chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...

, chromism is a process that induces a change, often reversible, in the

color Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...

s of compounds. In most cases, chromism is based on a change in the

electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...

states of

molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...

s, especially the π- or d-electron state, so this phenomenon is induced by various external stimuli which can alter the electron density of substances. It is known that there are many natural compounds that have chromism, and many artificial compounds with specific chromism have been synthesized to date. It is usually synonymous with chromotropism, the (reversible) change in color of a substance due to the physical and

chemical properties A chemical property is any of a material's properties that becomes evident during, or after, a chemical reaction; that is, any quality that can be established only by changing a substance's chemical identity.William L. Masterton, Cecile N. Hurley ...

of its ambient surrounding medium, such as temperature and pressure, light, solvent, and presence of

ions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...

and

electrons The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...

. Chromism is classified by what kind of stimuli are used. Examples of the major kinds of chromism are as follows. *

thermochromism Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a differen ...

is chromism that is induced by heat, that is, a change of temperature. This is the most common chromism of all. *

photochromism Photochromism is the reversible transformation of a chemical species (photoswitch) between two forms by the absorption of electromagnetic radiation (photoisomerization), where the two forms have different absorption spectra. In plain language, th ...

is induced by light irradiation. This phenomenon is based on the

isomerization In chemistry, isomerization or isomerisation is the process in which a molecule, polyatomic ion or molecular fragment is transformed into an isomer with a different chemical structure. Enolization is an example of isomerization, as is tautomeriz ...

between two different molecular structures, light-induced formation of color centers in crystals, precipitation of metal particles in a glass, or other mechanisms. *

electrochromism Electrochromism is a phenomenon in which a material displays changes in color or opacity in response to an electrical stimulus. In this way, a smart window made of an electrochromic material can block specific wavelengths of ultraviolet, visib ...

is induced by the gain and loss of

s. This phenomenon occurs in compounds with

redox Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction ...

active sites, such as metal

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...

s or organic radicals. *

solvatochromism In chemistry, solvatochromism is the phenomenon observed when the colour due to a solute is different when that solute is dissolved in different solvents. The solvatochromic effect is the way the spectrum of a substance (the solute) varies when th ...

depends on the

polarity Polarity may refer to: Science *Electrical polarity, direction of electrical current *Polarity (mutual inductance), the relationship between components such as transformer windings * Polarity (projective geometry), in mathematics, a duality of ord ...

of the

solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...

. Most solvatochromic compounds are

metal complexes A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many ...

. There are many more chromisms and these are listed below in . The output from the chromisms described above is observed by a change in the absorption spectra of the

chromic material Chromic means of, relating to, or containing chromium. *Chromic acid * Chromic phenomenon *Chromic anhydride Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO3. It is the ac ...

. An increasingly important group of chromisms are those where changes are displayed in their emission spectra. Hence they are called fluorochromisms, exemplified by solvatofluorochromism, electrofluorochromism and mechanofluorochromism.

Chromic phenomena

Chromic phenomena are those phenomena in which color is produced when

light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 tera ...

interacts with materials, often called

chromic materials Chromic means of, relating to, or containing chromium. *Chromic acid * Chromic phenomenon *Chromic anhydride Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO3. It is the ac ...

in a variety of ways. These can be categorized under the following five headings: *Stimulated (reversible) color change *The

absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...

and

reflection Reflection or reflexion may refer to: Science and technology * Reflection (physics), a common wave phenomenon ** Specular reflection, reflection from a smooth surface *** Mirror image, a reflection in a mirror or in water ** Signal reflection, in ...

of light *The absorption of energy followed by the emission of light *The absorption of light and energy transfer (or conversion) *The manipulation of light.

Color change phenomena

Those phenomena which involve the change in color of a chemical compound under an external stimulus fall under the generic term of chromisms. They take their individual names from the type of the external influence, which can be either

chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...

physical Physical may refer to: *Physical examination In a physical examination, medical examination, or clinical examination, a medical practitioner examines a patient for any possible medical signs or symptoms of a medical condition. It generally co ...

