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In condensed matter physics, a Bose–Einstein condensate (BEC) is a
state of matter In physics, a state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid, liquid, gas, and plasma. Many intermediate states are known to exist, such as liquid crystal ...
that is typically formed when a
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
of
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer spi ...
s at very low
densities Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek language, Greek letter Rho (letter), rho), although the Latin letter ''D'' ca ...
is cooled to
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...
s very close to absolute zero (−273.15 °C or −459.67 °F). Under such conditions, a large fraction of bosons occupy the lowest
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
, at which point microscopic
quantum mechanical Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, qua ...
phenomena, particularly wavefunction interference, become apparent macroscopically. A BEC is formed by cooling a gas of extremely low density (about 100,000 times less dense than normal air) to ultra-low temperatures. This state was first predicted, generally, in 1924–1925 by
Albert Einstein Albert Einstein ( ; ; 14 March 1879 – 18 April 1955) was a German-born theoretical physicist, widely acknowledged to be one of the greatest and most influential physicists of all time. Einstein is best known for developing the theory ...
following and crediting a pioneering paper by
Satyendra Nath Bose Satyendra Nath Bose (; 1 January 1894 – 4 February 1974) was a Bengali mathematician and physicist specializing in theoretical physics. He is best known for his work on quantum mechanics in the early 1920s, in developing the foundation for ...
on the new field now known as quantum statistics. In 1995, the Bose-Einstein condensate was created by
Eric Cornell Eric Allin Cornell (born December 19, 1961) is an American physicist who, along with Carl E. Wieman, was able to synthesize the first Bose–Einstein condensate in 1995. For their efforts, Cornell, Wieman, and Wolfgang Ketterle shared the Nobel ...
and Carl Wieman of the
University of Colorado at Boulder The University of Colorado Boulder (CU Boulder, CU, or Colorado) is a public research university in Boulder, Colorado. Founded in 1876, five months before Colorado became a state, it is the flagship university of the University of Colorado sys ...
using rubidium atoms; later that year,
Wolfgang Ketterle Wolfgang Ketterle (; born 21 October 1957) is a German physicist and professor of physics at the Massachusetts Institute of Technology (MIT). His research has focused on experiments that trap and cool atoms to temperatures close to absolute ze ...
of
MIT The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the m ...
produced a BEC using
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
atoms. In 2001 Cornell, Wieman and Ketterle shared the
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
"for the achievement of Bose-Einstein condensation in dilute gases of alkali atoms, and for early fundamental studies of the properties of the condensates."


History

Bose first sent a paper to Einstein on the quantum statistics of light quanta (now called
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s), in which he derived Planck's quantum radiation law without any reference to classical physics. Einstein was impressed, translated the paper himself from English to German and submitted it for Bose to the ''
Zeitschrift für Physik ''Zeitschrift für Physik'' (English: ''Journal for Physics'') is a defunct series of German peer-reviewed physics journals established in 1920 by Springer Berlin Heidelberg. The series stopped publication in 1997, when it merged with other journ ...
'', which published it in 1924. (The Einstein manuscript, once believed to be lost, was found in a library at Leiden University in 2005.) Einstein then extended Bose's ideas to matter in two other papers. The result of their efforts is the concept of a
Bose gas An ideal Bose gas is a quantum-mechanical phase of matter, analogous to a classical ideal gas. It is composed of bosons, which have an integer value of spin, and abide by Bose–Einstein statistics. The statistical mechanics of bosons were deve ...
, governed by
Bose–Einstein statistics In quantum statistics, Bose–Einstein statistics (B–E statistics) describes one of two possible ways in which a collection of non-interacting, indistinguishable particles may occupy a set of available discrete energy states at thermodynamic ...
, which describes the statistical distribution of
identical particles In quantum mechanics, identical particles (also called indistinguishable or indiscernible particles) are particles that cannot be distinguished from one another, even in principle. Species of identical particles include, but are not limited to, ...
with
integer An integer is the number zero (), a positive natural number (, , , etc.) or a negative integer with a minus sign (−1, −2, −3, etc.). The negative numbers are the additive inverses of the corresponding positive numbers. In the language ...
spin, now called
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer spi ...
s. Bosons, particles that include the
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
as well as
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...
s such as
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consis ...
(), are allowed to share a quantum state. Einstein proposed that cooling bosonic atoms to a very low temperature would cause them to fall (or "condense") into the lowest accessible
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
, resulting in a new form of matter. In 1938,
Fritz London Fritz Wolfgang London (March 7, 1900 – March 30, 1954) was a German physicist and professor at Duke University. His fundamental contributions to the theories of chemical bonding and of intermolecular forces ( London dispersion forces) are today ...
proposed the BEC as a mechanism for
superfluidity Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
in and superconductivity. The quest to produce a Bose–Einstein condensate in the laboratory was stimulated by a paper published in 1976 by two Program Directors at the National Science Foundation (William Stwalley and Lewis Nosanow). This led to the immediate pursuit of the idea by four independent research groups; these were led by Isaac Silvera (
University of Amsterdam The University of Amsterdam (abbreviated as UvA, nl, Universiteit van Amsterdam) is a public research university located in Amsterdam, Netherlands. The UvA is one of two large, publicly funded research universities in the city, the other being ...
), Walter Hardy (
University of British Columbia The University of British Columbia (UBC) is a public university, public research university with campuses near Vancouver and in Kelowna, British Columbia. Established in 1908, it is British Columbia's oldest university. The university ranks a ...
), Thomas Greytak (
Massachusetts Institute of Technology The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the ...
) and David Lee (
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
). On 5 June 1995, the first gaseous condensate was produced by
Eric Cornell Eric Allin Cornell (born December 19, 1961) is an American physicist who, along with Carl E. Wieman, was able to synthesize the first Bose–Einstein condensate in 1995. For their efforts, Cornell, Wieman, and Wolfgang Ketterle shared the Nobel ...
and Carl Wieman at the
University of Colorado at Boulder The University of Colorado Boulder (CU Boulder, CU, or Colorado) is a public research university in Boulder, Colorado. Founded in 1876, five months before Colorado became a state, it is the flagship university of the University of Colorado sys ...
NIST
JILA JILA, formerly known as the Joint Institute for Laboratory Astrophysics, is a physical science research institute in the United States. JILA is located on the University of Colorado Boulder campus. JILA was founded in 1962 as a joint institute ...
lab, in a gas of rubidium atoms cooled to 170 nanokelvins (nK). Shortly thereafter,
Wolfgang Ketterle Wolfgang Ketterle (; born 21 October 1957) is a German physicist and professor of physics at the Massachusetts Institute of Technology (MIT). His research has focused on experiments that trap and cool atoms to temperatures close to absolute ze ...
at MIT produced a Bose–Einstein Condensate in a gas of
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
atoms. For their achievements Cornell, Wieman, and Ketterle received the 2001
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
. These early studies founded the field of
ultracold atom Ultracold atoms are atoms that are maintained at temperatures close to 0 kelvin (absolute zero), typically below several tens of microkelvin (µK). At these temperatures the atom's quantum-mechanical properties become important. To reach such low ...
s, and hundreds of research groups around the world now routinely produce BECs of dilute atomic vapors in their labs. Since 1995, many other atomic species have been condensed, and BECs have also been realized using molecules, quasi-particles, and photons.


