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Thermochromism
Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a different color when cool enough to drink, or kettles which change color when water is at or near boiling point. Thermochromism is one of several types of chromism. Organic materials Thermochromatic liquid crystals The two common approaches are based on liquid crystals and leuco dyes. Liquid crystals are used in precision applications, as their responses can be engineered to accurate temperatures, but their color range is limited by their principle of operation. Leuco dyes allow wider range of colors to be used, but their response temperatures are more difficult to set with accuracy. Some liquid crystals are capable of displaying different colors at different temperatures. This change is dependent on selective reflection of certain wavelengt ...
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Leuco Dye
A leuco dye (from the Greek λευκός ''leukos'': white ) is a dye which can switch between two chemical forms; one of which is colorless. Reversible transformations can be caused by heat, light or pH; resulting in examples of thermochromism, photochromism and halochromism respectively. Irreversible transformations typically involve reduction or oxidation.Chemistry and Applications of Leuco Dyes. Ramaiah Muthyala. 302 pag. Springer; 1997 edition. The colorless form is sometimes referred to as the leuco form. Leuco dyes form the basis of thermal printer papers and certain pH indicators. Examples The most common example is in applying sulfur dyes and vat dyes; with indigo being a classic case. This is characteristically purple but is also completely insoluble in water, meaning that it cannot be applied to clothes directly. It is instead reduced to indigo white (sometimes Leucoindigo), which is water-soluble but colorless. When a submerged fabric is removed from a dyebath of ...
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Spiropyran
A spiropyran is a type of organic chemical compound, known for photochromic properties that provide this molecule with the ability of being used in medical and technological areas. Spiropyrans were discovered in the early twentieth century. However, it was in the middle twenties when Fisher and Hirshbergin observed their photochromic characteristics and reversible reaction. In 1952, Fisher and co-workers announced for the first time photochromism in spiropyrans. Since then, there have been many studies on photochromic compounds that have continued up to the present. Synthesis There are two methods for the production of spiropyrans. The first one can be by condensation of methylene bases with o-hydroxy aromatic aldehydes (or the condensation of the precursor of methylene bases). Spiropyrans generally could be obtained by boiling the aldehyde and the respective benzazolium salts in presence of pyridine or piperidine. The general formula of the synthesis of spiropyrans is shown in th ...
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Mood Ring
A mood ring is a finger ring that contains a thermochromic element, or "mood stone", that changes colors based on the temperature of the finger of the wearer. Finger temperature, as long as the ambient temperature is relatively constant, is significantly determined by peripheral blood flow, which is modulated by the autonomic nervous system. A mood ring contains liquid crystals Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. The ... that change color depending on the temperature. See also * Liquid crystal thermometer References {{DEFAULTSORT:Mood Ring 1970s fads and trends 1970s fashion Novelty items Rings (jewellery) Thermochromism ...
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Chromism
In chemistry, chromism is a process that induces a change, often reversible, in the colors of compounds. In most cases, chromism is based on a change in the electron states of molecules, especially the π- or d-electron state, so this phenomenon is induced by various external stimuli which can alter the electron density of substances. It is known that there are many natural compounds that have chromism, and many artificial compounds with specific chromism have been synthesized to date. It is usually synonymous with chromotropism, the (reversible) change in color of a substance due to the physical and chemical properties of its ambient surrounding medium, such as temperature and pressure, light, solvent, and presence of ions and electrons. Chromism is classified by what kind of stimuli are used. Examples of the major kinds of chromism are as follows. * thermochromism is chromism that is induced by heat, that is, a change of temperature. This is the most common chromism of all. * pho ...
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Hypercolor
Hypercolor was a line of clothing, mainly T-shirts and shorts, that changed color with heat. They were manufactured by Generra Sportswear Company of Seattle and marketed in the United States as Generra Hypercolor or Generra Hypergrafix and elsewhere as Global Hypercolor. They contained a thermochromic pigment made by Matsui Shikiso Chemical of Japan, that changed between two colors—one when cold, one when warm. The shirts were produced with several color change choices beginning in 1991. The effect could easily be permanently damaged, particularly when the clothing was washed in hotter than recommended water, ironed, bleached, or tumble-dried. Generra Sportswear Co. had originally been founded as a men's sportswear distributor and importer in Seattle in 1980. The company was sold to Texas-based Farah Manufacturing Co. in 1984 and bought back by its founders in 1989. In 1986, the company added childrenswear and womenswear items to their portfolio. They struggled to meet ...
