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Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
and originally formed deep under the sea by the compression of microscopic plankton that had settled to the
sea floor The seabed (also known as the seafloor, sea floor, ocean floor, and ocean bottom) is the bottom of the ocean. All floors of the ocean are known as 'seabeds'. The structure of the seabed of the global ocean is governed by plate tectonics. Most of ...
. Chalk is common throughout Western Europe, where deposits underlie parts of France, and steep cliffs are often seen where they meet the sea in places such as the Dover cliffs on the Kent coast of the English Channel. Chalk is mined for use in industry, such as for
quicklime Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ma ...
,
brick A brick is a type of block used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a block composed of dried clay, but is now also used informally to denote other chemically cured cons ...
s and builder's
putty Putty is a material with high plasticity, similar in texture to clay or dough, typically used in domestic construction and repair as a sealant or filler. Although some types of putty (typically those using linseed oil) slowly polymerise and be ...
, and in agriculture, for raising pH in soils with high acidity. It is also used for " blackboard chalk" for writing and drawing on various types of surfaces, although these can also be manufactured from other carbonate-based minerals, or gypsum.


Description

Chalk is a fine-textured, earthy type of limestone distinguished by its light color, softness, and high porosity. It is composed mostly of tiny fragments of the
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
shells or skeletons of plankton, such as foraminifera or coccolithophores. These fragments mostly take the form of calcite plates ranging from 0.5 to 4 microns in size, though about 10% to 25% of a typical chalk is composed of fragments that are 10 to 100 microns in size. The larger fragments include intact plankton skeletons and skeletal fragments of larger organisms, such as
mollusc Mollusca is the second-largest phylum of invertebrate animals after the Arthropoda, the members of which are known as molluscs or mollusks (). Around 85,000  extant species of molluscs are recognized. The number of fossil species is esti ...
s, echinoderms, or bryozoans. Chalk is typically almost pure calcite, , with just 2% to 4% of other minerals. These are usually quartz and
clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals ...
s, though collophane (cryptocrystalline
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...
, a phosphate mineral) is also sometimes present, as nodules or as small pellets interpreted as fecal pellets. In some chalk beds, the calcite has been converted to
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
, , and in a few cases the dolomitized chalk has been dedolomitized back to calcite. Chalk is highly porous, with typical values of porosity ranging from 35 to 47 per cent. While it is similar in appearance to both gypsum and diatomite, chalk is identifiable by its hardness, fossil content, and its reaction to
acid In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequ ...
(it produces effervescence on contact).


Formation

Chalk was formed in the Cretaceous Period, between 99 and 65 million years ago. It was deposited on extensive
continental shelves A continental shelf is a portion of a continent that is submerged under an area of relatively shallow water, known as a shelf sea. Much of these shelves were exposed by drops in sea level during glacial periods. The shelf surrounding an island ...
at depths between , during a time of nonseasonal (likely arid) climate that reduced the amount of erosion from nearby exposed rock. The lack of nearby erosion explains the high purity of chalk. The coccolithophores, foraminifera, and other microscopic organisms from which the chalk came mostly form low-magnesium calcite skeletons, so the sediments were already in the form of highly stable low-magnesium calcite when deposited. This is in contrast with most other limestones, which formed from high-magnesium calcite or aragonite that rapidly converted to the more stable low-magnesium calcite after deposition. Because this conversion process is responsible for the early cementing of limestone, chalk lacked early cementing, which partially accounts for its high porosity. Chalk is also the only form of limestone that commonly shows signs of compaction. Flint (a type of chert) is very common as bands parallel to the bedding or as nodules in
seams Seam may refer to: Science and technology * Seam (geology), a stratum of coal or mineral that is economically viable; a bed or a distinct layer of vein of rock in other layers of rock * Seam (metallurgy), a metalworking process the joins the ends ...
, or linings to
fractures Fracture is the separation of an object or material into two or more pieces under the action of stress. The fracture of a solid usually occurs due to the development of certain displacement discontinuity surfaces within the solid. If a displa ...
, embedded in chalk. It is probably derived from sponge spicules or other siliceous organisms as water is expelled upwards during compaction. Flint is often deposited around larger fossils such as Echinoidea which may be silicified (i.e. replaced molecule by molecule by flint).