Critical temperature

This transition to BEC occurs below a critical temperature, which for a uniform
three-dimensional Three-dimensional space (also: 3D space, 3-space or, rarely, tri-dimensional space) is a geometric setting in which three values (called ''parameters'') are required to determine the position of an element (i.e., point). This is the informa ...
gas consisting of non-interacting particles with no apparent internal degrees of freedom is given by: :T_=\left(\frac\right)^\frac \approx 3.3125 \ \frac where: : Interactions shift the value and the corrections can be calculated by
mean-field theory In physics and probability theory, Mean-field theory (MFT) or Self-consistent field theory studies the behavior of high-dimensional random (stochastic) models by studying a simpler model that approximates the original by averaging over degrees of ...
. This formula is derived from finding the gas degeneracy in the
Bose gas An ideal Bose gas is a quantum-mechanical phase of matter, analogous to a classical ideal gas. It is composed of bosons, which have an integer value of spin, and abide by Bose–Einstein statistics. The statistical mechanics of bosons were deve ...
using
Bose–Einstein statistics In quantum statistics, Bose–Einstein statistics (B–E statistics) describes one of two possible ways in which a collection of non-interacting, indistinguishable particles may occupy a set of available discrete energy states at thermodynamic ...
.


Derivation


Ideal Bose gas

For an ideal
Bose gas An ideal Bose gas is a quantum-mechanical phase of matter, analogous to a classical ideal gas. It is composed of bosons, which have an integer value of spin, and abide by Bose–Einstein statistics. The statistical mechanics of bosons were deve ...
we have the equation of state: :\frac=\fracg_(f)+\frac\frac where v=V/N is the per particle volume, \lambda the
thermal wavelength In physics, the thermal de Broglie wavelength (\lambda_, sometimes also denoted by \Lambda) is roughly the average de Broglie wavelength of particles in an ideal gas at the specified temperature. We can take the average interparticle spacing in ...
, f the
fugacity In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of the chemical equilibrium constant. It is equal to the pressure of an ideal gas whic ...
and :g_\alpha (f)=\sum \limits_^\infty \frac It is noticeable that g_ is a monotonically growing function of f in f \in , 1/math>, which are the only values for which the series converge. Recognizing that the second term on the right-hand side contains the expression for the average occupation number of the fundamental state \langle n_0 \rangle, the equation of state can be rewritten as :\frac=\fracg_(f)+\frac \Leftrightarrow \frac\lambda^3=\frac-g_(f) Because the left term on the second equation must always be positive, \frac>g_(f) and because g_(f)\le g_(1), a stronger condition is :\frac>g_(1) which defines a transition between a gas phase and a condensed phase. On the critical region it is possible to define a critical temperature and thermal wavelength: :\lambda_c^3=g_(1)v=\zeta(3/2)v :T_c=\frac recovering the value indicated on the previous section. The critical values are such that if T or \lambda >\lambda_c we are in the presence of a Bose–Einstein condensate. Understanding what happens with the fraction of particles on the fundamental level is crucial. As so, write the equation of state for f=1, obtaining :\frac=1-\left(\frac\right)^3 and equivalently \frac=1-\left(\frac\right)^. So, if T\ll T_c the fraction \frac \approx 1 and if T \gg T_c the fraction \frac \approx 0. At temperatures near to absolute 0, particles tend to condensate in the fundamental state, which is the state with momentum \vec=0.


Models


Bose Einstein's non-interacting gas

Consider a collection of ''N'' non-interacting particles, which can each be in one of two
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
s, , 0\rangle and , 1\rangle. If the two states are equal in energy, each different configuration is equally likely. If we can tell which particle is which, there are 2^N different configurations, since each particle can be in , 0\rangle or , 1\rangle independently. In almost all of the configurations, about half the particles are in , 0\rangle and the other half in , 1\rangle. The balance is a statistical effect: the number of configurations is largest when the particles are divided equally. If the particles are indistinguishable, however, there are only ''N''+1 different configurations. If there are ''K'' particles in state , 1\rangle, there are particles in state , 0\rangle. Whether any particular particle is in state , 0\rangle or in state , 1\rangle cannot be determined, so each value of ''K'' determines a unique quantum state for the whole system. Suppose now that the energy of state , 1\rangle is slightly greater than the energy of state , 0\rangle by an amount ''E''. At temperature ''T'', a particle will have a lesser probability to be in state , 1\rangle by e^. In the distinguishable case, the particle distribution will be biased slightly towards state , 0\rangle. But in the indistinguishable case, since there is no statistical pressure toward equal numbers, the most-likely outcome is that most of the particles will collapse into state , 0\rangle. In the distinguishable case, for large ''N'', the fraction in state , 0\rangle can be computed. It is the same as flipping a coin with probability proportional to ''p'' = exp(−''E''/''T'') to land tails. In the indistinguishable case, each value of ''K'' is a single state, which has its own separate Boltzmann probability. So the probability distribution is exponential: :\, P(K)= C e^ = C p^K. For large ''N'', the normalization constant ''C'' is . The expected total number of particles not in the lowest energy state, in the limit that N\rightarrow \infty, is equal to : \sum_ C p^n=p/(1-p) It does not grow when ''N'' is large; it just approaches a constant. This will be a negligible fraction of the total number of particles. So a collection of enough Bose particles in thermal equilibrium will mostly be in the ground state, with only a few in any excited state, no matter how small the energy difference. Consider now a gas of particles, which can be in different momentum states labeled , k\rangle. If the number of particles is less than the number of thermally accessible states, for high temperatures and low densities, the particles will all be in different states. In this limit, the gas is classical. As the density increases or the temperature decreases, the number of accessible states per particle becomes smaller, and at some point, more particles will be forced into a single state than the maximum allowed for that state by statistical weighting. From this point on, any extra particle added will go into the ground state. To calculate the transition temperature at any density, integrate, over all momentum states, the expression for maximum number of excited particles, : :\, N = V \int = V \int :\, p(k)= e^. When the integral (also known as
Bose–Einstein integral In mathematics, the polylogarithm (also known as Jonquière's function, for Alfred Jonquière) is a special function of order and argument . Only for special values of does the polylogarithm reduce to an elementary function such as the natu ...
) is evaluated with factors of k_B and ℏ restored by dimensional analysis, it gives the critical temperature formula of the preceding section. Therefore, this integral defines the critical temperature and particle number corresponding to the conditions of negligible
chemical potential In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species ...
\mu. In
Bose–Einstein statistics In quantum statistics, Bose–Einstein statistics (B–E statistics) describes one of two possible ways in which a collection of non-interacting, indistinguishable particles may occupy a set of available discrete energy states at thermodynamic ...
distribution, \mu is actually still nonzero for BECs; however, \mu is less than the ground state energy. Except when specifically talking about the ground state, \mu can be approximated for most energy or momentum states as \mu \approx 0.


