late 15th centuries, similar to the post-classical period of global history. It began with the fall of the Western Roman Empire a ...

until the end of the 18th century. Chemical tests made on the

Lachish letters The Lachish Letters or ''Lachish Ostraca'', sometimes called ''Hoshaiah Letters'', are a series of letters written in carbon ink containing Canaanite inscriptions in Ancient Hebrew on clay ostraca. The letters were discovered at the excavations at ...

() showed the possible presence of iron. It is thought that oak galls and copperas may have been used in making the ink on those letters. It also finds use in

wool Wool is the textile fibre obtained from sheep and other mammals, especially goats, rabbits, and camelids. The term may also refer to inorganic materials, such as mineral wool and glass wool, that have properties similar to animal wool. As ...

dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...

ing as a

mordant A mordant or dye fixative is a substance used to set (i.e. bind) dyes on fabrics by forming a coordination complex with the dye, which then attaches to the fabric (or tissue). It may be used for dyeing fabrics or for intensifying stains in ...

. Harewood, a material used in

marquetry Marquetry (also spelled as marqueterie; from the French ''marqueter'', to variegate) is the art and craft of applying pieces of veneer to a structure to form decorative patterns, designs or pictures. The technique may be applied to case furn ...

and

parquetry Parquet (; French for "a small compartment") is a geometric mosaic of wood pieces used for decorative effect in flooring. Parquet patterns are often entirely geometrical and angular—squares, triangles, lozenges—but may contain curves. T ...

since the 17th century, is also made using ferrous sulfate. Two different methods for the direct application of

indigo dye Indigo dye is an organic compound with a distinctive blue color. Historically, indigo was a natural dye extracted from the leaves of some plants of the ''Indigofera'' genus, in particular ''Indigofera tinctoria''; dye-bearing ''Indigofera'' pla ...

were developed in England in the 18th century and remained in use well into the 19th century. One of these, known as ''china blue'', involved iron(II) sulfate. After printing an insoluble form of indigo onto the fabric, the indigo was reduced to ''leuco''-indigo in a sequence of baths of ferrous sulfate (with reoxidation to indigo in air between immersions). The china blue process could make sharp designs, but it could not produce the dark hues of other methods. In the second half of the 1850s ferrous sulfate was used as a photographic developer for

collodion process The collodion process is an early photographic process. The collodion process, mostly synonymous with the "collodion wet plate process", requires the photographic material to be coated, sensitized, exposed, and developed within the span of about ...

images.

Hydrates

Iron(II) sulfate can be found in various states of

hydration Hydration may refer to: * Hydrate, a substance that contains water * Hydration enthalpy, energy released through hydrating a substance * Hydration reaction, a chemical addition reaction where a hydroxyl group and proton are added to a compound * ...

, and several of these forms exist in nature or were created synthetically. * FeSO₄·H₂O (mineral:

szomolnokite Szomolnokite (Fe2+SO4·H2O) is a monoclinic iron sulfate mineral forming a complete solid solution with magnesium end-member kieserite (MgSO4·H2O). In 1877 szomolnokite's name was derived by Joseph Krenner from its type locality of oxidized sulfi ...

, relatively rare,

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...

) * FeSO₄·H₂O (synthetic compound stable at pressures exceeding 6.2 GPa,

triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal is ...

) * FeSO₄·4H₂O (mineral:

rozenite Rozenite is a hydrous iron sulfate mineral, Fe2+SO4•4(H2O). It occurs as a secondary mineral, formed under low humidity at less than as an alteration of copper-free melanterite, which is a post mine alteration product of pyrite or marcasite. It ...

, white, relatively common, may be dehydration product of melanterite, monoclinic) * FeSO₄·5H₂O (mineral:

siderotil Siderotil is an iron(II) sulfate hydrate mineral with formula: FeSO4·5H2O which forms by the dehydration of melanterite. Copper commonly occurs substituting for iron in the structure. It typically occurs as fibrous or powdery encrustations, but m ...