Geology and geographic distribution

Chalk is so common in Cretaceous marine beds that the Cretaceous Period was named for these deposits. The name Cretaceous was derived from Latin ''creta'', meaning ''chalk''. The
Chalk Group The Chalk Group (often just called the Chalk) is the lithostratigraphic unit (a certain number of rock strata) which contains the Upper Cretaceous limestone succession in southern and eastern England. The same or similar rock sequences occur acr ...
is a European stratigraphic unit deposited during the late Cretaceous Period. It forms the famous White Cliffs of Dover in Kent, England, as well as their counterparts of the Cap Blanc Nez on the other side of the Dover Strait. The
Champagne region The wine region within the historical province of Champagne in the northeast of France is best known for the production of champagne, the sparkling white wine that bears the region's name. EU law and the laws of most countries reserve the term " ...
of France is mostly underlain by chalk deposits, which contain artificial caves used for
wine storage Wine is an alcoholic drink typically made from fermented grapes. Yeast consumes the sugar in the grapes and converts it to ethanol and carbon dioxide, releasing heat in the process. Different varieties of grapes and strains of yeasts are ma ...
. Some of the highest chalk cliffs in the world occur at Jasmund National Park in Germany and at Møns Klint in Denmark. Chalk deposits are also found in Cretaceous beds on other continents, such as the Austin Chalk, Selma Group, and Niobrara Formations of the North American interior. Chalk is also found in western Egypt (Khoman Formation) and western Australia (
Miria Formation The Miria Formation is a Late Cretaceous geologic formation, in Western Australia. Possible indeterminate theropod remains have been recovered from it, as well as those of sea turtles, and possible azhdarchid pterosaurs. The lithology of the uni ...
).


Mining

Chalk is mined from chalk deposits both above ground and
underground Underground most commonly refers to: * Subterranea (geography), the regions beneath the surface of the Earth Underground may also refer to: Places * The Underground (Boston), a music club in the Allston neighborhood of Boston * The Underground (S ...
. Chalk mining boomed during the Industrial Revolution, due to the need for chalk products such as
quicklime Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ma ...
and
brick A brick is a type of block used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a block composed of dried clay, but is now also used informally to denote other chemically cured cons ...
s.


Uses

Most people first encounter chalk in school where it refers to blackboard chalk, which was originally made of mineral chalk, since it readily crumbles and leaves particles that stick loosely to rough surfaces, allowing it to make writing that can be readily erased. Blackboard chalk manufacturers now may use mineral chalk, other mineral sources of calcium carbonate, or the mineral gypsum ( calcium sulfate). While gypsum-based blackboard chalk is the lowest cost to produce, and thus widely used in the
developing world A developing country is a sovereign state with a lesser developed industrial base and a lower Human Development Index (HDI) relative to other countries. However, this definition is not universally agreed upon. There is also no clear agreem ...
, use of carbonate-based chalk produces larger particles and thus less dust, and it is marketed as "dustless chalk". Coloured chalks, pastel chalks, and
sidewalk chalk Sidewalk chalk is typically large and thick sticks of chalk (calcium sulfate, gypsum, rather than calcium carbonate, rock chalk) that come in multiple colors and are mostly used for drawing on pavement or concrete sidewalks, frequently four sq ...
(shaped into larger sticks and often coloured), used to draw on
sidewalk A sidewalk (North American English), pavement (British English), footpath in Australia, India, New Zealand and Ireland, or footway, is a path along the side of a street, street, highway, terminals. Usually constructed of concrete, pavers, brick ...
s, streets, and driveways, are primarily made of gypsum rather than calcium carbonate chalk. Glazing
putty Putty is a material with high plasticity, similar in texture to clay or dough, typically used in domestic construction and repair as a sealant or filler. Although some types of putty (typically those using linseed oil) slowly polymerise and be ...
mainly contains chalk as a filler in
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
. Chalk and other forms of limestone may be used for their properties as a base. Chalk is a source of
quicklime Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ma ...
by thermal decomposition, or
slaked lime Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed or slaked with water. It has ma ...
following quenching of quicklime with water. In agriculture, chalk is used for raising pH in soils with high acidity. Small doses of chalk can also be used as an antacid. Additionally, the small particles of chalk make it a substance ideal for cleaning and polishing. For example, toothpaste commonly contains small amounts of chalk, which serves as a mild abrasive. Polishing chalk is chalk prepared with a carefully controlled grain size, for very fine polishing of metals. Chalk beds form important
petroleum reservoir A petroleum reservoir or oil and gas reservoir is a subsurface accumulation of hydrocarbons contained in porous or fractured rock formations. Such reservoirs form when kerogen (ancient plant matter) is created in surrounding rock by the presence ...
s in the North Sea and along the Gulf Coast of North America.