Bogoliubov theory for weakly interacting gas

Nikolay Bogoliubov Nikolay Nikolayevich Bogolyubov (russian: Никола́й Никола́евич Боголю́бов; 21 August 1909 – 13 February 1992), also transliterated as Bogoliubov and Bogolubov, was a Soviet and Russian mathematician and theoretic ...
considered perturbations on the limit of dilute gas, finding a finite pressure at zero temperature and positive chemical potential. This leads to corrections for the ground state. The Bogoliubov state has pressure (''T'' = 0): P = gn^2/2. The original interacting system can be converted to a system of non-interacting particles with a dispersion law.


Gross–Pitaevskii equation

In some simplest cases, the state of condensed particles can be described with a nonlinear Schrödinger equation, also known as Gross–Pitaevskii or Ginzburg–Landau equation. The validity of this approach is actually limited to the case of ultracold temperatures, which fits well for the most alkali atoms experiments. This approach originates from the assumption that the state of the BEC can be described by the unique wavefunction of the condensate \psi(\vec). For a system of this nature, , \psi(\vec), ^2 is interpreted as the particle density, so the total number of atoms is N=\int d\vec, \psi(\vec), ^2 Provided essentially all atoms are in the condensate (that is, have condensed to the ground state), and treating the bosons using
mean-field theory In physics and probability theory, Mean-field theory (MFT) or Self-consistent field theory studies the behavior of high-dimensional random (stochastic) models by studying a simpler model that approximates the original by averaging over degrees of ...
, the energy (E) associated with the state \psi(\vec) is: :E=\int d\vec\left \nabla\psi(\vec), ^2+V(\vec), \psi(\vec), ^2+\fracU_0, \psi(\vec), ^4\right/math> Minimizing this energy with respect to infinitesimal variations in \psi(\vec), and holding the number of atoms constant, yields the Gross–Pitaevski equation (GPE) (also a non-linear
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
): :i\hbar\frac = \left(-\frac+V(\vec)+U_0, \psi(\vec), ^2\right)\psi(\vec) where: : In the case of zero external potential, the dispersion law of interacting Bose–Einstein-condensed particles is given by so-called Bogoliubov spectrum (for \ T= 0): : = \sqrt The Gross-Pitaevskii equation (GPE) provides a relatively good description of the behavior of atomic BEC's. However, GPE does not take into account the temperature dependence of dynamical variables, and is therefore valid only for \ T= 0. It is not applicable, for example, for the condensates of excitons, magnons and photons, where the critical temperature is comparable to room temperature.


Numerical solution

The Gross-Pitaevskii equation is a partial differential equation in space and time variables. Usually it does not have analytic solution and different numerical methods, such as split-step Crank-Nicolson and Fourier spectral methods, are used for its solution. There are different Fortran and C programs for its solution for contact interaction and long-range dipolar interaction which can be freely used.


Weaknesses of Gross–Pitaevskii model

The Gross–Pitaevskii model of BEC is a physical
approximation An approximation is anything that is intentionally similar but not exactly equality (mathematics), equal to something else. Etymology and usage The word ''approximation'' is derived from Latin ''approximatus'', from ''proximus'' meaning ''very ...
valid for certain classes of BECs. By construction, the GPE uses the following simplifications: it assumes that interactions between condensate particles are of the contact two-body type and also neglects anomalous contributions to
self-energy In quantum field theory, the energy that a particle has as a result of changes that it causes in its environment defines self-energy \Sigma, and represents the contribution to the particle's energy, or effective mass, due to interactions between ...
. These assumptions are suitable mostly for the dilute three-dimensional condensates. If one relaxes any of these assumptions, the equation for the condensate
wavefunction A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements ...
acquires the terms containing higher-order powers of the wavefunction. Moreover, for some physical systems the amount of such terms turns out to be infinite, therefore, the equation becomes essentially non-polynomial. The examples where this could happen are the Bose–Fermi composite condensates, effectively lower-dimensional condensates, and dense condensates and
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
clusters and droplets. It is found that one has to go beyond the Gross-Pitaevskii equation. For example, the logarithmic term \psi \ln , \psi, ^2 found in the
Logarithmic Schrödinger equation In theoretical physics, the logarithmic Schrödinger equation (sometimes abbreviated as LNSE or LogSE) is one of the nonlinear modifications of Schrödinger's equation. It is a classical wave equation with applications to extensions of quantum mech ...
must be added to the Gross-Pitaevskii equation along with a Ginzburg-Sobyanin contribution to correctly determine that the speed of sound scales as the cubic root of pressure for Helium-4 at very low temperatures in close agreement with experiment.


Other

However, it is clear that in a general case the behaviour of Bose–Einstein condensate can be described by coupled evolution equations for condensate density, superfluid velocity and distribution function of elementary excitations. This problem was solved in 1977 by Peletminskii et al. in microscopical approach. The Peletminskii equations are valid for any finite temperatures below the critical point. Years after, in 1985, Kirkpatrick and Dorfman obtained similar equations using another microscopical approach. The Peletminskii equations also reproduce Khalatnikov hydrodynamical equations for superfluid as a limiting case.


