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Panizos is a
Late Miocene The Late Miocene (also known as Upper Miocene) is a sub-epoch of the Miocene epoch (geology), Epoch made up of two faunal stage, stages. The Tortonian and Messinian stages comprise the Late Miocene sub-epoch, which lasted from 11.63 Ma (million ye ...
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
in the
Potosí Department Potosí (; Aymara language, Aymara: ''Putusi''; qu, P'utuqsi) is a Departments of Bolivia, department in southwestern Bolivia. It comprises 118,218 km2 with 823,517 inhabitants (2012 census). The capital is the city of Potosí. It is most ...
of
Bolivia , image_flag = Bandera de Bolivia (Estado).svg , flag_alt = Horizontal tricolor (red, yellow, and green from top to bottom) with the coat of arms of Bolivia in the center , flag_alt2 = 7 × 7 square p ...
and the
Jujuy Province Jujuy is a province of Argentina, located in the extreme northwest of the country, at the borders with Chile and Bolivia. The only neighboring Argentine province is Salta to the east and south. Geography There are three main areas in Jujuy: * ...
of
Argentina Argentina (), officially the Argentine Republic ( es, link=no, República Argentina), is a country in the southern half of South America. Argentina covers an area of , making it the second-largest country in South America after Brazil, th ...
. It is part of the Altiplano-Puna volcanic complex of the
Central Volcanic Zone The Andean Volcanic Belt is a major volcanic belt along the Andean cordillera in Argentina, Bolivia, Chile, Colombia, Ecuador, and Peru. It is formed as a result of subduction of the Nazca Plate and Antarctic Plate underneath the South Americ ...
in the
Andes The Andes, Andes Mountains or Andean Mountains (; ) are the longest continental mountain range in the world, forming a continuous highland along the western edge of South America. The range is long, wide (widest between 18°S – 20°S ...
. 50 volcanoes active in recent times are found in the Central Volcanic Zone, and several major caldera complexes are situated in the area. The caldera is located in a difficult-to-access part of the Andes. Panizos and the majority of these volcanoes are formed by the
subduction Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
of the oceanic
Nazca Plate The Nazca Plate or Nasca Plate, named after the Nazca region of southern Peru, is an oceanic tectonic plate in the eastern Pacific Ocean basin off the west coast of South America. The ongoing subduction, along the Peru–Chile Trench, of the Na ...
under the continental South American continental lithosphere. The caldera is located east of the main arc and is supplied chiefly by
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...
magmas. Beneath Panizos lie
Tertiary Tertiary ( ) is a widely used but obsolete term for the geologic period from 66 million to 2.6 million years ago. The period began with the demise of the non-avian dinosaurs in the Cretaceous–Paleogene extinction event, at the start ...
ignimbrites and a
Paleozoic The Paleozoic (or Palaeozoic) Era is the earliest of three geologic eras of the Phanerozoic Eon. The name ''Paleozoic'' ( ;) was coined by the British geologist Adam Sedgwick in 1838 by combining the Greek words ''palaiós'' (, "old") and ' ...
sedimentary basement. The huge Panizos ignimbrite erupted by Cerro Panizos has a minimum volume of . It erupted during an event 6.71 ± 0.04 mya and was preceded by another ignimbrite 7.9 mya ago. The last activity is a lava flow 6.1 mya ago. The caldera is hidden beneath a shield with a diameter of and some of its central summits are over high. It has been referred to as an "ignimbrite shield".


