Boratabenzene
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Boratabenzene is the heteroaromatic anion with the formula 5H5BHsup>−. Derivatives of boratabenzene are ligands akin to
cyclopentadienyl Cyclopentadienyl can refer to *Cyclopentadienyl anion, or cyclopentadienide, **Cyclopentadienyl ligand *Cyclopentadienyl radical, • *Cyclopentadienyl cation, See also *Pentadienyl In organic chemistry, pentadienyl refers to the organic radic ...
anion. sandwich or half-sandwich type complexes of many transition metals have been reported.{{cite journal , doi=10.1016/j.ccr.2015.07.014, title=Boratabenzene Rare-earth Metal Complexes, year=2016, last1=Cui, first1=Peng, last2=Chen, first2=Yaofeng, journal=Coordination Chemistry Reviews, volume=314, pages=2–13 Electronically related heterocycles are adducts of borabenzene. The adduct C5H5B. pyridine exhibits properties of boratabenzene anion, i.e., it has the character C5H5B-N+C5H5.


See also

* borabenzene, silabenzene,
germabenzene Germabenzene (C5H6Ge) is the parent representative of a group of chemical compounds containing in their molecular structure a benzene ring with a carbon atom replaced by a germanium atom. Germabenzene itself has been studied theoretically, and syn ...
,
stannabenzene Stannabenzene (C5H6Sn) is the parent representative of a group of organotin compounds that are related to benzene with a carbon atom replaced by a tin atom. Stannabenzene itself has been studied by computational chemistry, but has not been isolate ...
, pyridine,
phosphorine Phosphorine ( IUPAC name: phosphinine) is a heavier element analog of pyridine, containing a phosphorus atom instead of an aza- moiety. It is also called phosphabenzene and belongs to the phosphaalkene class. It is a colorless liquid that is ...
, arsabenzene,
bismabenzene Bismabenzene () is the parent representative of a group of organobismuth compounds that are related to benzene with a carbon atom replaced by a bismuth atom. Bismabenzene itself has been synthesised but not isolated because it is too reactive, te ...
, pyrylium, thiopyrylium,
selenopyrylium Selenopyrylium is an aromatic heterocyclic compound consisting of a six-membered ring with five carbon atoms and a positively charged selenium atom. Naming and numbering Formerly it was named selenapyrylium. However, this is misleading as "selena ...
,
telluropyrylium Telluropyrylium is an aromatic heterocyclic compound consisting of a six member ring with five carbon atoms, and a positively charged tellurium atom. Derivatives of telluropyrylium are important in research of infrared dyes. Naming and numbering ...
* Borazine


References

Boron heterocycles Six-membered rings