Superfluidity of BEC and Landau criterion

The phenomena of superfluidity of a Bose gas and superconductivity of a strongly-correlated Fermi gas (a gas of Cooper pairs) are tightly connected to Bose–Einstein condensation. Under corresponding conditions, below the temperature of phase transition, these phenomena were observed in
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consis ...
and different classes of superconductors. In this sense, the superconductivity is often called the superfluidity of Fermi gas. In the simplest form, the origin of superfluidity can be seen from the weakly interacting bosons model.


Experimental observation


Superfluid helium-4

In 1938,
Pyotr Kapitsa Pyotr Leonidovich Kapitsa or Peter Kapitza ( Russian: Пётр Леонидович Капица, Romanian: Petre Capița ( – 8 April 1984) was a leading Soviet physicist and Nobel laureate, best known for his work in low-temperature physics ...
, John Allen and
Don Misener Don Misener (A.D. Misener) (1911-1996) was a physicist. Along with Pyotr Leonidovich Kapitsa and John F. Allen, Misener discovered the superfluid phase of matter in 1937. Misener was a graduate student at the University of Toronto in 1935. He j ...
discovered that
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consis ...
became a new kind of fluid, now known as a
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
, at temperatures less than 2.17 K (the
lambda point The lambda point is the temperature at which normal fluid helium (helium I) makes the transition to superfluid helium II (approximately 2.17 K at 1 atmosphere). The lowest pressure at which He-I and He-II can coexist is the vapor−He-I−He-II ...
). Superfluid helium has many unusual properties, including zero
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...
(the ability to flow without dissipating energy) and the existence of quantized vortices. It was quickly believed that the superfluidity was due to partial Bose–Einstein condensation of the liquid. In fact, many properties of superfluid helium also appear in gaseous condensates created by Cornell, Wieman and Ketterle (see below). Superfluid helium-4 is a liquid rather than a gas, which means that the interactions between the atoms are relatively strong; the original theory of Bose–Einstein condensation must be heavily modified in order to describe it. Bose–Einstein condensation remains, however, fundamental to the superfluid properties of helium-4. Note that helium-3, a fermion, also enters a
superfluid Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
phase (at a much lower temperature) which can be explained by the formation of bosonic
Cooper pairs In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Coope ...
of two atoms (see also
fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
).


Dilute atomic gases

The first "pure" Bose–Einstein condensate was created by
Eric Cornell Eric Allin Cornell (born December 19, 1961) is an American physicist who, along with Carl E. Wieman, was able to synthesize the first Bose–Einstein condensate in 1995. For their efforts, Cornell, Wieman, and Wolfgang Ketterle shared the Nobel ...
, Carl Wieman, and co-workers at
JILA JILA, formerly known as the Joint Institute for Laboratory Astrophysics, is a physical science research institute in the United States. JILA is located on the University of Colorado Boulder campus. JILA was founded in 1962 as a joint institute ...
on 5 June 1995. They cooled a dilute vapor of approximately two thousand
rubidium-87 Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%). Normal mixes of rubidium are radioactive enough to fog photographic film in approximately 30 to ...
atoms to below 170 nK using a combination of
laser cooling Laser cooling includes a number of techniques in which atoms, molecules, and small mechanical systems are cooled, often approaching temperatures near absolute zero. Laser cooling techniques rely on the fact that when an object (usually an atom) a ...
(a technique that won its inventors Steven Chu,
Claude Cohen-Tannoudji Claude Cohen-Tannoudji (; born 1 April 1933) is a French physicist. He shared the 1997 Nobel Prize in Physics with Steven Chu and William Daniel Phillips for research in methods of laser cooling and trapping atoms. Currently he is still an activ ...
, and William D. Phillips the 1997
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
) and
magnetic evaporative cooling Evaporative cooling is an atomic physics technique to achieve high phase space densities which optical cooling techniques alone typically can not reach. Atoms trapped in optical or magnetic traps can be evaporatively cooled via two primary mechan ...
. About four months later, an independent effort led by
Wolfgang Ketterle Wolfgang Ketterle (; born 21 October 1957) is a German physicist and professor of physics at the Massachusetts Institute of Technology (MIT). His research has focused on experiments that trap and cool atoms to temperatures close to absolute ze ...
at
MIT The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the m ...
condensed
sodium-23 There are 22 isotopes of sodium (11Na), ranging from to , and two isomers ( and ). is the only stable (and the only primordial) isotope. It is considered a monoisotopic element and it has a standard atomic weight of . Sodium has two radioact ...
. Ketterle's condensate had a hundred times more atoms, allowing important results such as the observation of
quantum mechanical Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, qua ...
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...
between two different condensates. Cornell, Wieman and Ketterle won the 2001
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
for their achievements. A group led by Randall Hulet at Rice University announced a condensate of
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid ...
atoms only one month following the JILA work. Lithium has attractive interactions, causing the condensate to be unstable and collapse for all but a few atoms. Hulet's team subsequently showed the condensate could be stabilized by confinement quantum pressure for up to about 1000 atoms. Various isotopes have since been condensed.


Velocity-distribution data graph

In the image accompanying this article, the velocity-distribution data indicates the formation of a Bose–Einstein condensate out of a gas of rubidium atoms. The false colors indicate the number of atoms at each velocity, with red being the fewest and white being the most. The areas appearing white and light blue are at the lowest velocities. The peak is not infinitely narrow because of the Heisenberg uncertainty principle: spatially confined atoms have a minimum width velocity distribution. This width is given by the curvature of the magnetic potential in the given direction. More tightly confined directions have bigger widths in the ballistic velocity distribution. This
anisotropy Anisotropy () is the property of a material which allows it to change or assume different properties in different directions, as opposed to isotropy. It can be defined as a difference, when measured along different axes, in a material's physic ...
of the peak on the right is a purely quantum-mechanical effect and does not exist in the thermal distribution on the left. This graph served as the cover design for the 1999 textbook ''Thermal Physics'' by Ralph Baierlein.