Previous uses

In southeast England, deneholes are a notable example of ancient chalk pits. Such
bell pit A bell pit is a primitive method of mining coal, iron ore, or other minerals lying near the surface. Operation A shaft is sunk to reach the mineral which is excavated by miners, transported to the surface by a winch, and removed by means of a b ...
s may also mark the sites of ancient flint mines, where the prime object was to remove flint
nodules Nodule may refer to: *Nodule (geology), a small rock or mineral cluster *Manganese nodule, a metallic concretion found on the seafloor *Nodule (medicine), a small aggregation of cells *Root nodule Root nodules are found on the roots of plants, p ...
for
stone tool A stone tool is, in the most general sense, any tool made either partially or entirely out of stone. Although stone tool-dependent societies and cultures still exist today, most stone tools are associated with prehistoric (particularly Stone Ag ...
manufacture. The surface remains at Cissbury are one such example, but perhaps the most famous is the extensive complex at Grimes Graves in Norfolk. Several traditional uses of chalk have been replaced by other substances, although the word "chalk" is often still applied to the usual replacements. Tailor's chalk (also known as French chalk) is traditionally a hard chalk used to make temporary markings on cloth, mainly by tailors. It is now usually made of talc (magnesium silicate). Chalk was traditionally used in recreation. In field sports, such as tennis played on grass, powdered chalk was used to mark the boundary lines of the playing field or court. If a ball hits the line, a cloud of chalk or pigment dust will be visible. In recent years, powdered chalk has been replaced with titanium dioxide. In gymnastics, rock-climbing, weightlifting and tug of war, chalk — now usually
magnesium carbonate Magnesium carbonate, (archaic name magnesia alba), is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals. Forms The most common magnesium carbonate forms are ...
— is applied to the hands and feet to remove perspiration and reduce slipping. Chalk may also be used as a house construction material instead of
brick A brick is a type of block used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a block composed of dried clay, but is now also used informally to denote other chemically cured cons ...
or wattle and daub: quarried chalk was cut into blocks and used as
ashlar Ashlar () is finely dressed (cut, worked) stone, either an individual stone that has been worked until squared, or a structure built from such stones. Ashlar is the finest stone masonry unit, generally rectangular cuboid, mentioned by Vitruv ...
, or loose chalk was rammed into blocks and laid in mortar. There are still houses standing which have been constructed using chalk as the main building material. Most are pre-
Victorian Victorian or Victorians may refer to: 19th century * Victorian era, British history during Queen Victoria's 19th-century reign ** Victorian architecture ** Victorian house ** Victorian decorative arts ** Victorian fashion ** Victorian literature ...
though a few are more recent. A mixture of chalk and
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
can be used as
fingerprint powder Fingerprint powders are fine powders used, in conjunction with fingerprint brushes, by crime scene investigators and other law enforcement personnel to search for and enhance latent/invisible fingerprints that can be used to determine identificati ...
. However, because of the toxicity of the mercury, the use of such mixtures for fingerprinting was abandoned in 1967.


See also

* * * * * * * * * *


References


Further reading

* *{{cite web , title=Landscapes , website=White Rocks , url=http://www.geographyinaction.co.uk/Landscapes/Landscapes_WhiteRocks.html , access-date=1 December 2005 , archive-date=7 June 2009 , archive-url=https://web.archive.org/web/20090607085758/http://www.geographyinaction.co.uk/Landscapes/Landscapes_WhiteRocks.html , url-status=dead The "White Rocks" is the name given to cliffs to the east of Portrush in County Antrim, Northern Ireland. Sewing equipment