Bunsen Burner
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A Bunsen burner, named after
Robert Bunsen Robert Wilhelm Eberhard Bunsen (; 30 March 1811 – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
, is a kind of ambient air
gas burner A gas burner is a device that produces a controlled flame by mixing a fuel gas such as acetylene, natural gas, or propane with an oxidizer such as the ambient air or supplied oxygen, and allowing for ignition and combustion. The flame is ge ...
used as
laboratory equipment A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratory services are provided in a variety of settings: physicia ...
; it produces a single open gas
flame A flame (from Latin '' flamma'') is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density they ...
, and is used for heating, sterilization, and combustion. The gas can be
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
(which is mainly
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Ea ...
) or a liquefied petroleum gas, such as propane, butane, or a mixture. Combustion temperature achieved depends in part on the
adiabatic flame temperature In the study of combustion, the adiabatic flame temperature is the temperature reached by a flame under ideal conditions. It is an upper bound of the temperature that is reached in actual processes. There are two types adiabatic flame temperature: ...
of the chosen fuel mixture.


History

In 1852, the
University of Heidelberg } Heidelberg University, officially the Ruprecht Karl University of Heidelberg, (german: Ruprecht-Karls-Universität Heidelberg; la, Universitas Ruperto Carola Heidelbergensis) is a public research university in Heidelberg, Baden-Württemberg, ...
hired Bunsen and promised him a new laboratory building. The city of Heidelberg had begun to install
coal-gas Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous ...
street lighting, and so the university laid gas lines to the new laboratory. The designers of the building intended to use the gas not just for illumination, but also in burners for laboratory operations. For any burner lamp, it was desirable to maximize the temperature and minimize luminosity. However, existing laboratory burner lamps left much to be desired not just in terms of the heat of the flame, but also regarding economy and simplicity. While the building was still under construction in late 1854, Bunsen suggested certain design principles to the university's mechanic,
Peter Desaga Peter Desaga was a German instrument maker at the University of Heidelberg who worked with Robert Bunsen. In 1855, Desaga perfected an earlier design of the laboratory burner by Michael Faraday into the Bunsen burner. Neither Desaga nor Bunsen ...
, and asked him to construct a prototype. Similar principles had been used in an earlier burner design by
Michael Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inducti ...
, as well as in a device patented in 1856 by the gas engineer R. W. Elsner. The Bunsen/Desaga design succeeded in generating a hot, sootless, non-luminous flame by mixing the gas with air in a controlled fashion before combustion. Desaga created adjustable slits for air at the bottom of the cylindrical burner, with the flame igniting at the top. By the time the building opened early in 1855, Desaga had made 50 burners for Bunsen's students. Two years later Bunsen published a description, and many of his colleagues soon adopted the design. Bunsen burners are now used in laboratories all around the world.