Quasiparticles

Bose–Einstein condensation also applies to
quasiparticle In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For exa ...
s in solids.
Magnon A magnon is a quasiparticle, a collective excitation of the electrons' spin structure in a crystal lattice. In the equivalent wave picture of quantum mechanics, a magnon can be viewed as a quantized spin wave. Magnons carry a fixed amount of ...
s,
excitons An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb force. It is an electrically neutral quasiparticle that exists in insulators, semiconductors and some liquids. The ...
, and
polaritons In physics, polaritons are quasiparticles resulting from strong coupling of electromagnetic waves with an electric or magnetic dipole-carrying excitation. They are an expression of the common quantum phenomenon known as level repulsion, also ...
have integer spin which means they are
bosons In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer ...
that can form condensates. Magnons, electron spin waves, can be controlled by a magnetic field. Densities from the limit of a dilute gas to a strongly interacting Bose liquid are possible. Magnetic ordering is the analog of superfluidity. In 1999 condensation was demonstrated in antiferromagnetic , at temperatures as great as 14 K. The high transition temperature (relative to atomic gases) is due to the magnons' small mass (near that of an electron) and greater achievable density. In 2006, condensation in a ferromagnetic yttrium-iron-garnet thin film was seen even at room temperature, with optical pumping. Excitons, electron-hole pairs, were predicted to condense at low temperature and high density by Boer et al., in 1961. Bilayer system experiments first demonstrated condensation in 2003, by Hall voltage disappearance. Fast optical exciton creation was used to form condensates in sub-kelvin in 2005 on. Polariton condensation was first detected for
exciton-polaritons In physics the Exciton–polariton is a type of polariton; a hybrid light and matter quasiparticle arising from the strong coupling of the electromagnetic dipolar oscillations of excitons (either in bulk or quantum wells) and photons. Because light ...
in a quantum well microcavity kept at 5 K.


In zero gravity

In June 2020, the
Cold Atom Laboratory The Cold Atom Laboratory (CAL) is an experimental instrument on board the ISS, which launched in 2018. It creates an extremely cold microgravity environment in order to study behaviour of atoms in these conditions. Timeline The CAL was developed ...
experiment on board the
International Space Station The International Space Station (ISS) is the largest modular space station currently in low Earth orbit. It is a multinational collaborative project involving five participating space agencies: NASA (United States), Roscosmos (Russia), JAXA ...
successfully created a BEC of rubidium atoms and observed them for over a second in free-fall. Although initially just a proof of function, early results showed that, in the microgravity environment of the ISS, about half of the atoms formed into a magnetically insensitive halo-like cloud around the main body of the BEC.


Peculiar properties


Quantized vortices

As in many other systems,
vortices In fluid dynamics, a vortex ( : vortices or vortexes) is a region in a fluid in which the flow revolves around an axis line, which may be straight or curved. Vortices form in stirred fluids, and may be observed in smoke rings, whirlpools in th ...
can exist in BECs. Vortices can be created, for example, by "stirring" the condensate with lasers, rotating the confining trap, or by rapid cooling across the phase transition. The vortex created will be a
quantum vortex In physics, a quantum vortex represents a quantized flux circulation of some physical quantity. In most cases, quantum vortices are a type of topological defect exhibited in superfluids and superconductors. The existence of quantum vortices was ...
with core shape determined by the interactions. Fluid circulation around any point is quantized due to the single-valued nature of the order BEC order parameter or wavefunction, that can be written in the form \psi(\vec)=\phi(\rho,z)e^ where \rho, z and \theta are as in the
cylindrical coordinate system A cylindrical coordinate system is a three-dimensional coordinate system that specifies point positions by the distance from a chosen reference axis ''(axis L in the image opposite)'', the direction from the axis relative to a chosen reference di ...
, and \ell is the angular quantum number (a.k.a. the "charge" of the vortex). Since the energy of a vortex is proportional to the square of its angular momentum, in
trivial topology In topology, a topological space with the trivial topology is one where the only open sets are the empty set and the entire space. Such spaces are commonly called indiscrete, anti-discrete, concrete or codiscrete. Intuitively, this has the conseque ...
only \ell=1 vortices can exist in the
steady state In systems theory, a system or a process is in a steady state if the variables (called state variables) which define the behavior of the system or the process are unchanging in time. In continuous time, this means that for those properties ''p' ...
; Higher-charge vortices will have a tendency to split into \ell=1 vortices, if allowed by the topology of the geometry. An axially symmetric (for instance, harmonic) confining potential is commonly used for the study of vortices in BEC. To determine \phi(\rho,z), the energy of \psi(\vec) must be minimized, according to the constraint \psi(\vec)=\phi(\rho,z)e^. This is usually done computationally, however, in a uniform medium, the following analytic form demonstrates the correct behavior, and is a good approximation: :\phi=\frac\,. Here, n is the density far from the vortex and x=\rho/(\ell \xi), where \xi=1/\sqrt is the healing length of the condensate. A singly charged vortex (\ell=1) is in the ground state, with its energy \epsilon_v given by :\epsilon_v=\pi n \frac\ln\left(1.464\frac\right) where \,b is the farthest distance from the vortices considered.(To obtain an energy which is well defined it is necessary to include this boundary b.) For multiply charged vortices (\ell >1) the energy is approximated by :\epsilon_v\approx \ell^2\pi n \frac\ln\left(\frac\right) which is greater than that of \ell singly charged vortices, indicating that these multiply charged vortices are unstable to decay. Research has, however, indicated they are metastable states, so may have relatively long lifetimes. Closely related to the creation of vortices in BECs is the generation of so-called dark
soliton In mathematics and physics, a soliton or solitary wave is a self-reinforcing wave packet that maintains its shape while it propagates at a constant velocity. Solitons are caused by a cancellation of nonlinear and dispersive effects in the medi ...
s in one-dimensional BECs. These topological objects feature a phase gradient across their nodal plane, which stabilizes their shape even in propagation and interaction. Although solitons carry no charge and are thus prone to decay, relatively long-lived dark solitons have been produced and studied extensively.