, that is involved. Many of these phenomena are reversible. The following list includes all the classic chromisms plus many others of increasing interest in newer outlets. There are also chromisms which involve two or more stimuli. Examples include: * Photoelectrochromism – Photovoltachromism – Bioelectrochromism – Solvatophotochromism – Thermosolvatochromism – Halosolvatochromism – Electromechanochromism. Color changes are also observed on the interaction of metallic nanoparticles and their attached

ligands In coordination chemistry, a ligand is an ion or molecule (functional group) that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electro ...

with another stimulus. Examples include plasmonic solvatochromism, plasmonic ionochromism, plasmonic chronochromism and plasmonic vapochromism.

Commercial applications

Color change materials have been used in several very common outlets but also in an increasing number of new ones. Commercial applications include

photochromic Photochromism is the reversible transformation of a chemical species (photoswitch) between two forms by the absorption of electromagnetic radiation (photoisomerization), where the two forms have different absorption spectra. In plain language, th ...

s in ophthalmics,

fashion Fashion is a form of self-expression and autonomy at a particular period and place and in a specific context, of clothing, footwear, lifestyle, accessories, makeup, hairstyle, and body posture. The term implies a look defined by the fashion in ...

cosmetics Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protect ...

security Security is protection from, or resilience against, potential harm (or other unwanted coercive change) caused by others, by restraining the freedom of others to act. Beneficiaries (technically referents) of security may be of persons and social ...

sensors A sensor is a device that produces an output signal for the purpose of sensing a physical phenomenon. In the broadest definition, a sensor is a device, module, machine, or subsystem that detects events or changes in its environment and sends ...

, optical memory and

optical switch An optical transistor, also known as an optical switch or a light valve, is a device that switches or amplifies optical signals. Light occurring on an optical transistor's input changes the intensity of light emitted from the transistor's output wh ...

es,

thermochromic Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a differen ...

s in

paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...

inks Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thicker ...

plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...

s and

textile Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...

s as indicators/sensors and in

architecture Architecture is the art and technique of designing and building, as distinguished from the skills associated with construction. It is both the process and the product of sketching, conceiving, planning, designing, and constructing building ...

, ionochromics in

copy paper Copy may refer to: * Copying or the product of copying (including the plural "copies"); the duplication of information or an artifact ** Cut, copy and paste, a method of reproducing text or other data in computing ** File copying **Photocopying, a ...

, direct thermal printing and textile sensors,

electrochromic Electrochromism is a phenomenon in which a material displays changes in color or opacity in response to an electrical stimulus. In this way, a smart window made of an electrochromic material can block specific wavelengths of ultraviolet, visib ...

s in car mirrors, smart windows, flexible devices and solar protection,

solvatochromic In chemistry, solvatochromism is the phenomenon observed when the colour due to a solute is different when that solute is dissolved in different solvents. The solvatochromic effect is the way the spectrum of a substance (the solute) varies when th ...

s in biological probes and

, gasochromics in

window A window is an opening in a wall, door, roof, or vehicle that allows the exchange of light and may also allow the passage of sound and sometimes air. Modern windows are usually glazed or covered in some other transparent or translucent materia ...

s and

gas sensors A gas detector is a device that detects the presence of gases in an area, often as part of a safety system. A gas detector can sound an alarm to operators in the area where the leak is occurring, giving them the opportunity to leave. This type of d ...

Dyes and pigments

Classical

dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...

s and

pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...

s produce color by the absorption and reflection of light; these are the materials that make a major impact on the color of our daily lives. In 2000, world production of

organic Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product ...

dyes was 800,000 tonnes and of organic pigments, 250,000 tonnes and the volume has grown at a steady rate throughout the early years of this century. In 2019 the value of the organic dyes/pigments market is forecast to be $19.5bn. Their value is exceeded by the very large production of

inorganic In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...

pigments. Organic dyes are used mainly to color textile fibers,

paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distributed ...

hair Hair is a protein filament that grows from follicles found in the dermis. Hair is one of the defining characteristics of mammals. The human body, apart from areas of glabrous skin, is covered in follicles which produce thick terminal and f ...

leather Leather is a strong, flexible and durable material obtained from the tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hogs, ...