Operation

The device in use today safely burns a continuous stream of a flammable
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
such as
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
(which is principally
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Ea ...
) or a liquefied petroleum gas such as propane, butane, or a mixture of both. The hose barb is connected to a gas nozzle on the laboratory bench with rubber tubing. Most laboratory benches are equipped with multiple gas nozzles connected to a central gas source, as well as vacuum,
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
, and steam nozzles. The gas then flows up through the base through a small hole at the bottom of the barrel and is directed upward. There are open slots in the side of the tube bottom to admit air into the stream using the
Venturi effect The Venturi effect is the reduction in fluid pressure that results when a fluid flows through a constricted section (or choke) of a pipe. The Venturi effect is named after its discoverer, the 18th century Italian physicist, Giovanni Battista ...
, and the gas burns at the top of the tube once ignited by a flame or spark. The most common methods of lighting the burner are using a
match A match is a tool for starting a fire. Typically, matches are made of small wooden sticks or stiff paper. One end is coated with a material that can be ignited by friction generated by striking the match against a suitable surface. Wooden matc ...
or a
spark lighter Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and some iron – about 95% lanthanides and 5% iron) hardened by blending in oxides of ...
. The amount of air mixed with the gas stream affects the completeness of the
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...
reaction. Less air yields an incomplete and thus cooler reaction, while a gas stream well mixed with air provides oxygen in a
stoichiometric Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equ ...
amount and thus a complete and hotter reaction. The air flow can be controlled by opening or closing the slot openings at the base of the barrel, similar in function to the choke in a carburettor. If the collar at the bottom of the tube is adjusted so more air can mix with the gas before combustion, the flame will burn hotter, appearing blue as a result. If the holes are closed, the gas will only mix with ambient air at the point of combustion, that is, only after it has exited the tube at the top. This reduced mixing produces an incomplete reaction, producing a cooler but brighter yellow, which is often called the "safety flame" or "
luminous flame A luminous flame is a burning flame which is brightly visible. Much of its output is in the form of visible light, as well as heat or light in the non-visible wavelengths. An early study of flame luminosity was conducted by Michael Faraday and bec ...
". The yellow flame is luminous due to small
soot Soot ( ) is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. It is more properly restricted to the product of the gas-phase combustion process but is commonly extended to include the residual pyrolysed ...
particles in the flame, which are heated to incandescence. The yellow flame is considered "dirty" because it leaves a layer of carbon on whatever it is heating. When the burner is regulated to produce a hot, blue flame, it can be nearly invisible against some backgrounds. The hottest part of the flame is the tip of the inner flame, while the coolest is the whole inner flame. Increasing the amount of fuel gas flow through the tube by opening the
needle valve A needle valve is a type of valve with a small port and a threaded, needle-shaped plunger. It allows precise regulation of flow, although it is generally only capable of relatively low flow rates. Construction and operation An instrument ne ...
will increase the size of the flame. However, unless the airflow is adjusted as well, the flame temperature will decrease because an increased amount of gas is now mixed with the same amount of air, starving the flame of oxygen. Generally, the burner is placed underneath a
laboratory tripod A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratory services are provided in a variety of settings: physici ...
, which supports a beaker or other container. The burner will often be placed on a suitable heatproof mat to protect the laboratory bench surface. A Bunsen burner is also used in microbiology laboratories to sterilise pieces of equipment and to produce an updraft that forces airborne contaminants away from the working area.


Variants

Other burners based on the same principle exist. The most important alternatives to the Bunsen burner are: *
Teclu burner The Teclu burner is an ambient air laboratory gas burner, that was created by Romanian chemist Nicolae Teclu in 1882. The burner is most commonly used to heat substances in a laboratory, can be used for sterilisation and sometimes it is used for s ...
– The lower part of its tube is conical, with a round screw nut below its base. The gap, set by the distance between the nut and the end of the tube, regulates the influx of the air in a way similar to the open slots of the Bunsen burner. The Teclu burner provides better mixing of air and fuel and can achieve higher flame temperatures than the Bunsen burner. * Meker burner – The lower part of its tube has more openings with larger total cross-section, admitting more air and facilitating better mixing of air and gas. The tube is wider and its top is covered with a wire grid. The grid separates the flame into an array of smaller flames with a common external envelope, and also prevents flashback to the bottom of the tube, which is a risk at high air-to-fuel ratios and limits the maximum rate of air intake in a conventional Bunsen burner. Flame temperatures of up to are achievable if properly used. The flame also burns without noise, unlike the Bunsen or Teclu burners. * Tirrill burner – The base of the burner has a needle valve which allows the regulation of gas intake directly from the Burner, rather than from the gas source. Maximum temperature of flame can reach 1560 °C.


See also

*
Alcohol burner An alcohol burner or spirit lamp is a piece of laboratory equipment used to produce an open flame. It can be made from brass, glass, stainless steel or aluminium. Uses Alcohol burners are preferred for some uses over Bunsen burners for safety p ...
*
Heating mantle A heating mantle, or isomantle, is a piece of laboratory equipment used to apply heat to containers, as an alternative to other forms of heated bath. In contrast to other heating devices, such as hotplates or Bunsen burners, glassware contain ...
* Meker-Fisher burner


References


External links

* * {{DEFAULTSORT:Bunsen Burner Burners Combustion engineering German inventions Laboratory equipment