Attractive interactions

Experiments led by Randall Hulet at Rice University from 1995 through 2000 showed that lithium condensates with attractive interactions could stably exist up to a critical atom number. Quench cooling the gas, they observed the condensate to grow, then subsequently collapse as the attraction overwhelmed the zero-point energy of the confining potential, in a burst reminiscent of a supernova, with an explosion preceded by an implosion. Further work on attractive condensates was performed in 2000 by the
JILA JILA, formerly known as the Joint Institute for Laboratory Astrophysics, is a physical science research institute in the United States. JILA is located on the University of Colorado Boulder campus. JILA was founded in 1962 as a joint institute ...
team, of Cornell, Wieman and coworkers. Their instrumentation now had better control so they used naturally ''attracting'' atoms of rubidium-85 (having negative atom–atom
scattering length The scattering length in quantum mechanics describes low-energy scattering. For potentials that decay faster than 1/r^3 as r\to \infty, it is defined as the following low-energy limit (mathematics), limit: : \lim_ k\cot\delta(k) =- \frac\;, wher ...
). Through
Feshbach resonance In physics, a Feshbach resonance can occur upon collision of two slow atoms, when they temporarily stick together forming an unstable compound with short lifetime (so-called resonance). It is a feature of many-body systems in which a bound state i ...
involving a sweep of the magnetic field causing spin flip collisions, they lowered the characteristic, discrete energies at which rubidium bonds, making their Rb-85 atoms repulsive and creating a stable condensate. The reversible flip from attraction to repulsion stems from quantum
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...
among wave-like condensate atoms. When the JILA team raised the magnetic field strength further, the condensate suddenly reverted to attraction, imploded and shrank beyond detection, then exploded, expelling about two-thirds of its 10,000 atoms. About half of the atoms in the condensate seemed to have disappeared from the experiment altogether, not seen in the cold remnant or expanding gas cloud. Carl Wieman explained that under current atomic theory this characteristic of Bose–Einstein condensate could not be explained because the energy state of an atom near absolute zero should not be enough to cause an implosion; however, subsequent mean-field theories have been proposed to explain it. Most likely they formed molecules of two rubidium atoms; energy gained by this bond imparts velocity sufficient to leave the trap without being detected. The process of creation of molecular Bose condensate during the sweep of the magnetic field throughout the Feshbach resonance, as well as the reverse process, are described by the exactly solvable model that can explain many experimental observations.


Current research

Compared to more commonly encountered states of matter, Bose–Einstein condensates are extremely fragile. The slightest interaction with the external environment can be enough to warm them past the condensation threshold, eliminating their interesting properties and forming a normal gas. Nevertheless, they have proven useful in exploring a wide range of questions in fundamental physics, and the years since the initial discoveries by the JILA and MIT groups have seen an increase in experimental and theoretical activity. Examples include experiments that have demonstrated
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...
between condensates due to
wave–particle duality Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be described as either a particle or a wave. It expresses the inability of the classical concepts "particle" or "wave" to fully describe the b ...
, the study of
superfluidity Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two ...
and quantized
vortices In fluid dynamics, a vortex ( : vortices or vortexes) is a region in a fluid in which the flow revolves around an axis line, which may be straight or curved. Vortices form in stirred fluids, and may be observed in smoke rings, whirlpools in th ...
, the creation of bright matter wave
soliton In mathematics and physics, a soliton or solitary wave is a self-reinforcing wave packet that maintains its shape while it propagates at a constant velocity. Solitons are caused by a cancellation of nonlinear and dispersive effects in the medi ...
s from Bose condensates confined to one dimension, and the slowing of light pulses to very low speeds using
electromagnetically induced transparency Electromagnetically induced transparency (EIT) is a coherent optical nonlinearity which renders a medium transparent within a narrow spectral range around an absorption line. Extreme dispersion is also created within this transparency "window" ...
. Vortices in Bose–Einstein condensates are also currently the subject of analogue gravity research, studying the possibility of modeling black holes and their related phenomena in such environments in the laboratory. Experimenters have also realized "
optical lattice An optical lattice is formed by the interference of counter-propagating laser beams, creating a spatially periodic polarization pattern. The resulting periodic potential may trap neutral atoms via the Stark shift. Atoms are cooled and congrega ...
s", where the interference pattern from overlapping lasers provides a periodic potential. These have been used to explore the transition between a superfluid and a
Mott insulator Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators (particularly at low temperatures). These insulators fail to be correctly described by band ...
, and may be useful in studying Bose–Einstein condensation in fewer than three dimensions, for example the
Tonks–Girardeau gas In physics, a Tonks–Girardeau gas is a Bose gas in which the repulsive interactions between bosonic particles confined to one dimension dominate the system's physics. It is named after physicists Marvin D. Girardeau and Lewi Tonks. It is not a B ...
. Further, the sensitivity of the pinning transition of strongly interacting bosons confined in a shallow one-dimensional optical lattice originally observed by Haller has been explored via a tweaking of the primary optical lattice by a secondary weaker one. Thus for a resulting weak bichromatic optical lattice, it has been found that the pinning transition is robust against the introduction of the weaker secondary optical lattice. Studies of vortices in nonuniform Bose–Einstein condensates as well as excitatons of these systems by the application of moving repulsive or attractive obstacles, have also been undertaken. Within this context, the conditions for order and chaos in the dynamics of a trapped Bose–Einstein condensate have been explored by the application of moving blue and red-detuned laser beams via the time-dependent Gross-Pitaevskii equation. Bose–Einstein condensates composed of a wide range of
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
s have been produced. Cooling fermions to extremely low temperatures has created
degenerate Degeneracy, degenerate, or degeneration may refer to: Arts and entertainment * Degenerate (album), ''Degenerate'' (album), a 2010 album by the British band Trigger the Bloodshed * Degenerate art, a term adopted in the 1920s by the Nazi Party i ...
gases, subject to the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
. To exhibit Bose–Einstein condensation, the fermions must "pair up" to form bosonic compound particles (e.g.
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
s or
Cooper pairs In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Coope ...
). The first molecular condensates were created in November 2003 by the groups of
Rudolf Grimm Rudolf Grimm (born 10 November 1961) is an experimental physicist from Austria. His work centres on ultracold atoms and quantum gases. He was the first scientist worldwide who, with his team, succeeded in realizing a Bose–Einstein condensation ...
at the
University of Innsbruck The University of Innsbruck (german: Leopold-Franzens-Universität Innsbruck; la, Universitas Leopoldino Franciscea) is a public research university in Innsbruck, the capital of the Austrian federal state of Tyrol, founded on October 15, 1669. ...
, Deborah S. Jin at the
University of Colorado at Boulder The University of Colorado Boulder (CU Boulder, CU, or Colorado) is a public research university in Boulder, Colorado. Founded in 1876, five months before Colorado became a state, it is the flagship university of the University of Colorado sys ...
and
Wolfgang Ketterle Wolfgang Ketterle (; born 21 October 1957) is a German physicist and professor of physics at the Massachusetts Institute of Technology (MIT). His research has focused on experiments that trap and cool atoms to temperatures close to absolute ze ...
at
MIT The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the m ...
. Jin quickly went on to create the first
fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
, working with the same system but outside the molecular regime. In 1999, Danish physicist
Lene Hau Lene Vestergaard Hau (; born November 13, 1959) is a Danish physicist and educator. She is the Mallinckrodt Professor of Physics and of Applied Physics at Harvard University. In 1999, she led a Harvard University team who, by use of a Bose–E ...
led a team from
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
which slowed a beam of light to about 17 meters per second using a superfluid. Hau and her associates have since made a group of condensate atoms recoil from a light pulse such that they recorded the light's phase and amplitude, recovered by a second nearby condensate, in what they term "slow-light-mediated atomic matter-wave amplification" using Bose–Einstein condensates: details are discussed in ''
Nature Nature, in the broadest sense, is the physics, physical world or universe. "Nature" can refer to the phenomenon, phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. ...
''. Another current research interest is the creation of Bose–Einstein condensates in microgravity in order to use its properties for high precision
atom interferometry An atom interferometer is an interferometer which uses the wave character of atoms. Similar to optical interferometers, atom interferometers measure the difference in phase between atomic matter waves along different paths. Atom interferometers h ...
. The first demonstration of a BEC in weightlessness was achieved in 2008 at a
drop tower A drop tower or big drop is a type of amusement ride incorporating a central structure or tower. Drop towers vary in height, passenger capacity, lift type, and brake type. Many are custom-made, although there are some mass-produced designs. T ...
in Bremen, Germany by a consortium of researchers led by
Ernst M. Rasel Ernst is both a surname and a given name, the German, Dutch, and Scandinavian form of Ernest. Notable people with the name include: Surname * Adolf Ernst (1832–1899) German botanist known by the author abbreviation "Ernst" * Anton Ernst (1975-) ...
from Leibniz University Hannover. The same team demonstrated in 2017 the first creation of a Bose–Einstein condensate in space and it is also the subject of two upcoming experiments on the
International Space Station The International Space Station (ISS) is the largest modular space station currently in low Earth orbit. It is a multinational collaborative project involving five participating space agencies: NASA (United States), Roscosmos (Russia), JAXA ...
. Researchers in the new field of
atomtronics Atomtronics is an emerging type of computing consisting of matter-wave circuits which coherently guide propagating ultra-cold atoms. The systems typically include components analogous to those found in electronic or optical systems, such as beam s ...
use the properties of Bose–Einstein condensates in the emerging quantum technology of matter-wave circuits. In 1970, BECs were proposed by
Emmanuel David Tannenbaum Emmanuel David Tannenbaum (June 28, 1978 – May 28, 2012) was an Israeli/American biophysicist and applied mathematician. He worked as a professor and researcher in the Department of Chemistry at the Ben-Gurion University of the Negev and the Dep ...
for anti- stealth technology. In 2020, researchers reported the development of
superconducting Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
BEC and that there appears to be a "smooth transition between" BEC and Bardeen–Cooper–Shrieffer regimes.