Geography and structure

The centre is located on the border between Argentina and Bolivia. It is a shield constructed from
ignimbrite Ignimbrite is a type of volcanic rock, consisting of hardened tuff. Ignimbrites form from the deposits of pyroclastic flows, which are a hot suspension of particles and gases flowing rapidly from a volcano, driven by being denser than the surrou ...
s. Research in this region of the Andes is made difficult by physical and logistics issues. Cerro Guacha and
La Pacana La Pacana is a Miocene age caldera in northern Chile's Antofagasta Region. Part of the Central Volcanic Zone of the Andes, it is part of the Altiplano–Puna volcanic complex, Altiplano-Puna volcanic complex, a major caldera and silicic ignimbri ...
are among the few systems that were the subject of research. The Panizos ignimbrite is well exposed with little modification. Cerro Panizos is part of the Central Volcanic Zone (CVZ) of the Andes, a belt of recent volcanism that runs from southern Peru into Chile and Argentina. 50 volcanoes in the belt have been identified as active in recent times. A major ignimbrite province called the Altiplano-Puna volcanic complex is associated with the area between 21° and 24° degrees southern latitude since 23 million years ago. Cerro Guacha, La Pacana and
Pastos Grandes Pastos Grandes is the name of a caldera and its crater lake in Bolivia. The caldera is part of the Altiplano-Puna volcanic complex, a large ignimbrite province that is part of the Central Volcanic Zone of the Andes. Pastos Grandes has erupted a ...
are calderas within this province which covers a surface of , with geothermal manifestations in
El Tatio El Tatio is a geothermal field with many geysers located in the Andes Mountains of northern Chile at above mean sea level. It is the third-largest geyser field in the world and the largest in the Southern Hemisphere. Various meanings have bee ...
and Sol de Manana being the latest manifestations of volcanism in the area. A group of lava domes with a diameter of of
dacitic Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite ...
composition forms the centre of the complex, with the domes having formed either during one single eruption or several. These domes form a ring structure with thin lava cover in its centre, which may be the rim of a collapse caldera formed in the later stages of the main Panizos eruption and filled by later eruption stages, as suggested by the outward dip of the lower unit of the Panizos Ignimbrite. This caldera has a diameter of . The centre is surrounded a shield with a diameter of . It is constructed from ignimbrites with a slope of 1–3°. Three lava platforms with the names Cerro Chinchinjaran, Cerro Tucunquis and Cerro Anta Quevas are present. The first and the last are part of a dacitic flowfield that includes a long lava flow on its northern sector with some resemblance to
pahoehoe Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or und ...
lava. A pre-caldera lava structure in the south of the complex is known as Cerro Limitayoc, but it erupted lavas even after the Panizos ignimbrite was erupted. A depression is located just south of the lava dome group and may be a downsag caldera, likewise infilled by activity. The Panizos complex covers an area of and has a total volume of . The structure of the Panizos complex has been called an "ignimbrite shield". The central summits Limitayoc, Panizos, La Ramada and Vicuñahuasi are over high.


Geology

The volcanism in the area is triggered by the subduction of the
Nazca plate The Nazca Plate or Nasca Plate, named after the Nazca region of southern Peru, is an oceanic tectonic plate in the eastern Pacific Ocean basin off the west coast of South America. The ongoing subduction, along the Peru–Chile Trench, of the Na ...
beneath the South America plate; magmas formed from the subduction process trigger the melting of the crust. The large calderas are located east of the main
volcanic arc A volcanic arc (also known as a magmatic arc) is a belt of volcanoes formed above a subducting oceanic tectonic plate, with the belt arranged in an arc shape as seen from above. Volcanic arcs typically parallel an oceanic trench, with the arc lo ...
of the Central Volcanic Zone, Panizos being east of the main arc. Volcanism in the area is heavily dominated by calderic silicic volcanics with volumes of contrasting to less than andesites. The volcano is part of the so-called ''
Tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
belt'', a territory in the Andes where large tin mineral deposits are found in granitic and extrusive rocks, formed from sulfidation reactions involving the numerous volcanoes in the area. Magmas in the territory are derived from crystal fractionation and were heavily modified by interactions with the crust that reaches a thickness of beneath the Central Volcanic Zone. Research by S. L. de Silva indicates that before 10 mya volcanic activity already existed north of 20°30' in form of the Oxaya and Altos de Pica ignimbrites. Changes in the subduction activity 12-10 mya caused a shortening and thickening of the crust in the central Andes and the formation of melt zones in the deeper crust, associated with the Quechua phase of Andean orogeny. Since 10.6 mya these rose to the surface, forming magma chambers and calderas. The eruptions of the Panizos ignimbrites coincide with major pulses in APVC activity.


Local

The basement beneath Panizos is formed from two formations, Acoite and Peña Colorada. The former is a
sedimentary Sedimentary rocks are types of rock (geology), rock that are formed by the accumulation or deposition of mineral or organic matter, organic particles at Earth#Surface, Earth's surface, followed by cementation (geology), cementation. Sedimentati ...
layer, formed during arc development in the Paleozoic. The latter is
Tertiary Tertiary ( ) is a widely used but obsolete term for the geologic period from 66 million to 2.6 million years ago. The period began with the demise of the non-avian dinosaurs in the Cretaceous–Paleogene extinction event, at the start ...
volcanic in origin, containing
breccia Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix. The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of di ...
, debris flow material, ignimbrites,
lava flow Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or und ...
s and
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...
. The basement dips westward. Based on
neodymium Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes i ...
isotope ratios, some of the basement rocks are about one billion years old. The volcano is part of a group with other volcanoes of the Lipez region. In this region, arc and back-arc volcanism occur in the same area and have generated some of the largest calderas in the world. These include Cerro Guacha, Pastos Grandes and Vilama. A meridional lineament of volcanoes including Limitayoc and Salle extends from the southern and western margin of the central lava domes to Cerro Pululu in the south. Another lineament may form the eastern rim of the lava dome complex. Other centres in the south are the Rose, Salle and West Zapaleri ignimbrites as well as the dacites of Cerro Bayo, all erupted 8.9–5.1 mya from the Vilama caldera. Cerro Panizos is associated with a large-scale topographic anomaly, similar to many other volcanic centres in the region.


