Central Valley Groundwater Pollution
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Contaminated groundwater Groundwater pollution (also called groundwater contamination) occurs when pollutants are released to the ground and make their way into groundwater. This type of water pollution can also occur naturally due to the presence of a minor and unwanted ...
in the Central Valley of
California California is a U.S. state, state in the Western United States, located along the West Coast of the United States, Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the List of states and territori ...
is a growing problem due to contamination and overuse. This problem is compounded by the
overdrafting Overdrafting is the process of extracting groundwater beyond the equilibrium yield of an aquifer. Groundwater is one of the largest sources of fresh water and is found underground. Groundwater depletion is comparable to a bank account in which mor ...
of underground
aquifer An aquifer is an underground layer of water-bearing, permeable rock, rock fractures, or unconsolidated materials (gravel, sand, or silt). Groundwater from aquifers can be extracted using a water well. Aquifers vary greatly in their characterist ...
s. Currently,
nitrates Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble ...
are the most abundant pollutants in the Central Valley due to the copious amounts of agricultural runoff from the farms. The concentration of naturally occurring
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
is also an issue. This is a public health concern as groundwater is often the primary water source in the region. Near-term solutions to reduce pollution and overuse are often costly and hard to implement in a timely manner.


Background

At the heart of this industry lies the Central Valley, a vital agricultural hub for the state and country. Consisting of both the
San Joaquin Valley The San Joaquin Valley ( ; es, Valle de San Joaquín) is the area of the Central Valley of the U.S. state of California that lies south of the Sacramento–San Joaquin River Delta and is drained by the San Joaquin River. It comprises seven c ...
and
Sacramento Valley , photo =Sacramento Riverfront.jpg , photo_caption= Sacramento , map_image=Map california central valley.jpg , map_caption= The Central Valley of California , location = California, United States , coordinates = , boundaries = Sierra Nevada (ea ...
, the Central Valley has an estimated two-thirds of the state's cropland with 7 million acres. California is also the leading dairy producer in the country, with 1.8 million mature cows in the Central Valley contributing to 80% of California's dairies. Water quantity and quality have been a leading concern in this crucial high-output agricultural region that often suffers from
drought A drought is defined as drier than normal conditions.Douville, H., K. Raghavan, J. Renwick, R.P. Allan, P.A. Arias, M. Barlow, R. Cerezo-Mota, A. Cherchi, T.Y. Gan, J. Gergis, D.  Jiang, A.  Khan, W.  Pokam Mba, D.  Rosenfeld, J. Tierney, an ...
.


History

Groundwater has been pumped in the valley since 1850, when residents began to build pumps to help make up for the lack of surface water in the area. At the turn of the 20th century, California became as a leading agricultural producer due to its technological advances in
land management Land management is the process of managing the use and development (in both urban and rural settings, but it is mostly managed in Urban places.) of land resources. Land resources are used for a variety of purposes which may include organic agricul ...
,
irrigation Irrigation (also referred to as watering) is the practice of applying controlled amounts of water to land to help grow Crop, crops, Landscape plant, landscape plants, and Lawn, lawns. Irrigation has been a key aspect of agriculture for over 5,00 ...
and machinery. The Central Valley had ideal economic and climate conditions for many crops and drew in wealthy landowners. Aquifers are critical because groundwater supplies much of the water needed for agricultural purposes and serves as the only source of water for several communities throughout the valley. However, reciprocal rainfall is not always available to recharge the aquifers, and recent years have seen an increase in drying wells. This overdraft of groundwater causes numerous problems for farmers and is only made worse by
climate change In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
. Throughout the early 1900s, technology for
waste management Waste management or waste disposal includes the processes and actions required to manage waste from its inception to its final disposal. This includes the collection, transport, treatment and disposal of waste, together with monitoring ...
did not advance at the same speed as the growth in
agriculture Agriculture or farming is the practice of cultivating plants and livestock. Agriculture was the key development in the rise of sedentary human civilization, whereby farming of domesticated species created food surpluses that enabled people to ...
. Issues in groundwater contamination by nitrates come from 50 years of unregulated management of livestock waste disposal, septic systems and commercial fertilizers. The California
Sustainable Groundwater Management Act The Sustainable Groundwater Management Act (SGMA) is a three-bill package that passed the California state legislature and was signed into California state law by Governor Jerry Brown in September 2014. Its purpose is to ensure better local and re ...
of 2014 was the first to specify how to manage groundwater in a way that would not harm or endanger future access to clean groundwater. Before this act, no regulations governed groundwater management other than the federal
Safe Drinking Water Act The Safe Drinking Water Act (SDWA) is the principal federal law in the United States intended to ensure safe drinking water for the public. Pursuant to the act, the Environmental Protection Agency (EPA) is required to set standards for drinking w ...
and
Clean Water Act The Clean Water Act (CWA) is the primary federal law in the United States governing water pollution. Its objective is to restore and maintain the chemical, physical, and biological integrity of the nation's waters; recognizing the responsibiliti ...
. These acts do not totally protect Central Valley residents. Consistent monitoring didn't begin until the 1950s, with only 13,000 tests completed in the 1980s compared to the over 133,329 tests in the Central Valley region conducted by the California Spatio Temporal Information on Nitrate in Groundwater (CASTING) database. With advances in testing and research, organizations and residents of the Central Valley have increased efforts to reduce the impact of nitrate water pollution, expected to drastically increase in the next couple decades.


