Brown spar or ''brown-spar'' ()
[''Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0] is a
trivial
Trivia is information and data that are considered to be of little value.
Modern usage of the term ''trivia'' dates to the 1960s, when college students introduced question-and-answer contests to their universities. A board game, ''Trivial Purs ...
, partly obsolete name for at least ''four''
carbonate mineral
Carbonate minerals are those minerals containing the carbonate ion, .
Carbonate divisions Anhydrous carbonates
*Calcite group: trigonal
**Calcite CaCO3
**Gaspéite (Ni,Mg,Fe2+)CO3
**Magnesite MgCO3
**Otavite CdCO3
**Rhodochrosite MnCO3
**Sider ...
s that are relatively similar in composition:
ankerite
Ankerite, also known as '' brown spar''礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese A ...
,
dolomite (with varieties),
magnesite
Magnesite is a mineral with the chemical formula ( magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts.
Occurrence
Magnesite occurs as veins in and an alteration product of ultramafic r ...
(with varieties) and
siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...
,
[Bulletin of the United States National Museum. No.30. Published under the Directions of the Smithsonian Institution. — Washington: Government Printing Office, 1885.] which have a characteristic dirty-brown hue due to the content of
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
compounds, as well as an admixture of
manganese oxide Manganese oxide is any of a variety of manganese oxides and hydroxides.Wells A.F. (1984) ''Structural inorganic chemistry'' 5th edition Oxford Science Publications, . These include
* Manganese(II) oxide, MnO
* Manganese(II,III) oxide, Mn3O4
* Man ...
. As a consequence, many varieties of
dolomite, colored brown or grey-brown by impurities, are also known as ''brown spar''.
The name brown spar is both capacious and vividly descriptive, referring exclusively to the appearance of the stones; short and convenient for everyday conversational use, it was approximately equally characteristic of both English-language and German mineralogy until the end of the 19th century. However, even later this stable phrase remained in the speech of miners, geologists and other craft specialties — as a colloquial term of broad or not entirely definite meaning, applicable to three or even four different minerals.
[''Georgy Shcherbina''. Mountain English-Russian Dictionary. — Moscow, Vologda: Infra-Engineering, 2022. — 784 p.]
Main minerals and varieties
*
Ankerite
Ankerite, also known as '' brown spar''礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese A ...
is a mineral, a complex
carbonate
A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
from the
dolomite group,
in which some of the
magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
ions are replaced by
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
calculated formula Ca(Fe,Mg,Mn)(CO
3)
2. The chemical composition is sometimes complicated by impurities of
manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
and
cobalt
Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...
. The ferrous member of the dolomite-ankerite isomorphic series, structurally close to dolomite.
*
Dolomite or ''
bitter spar''
is a mineral common in the earth's crust from the class of carbonates with the chemical composition CaCO
3•MgCO
3, varieties close to dolomite from the same isomorphic series, colored brown or dirty brown by iron and manganese impurities (ferriferous dolomite)
can also be found under the name brown spar.
*
Siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...
is a
hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
or
sedimentary
Sedimentary rocks are types of rock formed by the cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or deposited at Earth's surface. Sedime ...
mineral, in composition
iron carbonate
Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula , that occurs naturally as the mineral siderite. At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations and carbonate anions ...
with the ideal formula FeCO
3, depending on the amount and nature of impurities, has a color from white or yellowish-white to reddish-brown. Dirty-colored differences of brown shades are known as brown spar.
['' Lodotshnikov V. N.'' The main rock-forming minerals. — Moscow: ]Nedra
''Nedra'' is a genus of moths of the family Noctuidae
The Noctuidae, commonly known as owlet moths, cutworms or armyworms, are a family (biology), family of moths. Taxonomically, they are considered the most controversial family in the superfa ...
, 1974. — 248 p.
*
Magnesite
Magnesite is a mineral with the chemical formula ( magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts.
Occurrence
Magnesite occurs as veins in and an alteration product of ultramafic r ...
(ferrous)
or
breunnerite[礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese Academy of Sciences, 1956. — 279 p.] is a mineral common in the earth's crust from the class of carbonates with the chemical composition MgCO
3. Among the most common impurities found in magnesite are the same
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
ions (Fe
2+) or
manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
, which give the white or translucent mineral a cloudy red or brown color. In such cases, it can also be called ''brown spar''.
*
Mesitine spar (
mesitite),
['' Brush, George Jarvis'' (1875). Manual of Determinative Mineralogy: with an introduction on blow-pipe analysis. — New York : John Wiley & Son, 1875.] or ''
breunnerite'' — a
carbonate of iron
Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula , that occurs naturally as the mineral siderite. At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations and carbonate anions ...
and
manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
, occurring in yellowish
rhombohedron
In geometry, a rhombohedron (also called a rhombic hexahedron or, inaccurately, a rhomboid) is a special case of a parallelepiped in which all six faces are congruent rhombi. It can be used to define the rhombohedral lattice system, a honeycomb w ...
s. This includes much of what is called
rhomb spar (
rhombic spar), or brown spar, which becomes rusty on exposure.
['' Dana, James Dwight'' (1853). Manual of Mineralogy: Including Observations on Mines, Rocks, Reduction of Ores and the Application of the Science to the Arts. — Durrie and Peck (5th edition), 1853.]
*
Mesitine spar (
pistomesite),
['' Justus Freiherr von Liebig''. Annual Report of the Progress of Chemistry, and the Allied Sciences, Physics, Mineralogy, and Geology. — Taylor, Walton, and Maberly, 1850. — 646 p.] — another brown variety of the
magnesite
Magnesite is a mineral with the chemical formula ( magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts.
Occurrence
Magnesite occurs as veins in and an alteration product of ultramafic r ...
→
siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...
isomorphic series, formerly known as
mesitite or brown spar and containing a greater amount of
iron carbonate
Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula , that occurs naturally as the mineral siderite. At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations and carbonate anions ...
than mesitite and breunnerite.
Brown spar gallery
Ankerite, Pyrite - Goldmyer Hot Springs, King Co, Washington, USA.jpg,
Dolomite hg.jpg,
Siderite iron ore.jpg,
Magnesite1.jpg,
Magnesite var. Breunnerite detail.jpg,
Mesitite.jpg,
See also
*
Satin spar
Satin spar, less commonly atlas spar, is a trivial, partly obsolete name for fibrous varieties of two minerals, gypsum and calcite,''Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ ...
*
Feldspar
Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
s
*
Azure spar
Azure spar, sometimes azur-spar, is a trivial and commercial, partly obsolete name for several of the most famous bright blue or blue-colored minerals, which also have similar names, most notably for lazurite and azurite,''Krivovichev V. G.'' Mi ...
*
Moonstone
*
Belomorite
*
Albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
References
{{Set index article
Set index articles on minerals
Iron minerals
Magnesium minerals
Calcium minerals
Manganese minerals
Mining terminology
Mineral groups