, while pigments are used largely in

ink Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thi ...

and

. Both are used in the growth area of the

digital printing Digital printing is a method of printing from a digital-based image directly to a variety of media. It usually refers to professional printing where small-run jobs from desktop publishing and other digital sources are printed using large-format ...

of textiles, paper and other surfaces. Dyes are also made using the properties of chromic substances: Examples being Photochromic dyes and Thermochromic dyes

Luminescence

The absorption of energy followed by the emission of light is often described by the term ''

luminescence Luminescence is spontaneous emission of light by a substance not resulting from heat; or "cold light". It is thus a form of cold-body radiation. It can be caused by chemical reactions, electrical energy, subatomic motions or stress on a cryst ...

''. The exact term used is based on the energy source responsible for the luminescence as in color-change phenomena. *

Electrical Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by ...

–

electroluminescence Electroluminescence (EL) is an optical phenomenon, optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emissi ...

Galvanoluminescence Galvanoluminescence Is the emission of light produced by the passage of an electric current through an appropriate electrolyte in which an electrode, made of certain metals such as aluminium or tantalum, has been immersed. An example being the el ...

Sonoluminescence Sonoluminescence is the emission of light from imploding bubbles in a liquid when excited by sound. History The sonoluminescence effect was first discovered at the University of Cologne in 1934 as a result of work on sonar. Hermann Frenzel and ...

. * Photons (light) –

Photoluminescence Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photon ...

Fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...

Phosphorescence Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...

Biofluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...

. *

Chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...

–

Chemiluminescence Chemiluminescence (also chemoluminescence) is the emission of light (luminescence) as the result of a chemical reaction. There may also be limited emission of heat. Given reactants A and B, with an excited intermediate ◊, : + -> lozenge -> ...

Bioluminescence Bioluminescence is the production and emission of light by living organisms. It is a form of chemiluminescence. Bioluminescence occurs widely in marine vertebrates and invertebrates, as well as in some fungi, microorganisms including some b ...

Electrochemiluminescence Electrochemiluminescence or electrogenerated chemiluminescence (ECL) is a kind of luminescence produced during electrochemical reactions in solutions. In electrogenerated chemiluminescence, electrochemically generated intermediates undergo a highl ...

. *

Thermal A thermal column (or thermal) is a rising mass of buoyant air, a convective current in the atmosphere, that transfers heat energy vertically. Thermals are created by the uneven heating of Earth's surface from solar radiation, and are an example ...

–

Thermoluminescence Thermoluminescence is a form of luminescence that is exhibited by certain crystalline materials, such as some minerals, when previously absorbed energy from electromagnetic radiation or other ionizing radiation is re-emitted as light upon he ...

Pyroluminescence Candololuminescence. *

Electron Beam Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to ele ...

–

Cathodoluminescence Cathodoluminescence is an optical and electromagnetic phenomenon in which electrons impacting on a luminescent material such as a phosphor, cause the emission of photons which may have wavelengths in the visible spectrum. A familiar example is th ...

Anodoluminescence

Radioluminescence Radioluminescence is the phenomenon by which light is produced in a material by bombardment with ionizing radiation such as alpha particles, beta particles, or gamma rays. Radioluminescence is used as a low level light source for night illumi ...

. *

Mechanical Mechanical may refer to: Machine * Machine (mechanical), a system of mechanisms that shape the actuator input to achieve a specific application of output forces and movement * Mechanical calculator, a device used to perform the basic operations of ...

–

Triboluminescence Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation a ...

Fractoluminescence Triboluminescence is a phenomenon in which light is generated when a material is mechanically pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation a ...