, relatively rare, triclinic) * FeSO₄·6H₂O (mineral: ferrohexahydrite, very rare, monoclinic) * FeSO₄·7H₂O (mineral:

melanterite Melanterite is a mineral form of hydrous iron(II) sulfate: FeSO4·7H2O. It is the iron analogue of the copper sulfate chalcanthite. It alters to siderotil by loss of water. It is a secondary sulfate mineral which forms from the oxidation of prima ...

, blue-green, relatively common, monoclinic) Síran železnatý

The tetrahydrate is stabilized when the temperature of aqueous solutions reaches . At these solutions form both the tetrahydrate and monohydrate. Mineral forms are found in oxidation zones of iron-bearing ore beds, e.g.

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...

marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...

chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...

, etc. They are also found in related environments, like coal fire sites. Many rapidly dehydrate and sometimes oxidize. Numerous other, more complex (either basic, hydrated, and/or containing additional cations) Fe(II)-bearing sulfates exist in such environments, with

copiapite Copiapite is a hydrated iron sulfate mineral with formula: Fe2+Fe3+4(SO4)6(OH)2·20(H2O). Copiapite can also refer to a mineral group, the copiapite group. Copiapite is strictly a secondary mineral forming from the weathering or oxidation of iro ...

being a common example.

Production and reactions

In the finishing of

steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...

prior to plating or coating, the steel sheet or rod is passed through pickling baths of sulfuric acid. This treatment produces large quantities of iron(II) sulfate as a by-product. :Fe + H₂SO₄ → FeSO₄ + H₂ Another source of large amounts results from the production of

titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolubl ...

from

ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...

via the sulfate process. Ferrous sulfate is also prepared commercially by oxidation of

: :2 FeS₂ + 7 O₂ + 2 H₂O → 2 FeSO₄ + 2 H₂SO₄ It can be produced by displacement of metals less reactive than

Iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

from solutions of their sulfate: :CuSO₄ + Fe → FeSO₄ + Cu

Reactions

Upon dissolving in water, ferrous sulfates form the

metal aquo complex In chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species in aqueous solutions of many metal salts, such as metal nitrates, sulfates, and perchlorat ...

e(H₂O)₆sup>2+, which is an almost colorless,

ion. On heating, iron(II) sulfate first loses its

water of crystallization In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is ...

and the original green crystals are converted into a white

anhydrous A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achie ...

solid. When further heated, the anhydrous material decomposes into

sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...

and

sulfur trioxide Sulfur trioxide (alternative spelling sulphur trioxide, also known as ''nisso sulfan'') is the chemical compound with the formula SO3. It has been described as "unquestionably the most important economically" sulfur oxide. It is prepared on an ind ...

, leaving a reddish-brown

iron(III) oxide Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally ...

Thermolysis Thermal decomposition, or thermolysis, is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is req ...

of iron(II) sulfate begins at about . :2FeSO_4->

Delta Delta commonly refers to: * Delta (letter) (Δ or δ), a letter of the Greek alphabet * River delta, at a river mouth * D ( NATO phonetic alphabet: "Delta") * Delta Air Lines, US * Delta variant of SARS-CoV-2 that causes COVID-19 Delta may also ...

e_2O_3 + SO_2 + SO_3 Like other iron(II) salts, iron(II) sulfate is a reducing agent. For example, it reduces

nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...

nitrogen monoxide Nitric oxide (nitrogen oxide or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its c ...

and

chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...

chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...

: :6 FeSO₄ + 3 H₂SO₄ + 2 HNO₃ → 3 Fe₂(SO₄)₃ + 4 H₂O + 2 NO :6 FeSO₄ + 3 Cl₂ → 2 Fe₂(SO₄)₃ + 2 FeCl₃ Its mild reducing power is of value in organic synthesis. It is used as the iron catalyst component of

Fenton's reagent Fenton's reagent is a solution of hydrogen peroxide (H2O2) with ferrous iron (typically iron(II) sulfate, FeSO4) as a catalyst that is used to oxidize contaminants or waste waters as part of an advanced oxidation process. Fenton's reagent can be us ...

. Ferrous sulfate can be detected by the cerimetric method, which is the official method of the Indian Pharmacopoeia. This method includes the use of ferroin solution showing a red to light green colour change during titration.

References

External links

* * * {{Authority control Iron(II) compounds Sulfates World Health Organization essential medicines