Continuous Bose–Einstein condensation

Limitations of evaporative cooling have restricted atomic BECs to "pulsed" operation, involving a highly inefficient duty cycle that discards more than 99% of atoms to reach BEC. Achieving continuous BEC has been a major open problem of experimental BEC research, driven by the same motivations as continuous optical laser development: high flux, high coherence matter waves produced continuously would enable new sensing applications. Continuous BEC was achieved for the first time in 2022.


Dark matter

P. Sikivie and Q. Yang showed that cold dark matter
axions An axion () is a hypothetical elementary particle postulated by the Peccei–Quinn theory in 1977 to resolve the strong CP problem in quantum chromodynamics (QCD). If axions exist and have low mass within a specific range, they are of interes ...
form a Bose–Einstein condensate by
thermalisation In physics, thermalisation is the process of physical bodies reaching thermal equilibrium through mutual interaction. In general the natural tendency of a system is towards a state of equipartition of energy and uniform temperature that maximizes ...
because of gravitational self-interactions. Axions have not yet been confirmed to exist. However the important search for them has been greatly enhanced with the completion of upgrades to the Axion Dark Matter Experiment (ADMX) at the University of Washington in early 2018. In 2014, a potential dibaryon was detected at the Jülich Research Center at about 2380 MeV. The center claimed that the measurements confirm results from 2011, via a more replicable method. The particle existed for 10−23 seconds and was named d*(2380). This particle is hypothesized to consist of three up and three
down quark The down quark or d quark (symbol: d) is the second-lightest of all quarks, a type of elementary particle, and a major constituent of matter. Together with the up quark, it forms the neutrons (one up quark, two down quarks) and protons (two up ...
s. It is theorized that groups of d* (d-stars) could form Bose–Einstein condensates due to prevailing low temperatures in the early universe, and that BECs made of such
hexaquark In particle physics hexaquarks, alternatively known as sexaquarks, are a large family of hypothetical particles, each particle consisting of six quarks or antiquarks of any flavours. Six constituent quarks in any of several combinations could yiel ...
s with trapped electrons could behave like
dark matter Dark matter is a hypothetical form of matter thought to account for approximately 85% of the matter in the universe. Dark matter is called "dark" because it does not appear to interact with the electromagnetic field, which means it does not a ...
.


Isotopes

The effect has mainly been observed on alkaline atoms which have nuclear properties particularly suitable for working with traps. As of 2012, using ultra-low temperatures of 10^ K or below, Bose–Einstein condensates had been obtained for a multitude of isotopes, mainly of
alkali metal The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...
,
alkaline earth metal The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are al ...
, and lanthanide atoms (, , , , , , , , , , , , , , and ). Research was finally successful in hydrogen with the aid of the newly developed method of 'evaporative cooling'. In contrast, the superfluid state of below is not a good example, because the interaction between the atoms is too strong. Only 8% of atoms are in the ground state of the trap near absolute zero, rather than the 100% of a true condensate. The
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer spi ...
ic behavior of some of these alkaline gases appears odd at first sight, because their nuclei have half-integer total spin. It arises from a subtle interplay of electronic and nuclear spins: at ultra-low temperatures and corresponding excitation energies, the half-integer total spin of the electronic shell and half-integer total spin of the nucleus are coupled by a very weak hyperfine interaction. The total spin of the atom, arising from this coupling, is an integer lower value. The chemistry of systems at room temperature is determined by the electronic properties, which is essentially fermionic, since room temperature thermal excitations have typical energies much higher than the hyperfine values.


