Calcium silicate is the

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

Ca₂SiO₄, also known as calcium

orthosilicate In chemistry, orthosilicate is the anion , or any of its salts and esters. It is one of the silicate anions. It is occasionally called the silicon tetroxide anion or group.C. A. Kumins, and A. E. Gessler (1953), "Short-Cycle Syntheses of Ultrama ...

and is sometimes formulated as 2CaO·SiO₂. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite.

Properties

Calcium silicate is a white free-flowing powder. It can be derived from naturally occurring

limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...

and

diatomaceous earth Diatomaceous earth (), diatomite (), or kieselgur/kieselguhr is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 μm to le ...

, a siliceous sedimentary rock. It is one of a group of compounds that can be produced by reacting

calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, Caustic (substance), caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime (material), lime''" co ...

and

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

in various ratios e.g. 3CaO·SiO₂, alite (Ca₃SiO₅); 2CaO·SiO₂, (Ca₂SiO₄); 3CaO·2SiO₂, (Ca₃SiO₇); and CaO·SiO₂, wollastonite (CaSiO₃). It has a low

bulk density Bulk density, also called apparent density or volumetric density, is a property of powders, granules, and other "divided" solids, especially used in reference to mineral components (soil, gravel), chemical substances, (pharmaceutical) ingredients ...

and high physical

water absorption The absorption of electromagnetic radiation by water depends on the state of the water. The absorption in the gas phase occurs in three regions of the spectrum. Rotational transitions are responsible for absorption in the microwave and far-inf ...

Use

Calcium silicate is used as an

anticaking agent An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption. Caking mechanisms d ...

in food preparation, including table salt
and as an antacid. It is approved by the United Nations' FAO and WHO bodies as a safe

food additive Food additives are substances added to food to preserve flavor or enhance taste, appearance, or other sensory qualities. Some additives have been used for centuries as part of an effort to preserve food, for example vinegar (pickling), salt (salt ...

in a large variety of products. It has the

E number E numbers ("E" stands for "Europe") are codes for substances used as food additives, including those found naturally in many foods such as vitamin C, for use within the European Union (EU) and European Free Trade Association (EFTA). Commonly ...

reference E552.

High-temperature insulation

Calcium silicate is commonly used as a safe alternative to

asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...

for high-temperature insulation materials. Industrial-grade piping and equipment insulation is often fabricated from calcium silicate. Its fabrication is a routine part of the curriculum for insulation

apprentice Apprenticeship is a system for training a new generation of practitioners of a trade or profession with on-the-job training and often some accompanying study (classroom work and reading). Apprenticeships can also enable practitioners to gain a ...

s. Calcium silicate competes in these realms against

rockwool Mineral wool is any fibrous material formed by spinning or drawing molten mineral or rock materials such as slag and ceramics. Applications of mineral wool include thermal insulation (as both structural insulation and pipe insulation), f ...

and proprietary

insulation Insulation may refer to: Thermal * Thermal insulation, use of materials to reduce rates of heat transfer ** List of insulation materials ** Building insulation, thermal insulation added to buildings for comfort and energy efficiency *** Insulated ...

solids, such as perlite mixture and

vermiculite Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently, and commercial furnaces can routinely produce this effect. Vermiculite forms by the wea ...

bonded with

sodium silicate Sodium silicate is a generic name for chemical compounds with the formula or ·, such as sodium metasilicate , sodium orthosilicate , and sodium pyrosilicate . The anions are often polymeric. These compounds are generally colorless transparent ...

. Although it is popularly considered an asbestos substitute, early uses of calcium silicate for insulation still made use of asbestos fibers.

Passive fire protection

It is used in

passive fire protection Passive fire protection (PFP) is components or systems of a building or structure that slows or impedes the spread of the effects of fire or smoke without system activation, and usually without movement. Examples of passive systems include floor- ...

and

fireproofing Fireproofing is rendering something (structures, materials, etc.) resistant to fire, or incombustible; or material for use in making anything fire-proof. It is a passive fire protection measure. "Fireproof" or "fireproofing" can be used as a n ...

calcium silicate brick A brick is a type of block used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a block composed of dried clay, but is now also used informally to denote other chemically cured cons ...

or in roof tiles. It is one of the most successful materials in

Europe Europe is a large peninsula conventionally considered a continent in its own right because of its great physical size and the weight of its history and traditions. Europe is also considered a Continent#Subcontinents, subcontinent of Eurasia ...

because of regulations and fire safety guidelines for commercial and residential building codes. Where

North America North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the Car ...

ns use spray fireproofing

plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for Molding (decorative), moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of ...

s, Europeans are more likely to use cladding made of calcium silicate. High-performance calcium-silicate boards retain their excellent dimensional stability even in damp and humid conditions and can be installed at an early stage in the construction program, before wet trades are completed and the building is weather-tight. For sub-standard products,

silicone A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking ...

-treated sheets are available to fabricators to mitigate potential harm from high

humidity Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present. Humidity depe ...

or general presence of

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...

. Fabricators and installers of calcium silicate in

often also install firestops. While the best possible reaction to fire classifications are A1 (construction applications) and A1Fl (flooring applications) respectively, both of which mean "non-combustible" according to EN 13501-1: 2007, as classified by a notified laboratory in Europe, some calcium-silicate boards only come with fire classification of A2 (limited combustibility) or even lower classifications (or no classification), if they are tested at all.

Acid mine drainage remediation

Calcium silicate, also known as

slag Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...

, is produced when molten

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

is made from

iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the fo ...

silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

and calcium carbonate in a

blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...

. When this material is processed into a highly refined, re-purposed calcium silicate aggregate, it is used in the remediation of acid mine drainage (AMD) on active and passive mine sites. Calcium silicate neutralizes active acidity in AMD systems by removing free hydrogen ions from the bulk solution, thereby increasing pH. As its silicate anion captures H⁺ ions (raising the pH), it forms monosilicic acid (H₄SiO₄), a neutral solute. Monosilicic acid remains in the bulk solution to play other important roles in correcting the adverse effects of acidic conditions. As opposed to limestone (a popular remediation material), calcium silicate effectively precipitates heavy metals and does not armor over, prolonging its effectiveness in AMD systems.

As a product of sealants

It is used as a sealant in roads or on the shells of fresh eggs: when

is applied as a sealant to cured

concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...

or egg shells, it chemically reacts with

calcium hydroxide Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed or slaked with water. It has m ...

or calcium carbonate to form calcium silicate hydrate, sealing micropores with a relatively impermeable material.

As a component of cement

It also occurs in cements, where it is known as

belite Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in ...

or in cement chemist notation C₂S.

Agriculture

Calcium silicate is often used in agriculture as a plant available source of silicon. It is "applied extensively to Everglades mucks and associated sands planted to sugarcane and rice"

References

{{DEFAULTSORT:Calcium Silicate Inorganic silicon compounds Calcium compounds Antacids Silicates E-number additives