Geologic record

According to Turner (1978), the ignimbrites are part of the Lipiyoc formation and the lava dome structures of the Vicuñahuasi formation. The Panizos eruption products display strong local variations, with features at different depths and different distances from the central dome complex being very dissimilar. The Cerro Corutu centre southwest of Panizos was active in the Miocene, forming an ignimbrite layer, whose exposure in the Quebrada Queñoal valley is thick. It contains
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...
,
orthopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
,
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
and smaller amounts of
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
. Another tuff is found in Quebrada Cusi Cusi. Above these lies an eastward sloping layer of volcaniclastic material. The area covered by the Panizos products had been subject to earlier eruptive activity from unknown centres between 15.4–13.4 mya, generating tuffs recognized in the
San Pablo de Lípez San Pablo de Lípez is a small town in the Potosí Department of Bolivia. It is the seat of the Sur Lípez Province and of the San Pablo de Lípez Municipality. See also * Kuntur Wasi (Bolivia), Kuntur Wasi * Q'illu Salli * Yana Urqu (Sud Líp ...
region as outcrops. Changes in the subduction geometry since the late Miocene have caused volcanism to diminish from east to west, including cessation of activity at the Panizos centre. Uturuncu volcano was last active 271,000 years ago and the Cerro Chascon-Runtu Jarita complex 85,000 years ago.


Composition

With the exception of some
andesitic Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomina ...
products, mostly lava flows, dacite is the main component of Panizos eruptive products. The rock matrix and
clast Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus,Essentials of Geology, 3rd Ed, Stephen Marshak, p. G-3 chunks, and smaller grains of rock broken off other rocks ...
s in the rock have similar minerals. Plagioclase is the main component of the lower cooling unit. Vesicles are rare in the Panizos ignimbrite, forming no more than 25%. Calling it "densely welded" is difficult at percentages of more than 10%. Pumice is also found, chemically it contains biotite, plagioclase, quartz and some orthopyroxene. In the lower units,
tonalite Tonalite is an igneous, plutonic ( intrusive) rock, of felsic composition, with phaneritic (coarse-grained) texture. Feldspar is present as plagioclase (typically oligoclase or andesine) with alkali feldspar making up less than 10% of the total ...
and
ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
are also found. The Cienago and Cusi Cusi ignimbrites both contain biotite, quartz, plagioclase and Cusi Cusi also
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system ...
. The ignimbrites of Panizos are alumina- and
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
-rich and contain 61–66% SiO2. The Cienago ignimbrite has by one study the largest amount of SiO2 of all magmas of Panizos, whereas another indicates that the Cusi Cusi ignimbrite has the highest with 69%. The Cienago ignimbrites would have 63–65% and the Panizos ones 61–66%.
Isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
analysis indicates high / ratios and high / and / ratios. These are associated with arc volcanism, unlike the much lower ratios found at Galan which are typical for intraplate volcanism. Along with the neodymium isotope ratios this suggests that Panizos magmas have a strong crustal component.
Lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
isotope ratios are comparable with these of Galan and La Pacana and are linked to the domain of the crust they are constructed on. There are some compositional variations in various stages of volcanism at Cerro Panizos. The Cienago ignimbrite is a highly evolved magma. Magmas from the Panizos ignimbrite display only weak variations that may be linked to temperature differences in the magma chamber. The magmas of the Panizos ignimbrite underwent strong crystallization between eruptions and crystals are often heavily modified. The formation of all magmas was initiated by the interaction of
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...
mantle melts with the crust. The mantle component is up to 50% of the main Panizos ignimbrite. A notable feature of Cerro Panizos is the presence of so-called orbs, which are rocks with concentric layers of igneous material surrounding them. They are known from
plutonic Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form '' intrusions'', such as batholiths, dikes, sills, laccoliths, and volcanic necks.Intrusive RocksIntrusive rocks accessdate: March ...
rocks, but orbs in erupted magmas are only known from Akagi volcano,
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
. In Panizos they are found in the upper part of the lower cooling unit of the Cerro Panizos ignimbrite and are associated with pumice and
megacryst In geology, a megacryst is a crystal or grain that is considerably larger than the encircling matrix. They are found in igneous and metamorphic rocks. Megacrysts can be further classified based on the nature of their origin, either as:Chapman, Carle ...
s in the surrounding rock. Buried within the ignimbrites and lavas, some orbs contain layers of biotite,
bronzite Bronzite is a member of the pyroxene group of minerals, belonging with enstatite and hypersthene to the orthorhombic series of the group. Rather than a distinct species, it is really a ferriferous variety of enstatite, which owing to partial alt ...
, ilmenite and plagioclase around a centimetre-sized xenolith or orthopyroxene core. The layering is not disturbed by irregular shapes of the cores. These orbs most likely formed from material crystallizing around pre-existent cores during rapid changes in magma temperature that occurred shortly before the end of the first phase of the Cerro Panizos eruption through changes in magma water content. Opening of ring vents then delivered the orb-containing magma to the surface.