In fiction

* In the 2016 film ''
Spectral ''Spectral'' is a 2016 3D military science fiction, supernatural horror fantasy and action-adventure thriller war film directed by Nic Mathieu. Written by himself, Ian Fried, and George Nolfi from a story by Fried and Mathieu. The film stars ...
'', the US military battles mysterious enemy creatures fashioned out of Bose–Einstein condensates. * In the 2003 novel '' Blind Lake'', scientists observe sentient life on a planet 51 light-years away using telescopes powered by Bose–Einstein condensate-based quantum computers. * The video game franchise ''
Mass Effect ''Mass Effect'' is a military science fiction media franchise created by Casey Hudson, Drew Karpyshyn and Preston Watamaniuk. The franchise depicts a distant future where humanity and several alien civilizations have colonized the known unive ...
'' has cryonic ammunition whose flavour text describes it as being filled with Bose-Einstein condensates. Upon impact, the bullets rupture and spray super-cold liquid on the enemy.


See also

*
Atom laser An atom laser is a coherent state of propagating atoms. They are created out of a Bose–Einstein condensate of atoms that are output coupled using various techniques. Much like an optical laser, an atom laser is a coherent beam that behaves like ...
*
Atomic coherence Atomic may refer to: * Of or relating to the atom, the smallest particle of a chemical element that retains its chemical properties * Atomic physics, the study of the atom * Atomic Age, also known as the "Atomic Era" * Atomic scale, distances com ...
*
Bose–Einstein correlations In physics, Bose–Einstein correlations are correlations between identical bosons. They have important applications in astronomy, optics, particle and nuclear physics. From intensity interferometry to Bose–Einstein correlations The interf ...
* Bose–Einstein condensation: a network theory approach *
Bose–Einstein condensation of quasiparticles Bose–Einstein condensation can occur in quasiparticles, particles that are effective descriptions of collective excitations in materials. Some have integer spins and can be expected to obey Bose–Einstein statistics like traditional particles. ...
*
Bose–Einstein statistics In quantum statistics, Bose–Einstein statistics (B–E statistics) describes one of two possible ways in which a collection of non-interacting, indistinguishable particles may occupy a set of available discrete energy states at thermodynamic ...
*
Cold Atom Laboratory The Cold Atom Laboratory (CAL) is an experimental instrument on board the ISS, which launched in 2018. It creates an extremely cold microgravity environment in order to study behaviour of atoms in these conditions. Timeline The CAL was developed ...
*
Electromagnetically induced transparency Electromagnetically induced transparency (EIT) is a coherent optical nonlinearity which renders a medium transparent within a narrow spectral range around an absorption line. Extreme dispersion is also created within this transparency "window" ...
*
Fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
*
Gas in a box In quantum mechanics, the results of the quantum particle in a box can be used to look at the equilibrium situation for a quantum ideal gas in a box which is a box containing a large number of molecules which do not interact with each other exce ...
*
Gross–Pitaevskii equation The Gross–Pitaevskii equation (GPE, named after Eugene P. Gross and Lev Petrovich Pitaevskii) describes the ground state of a quantum system of identical bosons using the Hartree–Fock approximation and the pseudopotential interaction model. ...
*
Macroscopic quantum phenomena Macroscopic quantum phenomena are processes showing quantum behavior at the macroscopic scale, rather than at the atomic scale where quantum effects are prevalent. The best-known examples of macroscopic quantum phenomena are superfluidity and su ...
*
Macroscopic quantum self-trapping In quantum mechanics, macroscopic quantum self-trapping is when two Bose-Einstein condensates weakly linked by an energy barrier which particles can tunnel through, nevertheless end up with a higher average number of bosons on one side of the junc ...
*
Slow light Slow light is the propagation of an optical pulse or other modulation of an optical carrier at a very low group velocity. Slow light occurs when a propagating pulse is substantially slowed by the interaction with the medium in which the propagatio ...
* Super-heavy atom * Superconductivity * Superfluid film * Superfluid helium-4 * Supersolid *
Tachyon condensation A tachyon () or tachyonic particle is a hypothetical particle that always travels faster than light. Physicists believe that faster-than-light particles cannot exist because they are not consistent with the known laws of physics. If such parti ...
*
Timeline of low-temperature technology The following is a timeline of low-temperature technology and cryogenic technology (refrigeration down to –273.15 °C, –459.67 °F or 0 K). It also lists important milestones in thermometry, thermodynamics, statistical physics and c ...
*
Ultracold atom Ultracold atoms are atoms that are maintained at temperatures close to 0 kelvin (absolute zero), typically below several tens of microkelvin (µK). At these temperatures the atom's quantum-mechanical properties become important. To reach such low ...
*
Wiener sausage In the mathematical field of probability, the Wiener sausage is a neighborhood of the trace of a Brownian motion up to a time ''t'', given by taking all points within a fixed distance of Brownian motion. It can be visualized as a sausage of fixe ...


References


Further reading

* * , * * * * * * . * * . * * * * * . * * * * * C. J. Pethick and H. Smith, ''Bose–Einstein Condensation in Dilute Gases'', Cambridge University Press, Cambridge, 2001. * Lev P. Pitaevskii and S. Stringari, ''Bose–Einstein Condensation'', Clarendon Press, Oxford, 2003. * * Monique Combescot and Shiue-Yuan Shiau, "Excitons and Cooper Pairs: Two Composite Bosons in Many-Body Physics", Oxford University Press ().


External links


Bose–Einstein Condensation 2009 Conference
Bose–Einstein Condensation 2009 – Frontiers in Quantum Gases

General introduction to Bose–Einstein condensation

– for the achievement of Bose–Einstein condensation in dilute gases of alkali atoms, and for early fundamental studies of the properties of the condensates *
Bose–Einstein condensates at JILAAtomcool at Rice UniversityAtom Optics at UQEinstein's manuscript on the Bose–Einstein condensate discovered at Leiden UniversityBose–Einstein condensate on arxiv.orgEasy BEC machine
– information on constructing a Bose–Einstein condensate machine.
Verging on absolute zero – Cosmos Online

Lecture by W Ketterle at MIT in 2001Bose–Einstein Condensation at NIST
NIST resource on BEC {{DEFAULTSORT:Bose-Einstein Condensate Albert Einstein Condensed matter physics Exotic matter Phases of matter Articles containing video clips