Regulations and standards

Set by the
California Department of Public Health The California Department of Public Health (CDPH) is the state department responsible for public health in California. It is a subdivision of the California Health and Human Services Agency. It enforces some of the laws in the California Healt ...
, the maximum contaminant level for nitrates, in CCR §63341, is 45 milligrams per liter (mg/L) for nitrate as NO3 (equivalent to 10 mg/L for nitrate as nitrogen or “N”); 10 mg/L for nitrate plus nitrite as N; and 1 mg/L for nitrite as N. Public wells are required to test their water annually and submit the results to the Department of Health, but private wells are not required to do so. A documented 98% of the state has access to drinkable water, though some studies note that access disparities exist. Despite modern data and methods for agricultural safety, 92 water systems in the Central Valley were attached to wells containing illegal levels of nitrates between 2005 and 2008, impacting the 1,335,000 residents in the area. Historically, programs to identify and address the impact nitrates have on communities and industries have run at around $1 million each. The Californian
Sustainable Groundwater Management Act The Sustainable Groundwater Management Act (SGMA) is a three-bill package that passed the California state legislature and was signed into California state law by Governor Jerry Brown in September 2014. Its purpose is to ensure better local and re ...
of 2014 was the first of its kind to specify how to manage groundwater in a way that would not harm or endanger future generations' access to clean groundwater. Signed by Gov.
Jerry Brown Edmund Gerald Brown Jr. (born April 7, 1938) is an American lawyer, author, and politician who served as the 34th and 39th governor of California from 1975 to 1983 and 2011 to 2019. A member of the Democratic Party, he was elected Secretary of S ...
in 2014, this three-bill legislative package created a framework for preserving and managing groundwater at the local and state level. This creates a regulatory process mandating that Groundwater Sustainability Agencies (GSAs) to adopt Ground Water Sustainability Plans (GSPs) to manage supply. Before this act, regulations existed only at the federal level with the
Safe Drinking Water Act The Safe Drinking Water Act (SDWA) is the principal federal law in the United States intended to ensure safe drinking water for the public. Pursuant to the act, the Environmental Protection Agency (EPA) is required to set standards for drinking w ...
and the
Clean Water Act The Clean Water Act (CWA) is the primary federal law in the United States governing water pollution. Its objective is to restore and maintain the chemical, physical, and biological integrity of the nation's waters; recognizing the responsibiliti ...
, which failed to protect Central Valley residents. Based on these laws, farms and oil drilling sites could not dump waste into the ground if it impacted clean drinking water; however, if the water was not suitable to drink, consumers and businesses could dump waste freely into the water, limiting access to drinking water by further contaminating sources already deemed undrinkable.


Sources of nitrogen

Manure,
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
, and septic waste are the leading sources of
nitrates Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble ...
in groundwater. Manure produces around 6.5 million tons of nitrogen, which, when not handled properly or with improper drainage methods, can contaminate soil and water sources. Nitrogen-based soil compounds produced by crops such as legumes, are consistently a minimal source. Fertilizers add roughly 11.5 million tons of nitrogen annually in the United States. Nitrogen in fertilizers is converted to nitrates, which is the main form of nitrogen in wastewater. Nitrogen from fertilizers can also be released into the atmosphere as
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
gas, commonly recognized as a
greenhouse gas A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse ...
. In the U.S. 53% of nitrates originate from fertilizers, making this a priority for Californian officials.


Population impact

Several studies have investigated the impact of nitrogen-based wastes such as
nitrate Nitrate is a polyatomic ion A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zer ...
s on human health. Some studies suggest that exposure to such wastes is correlated to an increased risk of cancer. The exposure period is a determining factor in increased risk consistent through all of the studies. In cases where the incidence of cancer was found to be significantly higher, the exposure period was at least five and in some cases ten years. Women who consume water with nitrates over 5 mg/L are at a higher risk of
thyroid cancer Thyroid cancer is cancer that develops from the tissues of the thyroid gland. It is a disease in which cells grow abnormally and have the potential to spread to other parts of the body. Symptoms can include swelling or a lump in the neck. C ...
. This 5 mg/L level is 5 mg below the federally accepted limit. When consumed, nitrate competes with
iodine Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , and boils to a vi ...
in the body to be taken up by the
thyroid The thyroid, or thyroid gland, is an endocrine gland in vertebrates. In humans it is in the neck and consists of two connected lobes. The lower two thirds of the lobes are connected by a thin band of tissue called the thyroid isthmus. The thy ...
. When the thyroid takes up nitrogen instead of iodine, the thyroid begins to lose function. Only five years of this exposure significantly increases the risk of thyroid cancer. A higher risk of colon and
rectal The rectum is the final straight portion of the large intestine in humans and some other mammals, and the gut in others. The adult human rectum is about long, and begins at the rectosigmoid junction (the end of the sigmoid colon) at the le ...
cancer also accompanies water consumption with nitrate levels above 5 mg/L. Exposure for 10+ years is associated with increased colon cancer risk in susceptible populations. Populations affected may also lack access to fresh fruits and vegetables, and a lack of vitamin C is a major risk factor for colorectal cancers. Drinking water and consuming dietary sources of nitrates/nitrites are speculated to cause increased cancer risks when the nitrate compounds react with amines and amides to form carcinogens. The exact process of how this happens is still being researched.


References

{{Reflist Central Valley (California) Water in California Environmental issues in California