Climate and hydrography

Panizos has an arid climate, although some stream erosion is visible. Some stream valleys are known, clockwise from northeast, as Quebrada Buenos Aires, Quebrada Cienago, Quebrada Paicone Quebrada Pupusayo, Quebrada Cusi Cusi, Quebrada Cuevas and Quebrada Garcia. The dissection is particularly pronounced on the Argentine side of the complex.
Oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
isotopic analysis of magmas from other APVC centres support the notion that the area of the APVC has been subject to arid climate for the duration of its active phase.


Eruptive history

Two ignimbrite eruptions have taken place in Panizos. A number of lava flows also formed. Volcanic activity took place in the Late Miocene. The main Cerro Panizos ignimbrite lies on top three older ignimbrite layers. Potassium-argon dating has yielded ages of 9.7 ± 0.4, 8.49 ± 0.2 and 9.4 mya. Dates often differ between newly established and old established dates, presumably due to xenolith contamination. The Cusi Cusi tuff is 12.4 mya old or more than 10 million years old and has been associated with the Panizos centre. The first recorded ignimbrite in the area is named Quebrada Cienago ignimbrite after the valley where it is exposed. It contains biotite quartz dacite and is formed from four units, two ashfall deposits and two ignimbrite flows. Some of these have undergone reworking. It was emplaced 7.9 mya. After the emplacement of the Cienago ignimbrite, eruption of dacite lava flows continued. Erupted 6.71 ± 0.04 mya, the Panizos ignimbrite proper is a complex structure with several cooling units and an interlayered pyroclastic deposit, which contains pumice, sandstone boulders up to two metres thick and has carved channels into the lower unit. At the edge of the plateau the upper and lower cooling units are and thick. In the plateau centre, the lower unit is completely hidden beneath the now more than thick upper unit. The lower unit begins with one metre of lapilli and above it thick ignimbrite layers that become increasingly non-welded farther up with vapour phase components appearing. There was no prior Plinian fallout. Orbs and two differently coloured pumices are located in the upper section of the lower unit, with some xenoliths. The upper cooling unit contains two types of pumice, one strongly welded and the other weakly so, and is much richer in lithic fragments. The upper unit was erupted in several discrete flows from the central complex. Some pumice fall layers are embedded in the upper unit. Based on the structure, the main Panizos ignimbrite was probably erupted in a steady eruption at first, from either one vent or several smaller ones in close association. Either a column collapse or a change in vent geometries triggered a temporary pause which separates the upper and lower cooling units. After a short timespan, the eruption restarted, this time through several eruption flows and a more unsteady regimen with a lower flow rate. Based on welding patterns, the eruption commenced in the southern sector later covered by lava domes and migrated northward. Calculations indicate that the main Panizos ignimbrite has minimum volumina of outside of the calderas and
dense rock equivalent Dense-rock equivalent (DRE) is a volcanologic calculation used to estimate volcanic eruption volume. One of the widely accepted measures of the size of a historic or prehistoric eruption is the volume of magma ejected as pumice and volcanic ash, k ...
. This ignimbrite flow was of comparatively low fluidity, likely due to its high crystal content. The amount of vesicles present in the lower cooling unit is inferior to 20% of volume. Above the Panizos ignimbrite, a lava flow platform and a set of lava domes were emplaced. A last manifestation is the Cerro La Ramada lava flow, with an age of 6.1 mya. A tephra layer found in the Coastal Cordillera and dated 6.66 ± 0.13 mya may also be linked to the Panizos complex. The much younger (1.9±0.2–1.7±0.5 mya) Laguna Colorada ignimbrite is sometimes called Panizos, generating confusion.


See also

*
Aguas Calientes caldera Aguas Calientes is a major Miocene caldera in Salta Province, Argentina. It is in the Central Volcanic Zone of the Andes, a zone of volcanism covering southern Peru, Bolivia, northwest Argentina and northern Chile. This zone contains stratovo ...


References


Additional sources

* {{DEFAULTSORT:Panizos, Cerro Calderas of Bolivia Andean Volcanic Belt Calderas of Argentina Subduction volcanoes Supervolcanoes Miocene calderas
Cerro Panizos Panizos is a Late Miocene caldera in the Potosí Department of Bolivia and the Jujuy Province of Argentina. It is part of the Altiplano-Puna volcanic complex of the Central Volcanic Zone in the Andes. 50 volcanoes active in recent times are found ...