Mechanoluminescence Mechanoluminescence is light emission resulting from any mechanical action on a solid. It can be produced through ultrasound, or through other means. * Fractoluminescence is caused by stress that results in the formation of fractures. * Piezolumi ...

Crystalloluminescence Crystalloluminescence is the effect of luminescence produced during crystallization. The phenomenon was first reported in the 1800s from the rapid crystallization of potassium sulfate from an aqueous solution An aqueous solution is a solution i ...

Lyoluminescence Lyoluminescence refers to the emission of light while dissolving a solid into a liquid solvent. It is a form of chemiluminescence. The most common lyoluminescent effect is seen when solid samples which have been heavily irradiated by ionizing radia ...

Elasticoluminescence. Many of these phenomena are widely used in

consumer product A final good or consumer good is a final product ready for sale that is used by the consumer to satisfy current wants or needs, unlike a intermediate good, which is used to produce other goods. A microwave oven or a bicycle is a final good, but t ...

s and other important outlets.

is used in

cathode ray tube A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms ( oscilloscope), pictu ...

photoluminescence Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photon ...

fluorescent lighting A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet ligh ...

and

plasma display panel A plasma display panel (PDP) is a type of flat panel display that uses small cells containing plasma: ionized gas that responds to electric fields. Plasma televisions were the first large (over 32 inches diagonal) flat panel displays to be released ...

phosphorescence Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...

in safety signs and low energy lighting,

fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...

pigments A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...

, inks,

optical brightener Optical brighteners, optical brightening agents (OBAs), fluorescent brightening agents (FBAs), or fluorescent whitening agents (FWAs), are chemical compounds that absorb light in the ultraviolet and violet region (usually 340-370 nm) of the ...

safety clothing Personal protective equipment (PPE) is protective clothing, helmets, goggles, or other garments or equipment designed to protect the wearer's body from injury or infection. The hazards addressed by protective equipment include physical, elec ...

, and

biological Biology is the scientific study of life. It is a natural science with a broad scope but has several unifying themes that tie it together as a single, coherent field. For instance, all organisms are made up of cells that process hereditary in ...

and medicinal analysis and diagnostics,

chemoluminescence Chemiluminescence (also chemoluminescence) is the emission of light (luminescence) as the result of a chemical reaction. There may also be limited emission of heat. Given reactants A and B, with an excited intermediate ◊, : + -> lozenge - ...

and

bioluminescence Bioluminescence is the production and emission of light by living organisms. It is a form of chemiluminescence. Bioluminescence occurs widely in marine vertebrates and invertebrates, as well as in some fungi, microorganisms including some b ...

in analysis, diagnostics and sensors, and

in the burgeoning areas of

light-emitting diode A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...

s (LEDs/OLEDs), displays and panel lighting. Important new developments are taking place in the areas of

quantum dots Quantum dots (QDs) are semiconductor particles a few nanometres in size, having optical and electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanotechnology. When the ...

and metallic nanoparticles.

Light and energy transfer

Absorption of light and energy transfer (or conversion) involves colored molecules that can transfer electromagnetic energy, commonly in the form of a

laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...

light source, to other molecules in another form of energy, such as

thermal A thermal column (or thermal) is a rising mass of buoyant air, a convective current in the atmosphere, that transfers heat energy vertically. Thermals are created by the uneven heating of Earth's surface from solar radiation, and are an example ...

or electrical. These laser addressable colorants, also called near-infrared absorbers, are used in thermal

energy conversion Energy transformation, also known as energy conversion, is the process of changing energy from one form to another. In physics, energy is a quantity that provides the capacity to perform work or moving, (e.g. Lifting an object) or provides heat. ...

, photosensitisation of chemical reactions and the selective absorption of light. Applications areas include

optical data storage IBM defines optical storage as "any storage method that uses a laser to store and retrieve data from optical media." '' Britannica'' notes that it "uses low-power laser beams to record and retrieve digital (binary) data." Compact disc (CD) an ...

