Chabazite-Ca
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Chabazite ()The New Oxford Dictionary of English (1998) - p. 300 "chabazite /'kabəzʌɪt/ noun "A colourless, pink or yellow zeolite mineral, typically occurring as rhombohedral crystals.". is a
tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
of the
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These pos ...
group, closely related to
gmelinite Gmelinite-Na is one of the rarer zeolites but the most common member of the gmelinite series, gmelinite-Ca, gmelinite-K and gmelinite-Na. It is closely related to the very similar mineral chabazite. Gmelinite was named as a single species in 182 ...
, with the chemical formula . Recognized varieties include Chabazite-Ca, Chabazite-K, Chabazite-Na, and Chabazite-Sr, depending on the prominence of the indicated
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
. Chabazite crystallizes in the
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal is ...
crystal system with typically rhombohedral shaped crystals that are pseudo-cubic. The crystals are typically twinned, and both contact twinning and penetration twinning may be observed. They may be colorless, white, orange, brown, pink, green, or yellow. The hardness ranges from 3 to 5 and the specific gravity from 2.0 to 2.2. The luster is vitreous. It was named chabasie in 1792 by Bosc d'Antic and later changed to the current spelling. Chabazite occurs most commonly in voids and
amygdule Amygdules or amygdales () form when the vesicles (pores from gas bubbles in lava) of a volcanic rock or other extrusive igneous rock are infilled with a secondary mineral, such as calcite, quartz, chlorite, or one of the zeolite Zeolites are mi ...
s in
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
ic rocks. Chabazite is found in
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, the
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in
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, along the
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in
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, and
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.


Synthetic chabazite

Many different materials that are
isostructural Isostructural chemical compounds have similar chemical structures. "Isomorphous" when used in the relation to crystal structures is not synonymous: in addition to the same atomic connectivity that characterises isostructural compounds, isomorphous s ...
with the chabazite mineral have been synthesized in laboratories.
SSZ-13 SSZ-13 (framework type code CHA) is a high-silica aluminosilicate zeolite possessing 0.38 × 0.38 nm micropores.Baerlocher, Ch.; McCusker, L.B..; Olson, D.H. Atlas of Zeolite framework Types, Elsevier, Amsterdam, 6th edn., 2007, see also: http ...
is a CHA type zeolite with an Si/Al ratio of 14. This is a composition not found in nature.


References


External links


Webmineralstructure type CHA
Tectosilicates Calcium minerals Sodium minerals Potassium minerals Magnesium minerals Aluminium minerals Zeolites Trigonal minerals Minerals in space group 166 {{silicate-mineral-stub