Chalcanthum
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Chalcanthum
In alchemy, chalcanthum, also called chalcanth or calcanthum, was a term used for the compound blue vitriol (CuSO4), and the ink made from it. The term was also applied to red vitriol (a native sulfate of cobalt), and to green vitriol (ferrous sulfate). Some maintained calcanthum to be the same thing as colcothar, while others believed it was simply vitriol (sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...). References #{{1728, title=Chalcanthum #''Webster's Revised Unabridged Dictionary'' (1913) Alchemical substances Sulfates ...
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Blue Vitriol
Copper(II) sulfate, also known as copper sulphate, is an inorganic compound with the chemical formula . It forms hydrates , where ''n'' can range from 1 to 7. The pentahydrate (''n'' = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate. Older names for the pentahydrate include blue vitriol, bluestone, vitriol of copper,Antoine-François de Fourcroy, tr. by Robert Heron (1796) "Elements of Chemistry, and Natural History: To which is Prefixed the Philosophy of Chemistry". J. Murray and others, Edinburgh. Page 348. and Roman vitriol.Oxford University Press,Roman vitriol, Oxford Living Dictionaries. Accessed on 2016-11-13 It exothermically dissolves in water to give the aquo complex , which has octahedral molecular geometry. The structure of the solid pentahydrate reveals a polymeric structure wherein copper is again octahedral but bound to four water ligands. The centers are interconnected by sulfate anions to form chains. Anhydrous copper sulf ...
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Green Vitriol
Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the hepta hydrate (''x'' = 7) but several values for x are known. The hydrated form is used medically to treat iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for sulfate), the blue-green heptahydrate ( hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex e(H2O)6sup>2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas. It is on the World Health Organization's List of Essential Medicines. In 2020, it was the 1 ...
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Colcothar
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally as the mineral magnetite. As the mineral known as hematite, Fe2O3 is the main source of iron for the steel industry. Fe2O3 is readily attacked by acids. Iron(III) oxide is often called rust, and to some extent this label is useful, because rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as Hydrous ferric oxide. Structure Fe2O3 can be obtained in various polymorphs. In the main one, α, iron adopts octahedral coordination geometry. That is, each Fe center is bound to six oxygen ligands. In the γ polymorph, some of the Fe sit on tetrahedral sites, with four oxygen ligands. Alpha phase α-Fe2O3 has the rhombohedral, corundum (α-Al2O3) structure and i ...
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Alchemy
Alchemy (from Arabic: ''al-kīmiyā''; from Ancient Greek: χυμεία, ''khumeía'') is an ancient branch of natural philosophy, a philosophical and protoscientific tradition that was historically practiced in China, India, the Muslim world, and Europe. In its Western form, alchemy is first attested in a number of pseudepigraphical texts written in Greco-Roman Egypt during the first few centuries AD.Principe, Lawrence M. The secrets of alchemy'. University of Chicago Press, 2012, pp. 9–14. Alchemists attempted to purify, mature, and perfect certain materials. Common aims were chrysopoeia, the transmutation of "base metals" (e.g., lead) into "noble metals" (particularly gold); the creation of an elixir of immortality; and the creation of panaceas able to cure any disease. The perfection of the human body and soul was thought to result from the alchemical ''magnum opus'' ("Great Work"). The concept of creating the philosophers' stone was variously connected with all of the ...
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Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, using the s ...
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Red Vitriol
Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively. The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic. Preparation, and structure It forms by the reaction of metallic cobalt, its oxide, hydroxide, or carbonate with aqueous sulfuric acid: :Co + H2SO4 + 7 H2O → CoSO4(H2O)7 + H2 :CoO + H2SO4 + 6 H2O → CoSO4(H2O)7 The heptahydrate is only stable at humidity >70% at room temperature, otherwise it converts to the hexahydrate. The hexahydrate converts to the monohydrate and the anhydrous forms at 100 and 250 °C, respectively. :CoSO4(H2O)7 → CoSO4(H2O)6 + H2O :CoSO4(H2O)6 → CoSO4(H2O) + 5H2O :CoSO4(H2O) → CoSO4 + H2O The hexahydrate is a metal aquo complex consisting of octahedral o(H2O)6sup>2+ ions associated with sulfate a ...
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Vitriol
Vitriol is the general chemical name encompassing a class of chemical compound comprising sulfates of certain metalsoriginally, iron or copper. Those mineral substances were distinguished by their color, such as green vitriol for hydrated iron(II) sulfate and blue vitriol for hydrated copper(II) sulfate.Vitriol
entry in the online Encyclopaedia Britannica. Accessed on 2020-08-28.
These materials were originally found as crystals formed by evaporation of groundwater that percolated through minerals and collected in pools on the floor of old s. The word ''vitriol'' comes from the Latin word ''vitriolus'', meanin ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released may boi ...
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Alchemical Substances
Alchemical studies produced a number of substances, which were later classified as particular chemical compounds or mixtures of compounds. Many of these terms were in common use into the 20th century. Metals and metalloids * Antimony/ – Sb * Bismuth (german: Wismuth) – Bi * Copper/ – associated with Venus. Cu * Gold/ – associated with the Sun. Au * Iron/ – associated with Mars. Fe * Lead/ – associated with Saturn. Pb * Quicksilver/ – associated with Mercury. Hg * Silver/ – associated with the Moon. Ag * Tin/ – associated with Jupiter. Sn Minerals, stones, and pigments * Bluestone – mineral form of copper(II) sulfate pentahydrate, also called blue vitriol. * Borax – sodium borate; was also used to refer to other related minerals. * Cadmia/Tuttia/Tutty – probably zinc carbonate. * Calamine – zinc carbonate. * Calomel/Horn Quicksilver/horn mercury – mercury(I) chloride, a very poisonous purgative formed by subliming a mixture of mercuric chlori ...
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