, as organic

photoconductor Photoconductivity is an optical and electrical phenomenon in which a material becomes more electrically conductive due to the absorption of electromagnetic radiation such as visible light, ultraviolet light, infrared light, or gamma radiation. Whe ...

s, as sensitisers in photomedicine, such as

photodynamic therapy Photodynamic therapy (PDT) is a form of phototherapy involving light and a photosensitizing chemical substance, used in conjunction with molecular oxygen to elicit cell death (phototoxicity). PDT is popularly used in treating acne. It is used cl ...

and

photothermal therapy Photothermal therapy (PTT) refers to efforts to use electromagnetic radiation (most often in infrared wavelengths) for the treatment of various medical conditions, including cancer. This approach is an extension of photodynamic therapy, in which a p ...

in the treatment of cancer, in photodiagnosis and phototheranostics, and in the photoinactivation of microbes, blood and insects. The absorption of natural sunlight by chromic materials/chromophores is exploited in solar cells for the production of electrical energy via

solar cells A solar cell, or photovoltaic cell, is an electronic device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physics, physical and Chemical substance, chemical phenomenon.inorganic photovoltaics and organic materials (

organic photovoltaics An organic solar cell (OSC) or plastic solar cell is a type of photovoltaic that uses organic electronics, a branch of electronics that deals with conductive organic polymers or small organic molecules, for light absorption and charge transport t ...

) and dye sensitized solar cells (DSSCs), and also in the production of useful chemicals via

artificial photosynthesis Artificial photosynthesis is a chemical process that biomimics the natural process of photosynthesis to convert sunlight, water, and carbon dioxide into carbohydrates and oxygen. The term artificial photosynthesis is commonly used to refer to ...

. A developing area is the conversion of light into kinetic energy, often described under the generic term of lightdriven/

molecular machines A molecular machine, nanite, or nanomachine is a molecular component that produces quasi-mechanical movements (output) in response to specific stimuli (input). In cellular biology, macromolecular machines frequently perform tasks essential for l ...

Light manipulation

Materials may be used to control and manipulate light via a variety of mechanisms to produce useful effects involving color. For instance, a change of orientation of molecules to produce a visual effect as in

liquid crystal display A liquid-crystal display (LCD) is a flat panel display, flat-panel display or other Electro-optic modulator, electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers. Liqui ...

s. Other materials operate by producing a physical effect, by

interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...

and

diffraction Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...

as in lustre pigments and optically variable pigments, colloidal

photonic crystals A photonic crystal is an optical nanostructure in which the refractive index changes periodically. This affects the propagation of light in the same way that the structure of natural crystals gives rise to X-ray diffraction and that the atomi ...

and in

holography Holography is a technique that enables a wavefront to be recorded and later re-constructed. Holography is best known as a method of generating real three-dimensional images, but it also has a wide range of other applications. In principle, i ...

. Increasingly inspiration is coming from Nature, in the form of bioinspired structural colors. Molecular materials are also used to increase the intensity of light by modifying its movement through the materials by electrical means, so increasing its intensity as in organic lasers, or in modifying the transmission of light through materials, as in

opto-electronics Optoelectronics (or optronics) is the study and application of electronics, electronic devices and systems that find, detect and control light, usually considered a sub-field of photonics. In this context, ''light'' often includes invisible form ...

, or by purely by all optical means as in optical limiters.

References

Bibliography

*Bamfield Peter and Hutchings Michael, Chromic Phenomena; technological applications of colour chemistry, 3rd Edition, Royal Society of Chemistry, Cambridge, 2018. . *Vik Michal and Periyasamy Aravin Prince, Chromic Materials; Fundamentals, Measurements and Applications, Apple Academic Press, 2018. . *Ferrara Mariella and Murat Bengisu, Materials that Change Color: Smart Materials and Intelligent Design, Springer, 2014. {{Color topics Photochemistry