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Thermochromic Mug
A mug is a type of cup typically used for drinking hot drinks, such as coffee, hot chocolate, or tea. Mugs usually have handles and hold a larger amount of fluid than other types of cup. Typically, a mug holds approximately of liquid. A mug is a less formal style of drink container and is not usually used in formal place settings, where a teacup or coffee cup is preferred. Shaving mugs are used to assist in wet shaving. Ancient mugs were usually carved in wood or bone, ceramic or shaped of clay, while most modern ones are made of ceramic materials such as bone china, earthenware, porcelain, or stoneware. Some are made from strengthened glass, such as Pyrex. Other materials, including enameled metal, plastic, or steel are preferred, when reduced weight or resistance to breakage is at a premium, such as for camping. A travel mug is insulated and has a cover with a small sipping opening to prevent spills. Techniques such as silk screen printing or decals are used to apply decorati ...
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Liquid Crystal
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. LC materials may not always be in a LC state of matter (just as water may be ice or water vapor). Liquid crystals can be divided into 3 main types: * thermotropic, *lyotropic, and * metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as temperature changes. Lyotropic LCs exhibit phase transitions as a function of b ...
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Generra Hypercolor
Hypercolor was a line of clothing, mainly T-shirts and shorts, that changed color with heat. They were manufactured by Generra Sportswear Company of Seattle and marketed in the United States as Generra Hypercolor or Generra Hypergrafix and elsewhere as Global Hypercolor. They contained a thermochromic pigment made by Matsui Shikiso Chemical of Japan, that changed between two colors—one when cold, one when warm. The shirts were produced with several color change choices beginning in 1991. The effect could easily be permanently damaged, particularly when the clothing was washed in hotter than recommended water, ironed, bleached, or tumble-dried. Generra Sportswear Co. had originally been founded as a men's sportswear distributor and importer in Seattle in 1980. The company was sold to Texas-based Farah Manufacturing Co. in 1984 and bought back by its founders in 1989. In 1986, the company added childrenswear and womenswear items to their portfolio. They struggled to meet ...
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Nematic
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC Phase (matter), phases, which can be distinguished by their Optics, optical properties (such as Texture (crystalline), textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. LC materials may not always be in a LC state of matter (just as water may be ice or water vapor). Liquid crystals can be divided into 3 main types: *thermotropic, *lyotropic, and *#Metallotropic liquid crystals, metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as tempera ...
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Weak Acid
Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a hydron (chemistry), proton, H+, and an anion, A-. The Dissociation (chemistry), dissociation of a strong acid in solution is effectively complete, except in its most concentrated solutions. :HA -> H+ + A- Examples of strong acids are hydrochloric acid (HCl), perchloric acid (HClO4), nitric acid (HNO3) and sulfuric acid (H2SO4). A weak acid is only partially dissociated, with both the undissociated acid and its dissociation products being present, in solution, in Equilibrium chemistry, equilibrium with each other. :HA H+ + A- Acetic acid (CH3COOH) is an example of a weak acid. The strength of a weak acid is quantified by its acid dissociation constant, K_\ce value. The strength of a weak organic chemistry, organic acid may depend on substituent effects. The strength of an inorganic chemistry, inorganic acid is dependent on the oxidation state for the atom to which the prot ...
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Microcapsule
Microencapsulation is a process in which tiny particles or droplets are surrounded by a coating to give small capsules, with useful properties. In general, it is used to incorporate food ingredients, enzymes, cells or other materials on a micro metric scale. Microencapsulation can also be used to enclose solids, liquids, or gases inside a micrometric wall made of hard or soft soluble film, in order to reduce dosing frequency and prevent the degradation of pharmaceuticals. In its simplest form, a microcapsule is a small sphere comprising a near-uniform wall enclosing some material. The enclosed material in the microcapsule is referred to as the core, internal phase, or fill, whereas the wall is sometimes called a shell, coating, or membrane. Some materials like lipids and polymers, such as alginate, may be used as a mixture to trap the material of interest inside. Most microcapsules have pores with diameters between a few nanometers and a few micrometers. Materials generally used f ...
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Crystal Violet Lactone
Crystal violet lactone (CVL) is a leuco dye, a lactone derivate of crystal violet 10B. In pure state it is a slightly yellowish crystalline powder, soluble in nonpolar or slightly polar organic solvents. The central carbon in the leuco form is in a tetrahedral configuration, with four covalent bonds. In an acidic environment, the lactone ring is broken, with the oxygen detaching from the central carbon. This now-trivalent position is a planar carbocation that is resonance stabilized, interconnecting the π systems of the aromatic rings and the amino functional groups. This single large conjugated system is a chromophore with strong absorption in visible spectrum, giving this compound its distinctive color. This chemical is usually drawn in the resonance structure with the cation on nitrogen. : It was the first dye used in carbonless copy papers, and it is still widely used in this application. It is also the leuco dye component in some thermochromic dyes, e.g. in the Hypercolor ...
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