A binary cycle is a method for generating electrical power from
geothermal resources and employs two separate fluid cycles, hence binary cycle. The primary cycle extracts the geothermal energy from the
reservoir
A reservoir (; ) is an enlarged lake behind a dam, usually built to water storage, store fresh water, often doubling for hydroelectric power generation.
Reservoirs are created by controlling a watercourse that drains an existing body of wa ...
, and secondary cycle converts the
heat
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-atomic, ato ...
into
work
Work may refer to:
* Work (human activity), intentional activity people perform to support themselves, others, or the community
** Manual labour, physical work done by humans
** House work, housework, or homemaking
** Working animal, an ani ...
to drive the generator and generate
electricity
Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
.
Binary cycles permit electricity generation even from low temperature geothermal resources (<180°C) that would otherwise produce insufficient quantities of steam to make
flash power plants economically viable. However, due to the lower temperatures binary cycles have low overall efficiencies of about 10-13%.
Introduction

In contrast to conventional geothermal power generation methods like
dry-steam or
flash
Flash, flashes, or FLASH may refer to:
Arts, entertainment, and media
Fictional aliases
* The Flash, several DC Comics superheroes with super speed:
** Flash (Jay Garrick)
** Barry Allen
** Wally West, the first Kid Flash and third adult Flash ...
, which use a single open cycle, a binary cycle has two separate cycles operating in tandem, hence binary cycle. The primary cycle extracts heat from the
geothermal reservoir and provides this to the secondary cycle, which converts
heat
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by such mechanisms as thermal conduction, electromagnetic radiation, and friction, which are microscopic in nature, involving sub-atomic, ato ...
into
work
Work may refer to:
* Work (human activity), intentional activity people perform to support themselves, others, or the community
** Manual labour, physical work done by humans
** House work, housework, or homemaking
** Working animal, an ani ...
(see
Heat Engine
A heat engine is a system that transfers thermal energy to do mechanical or electrical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, pa ...
) to drive a
generator and produce
electricity
Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
. Thermodynamically, binary cycle power plants are similar to
coal-fired or
nuclear power plants
A nuclear power plant (NPP), also known as a nuclear power station (NPS), nuclear generating station (NGS) or atomic power station (APS) is a thermal power station in which the heat source is a nuclear reactor. As is typical of thermal power s ...
in that they employ
Rankine Power Cycles, the main difference being the heat source and the choice of cycle
working fluid
For fluid power, a working fluid is a gas or liquid that primarily transfers force, motion, or mechanical energy. In hydraulics, water or hydraulic fluid transfers force between hydraulic components such as hydraulic pumps, hydraulic cylinders, a ...
.
Primary cycle
The geothermal reservoir's hot in-situ fluid (or geofluid) is produced to the surface via a
wellbore
A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as petr ...
, if necessary assisted by a pump. On the surface, the hot geofluid transfers some of its heat to the secondary cycle, via a
heat exchanger
A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
, thus cooling in the process. The cold geofluid is then reinjected into the geothermal reservoir via a separate wellbore, where it is reheated. The primary cycle is considered an "open" cycle.
Secondary cycle
Cold high-pressure working fluid is heated and vapourised in a heat exchanger by the hot geofluid. The hot high-pressure vapour is expanded in a
turbine
A turbine ( or ) (from the Greek , ''tyrbē'', or Latin ''turbo'', meaning vortex) is a rotary mechanical device that extracts energy from a fluid flow and converts it into useful work. The work produced can be used for generating electrical ...
before being cooled and condensed in a
condenser. To close the loop, the cold low-pressure liquid is repressurised via a
feed pump. The secondary cycle is a closed cycle.
The two main secondary cycle configurations are
Organic Rankine cycles (ORC) or
Kalina cycles, the main difference being the choice of working fluid; an organic fluid (commonly a
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
or
refrigerant
A refrigerant is a working fluid used in the cooling, heating, or reverse cooling/heating cycles of air conditioning systems and heat pumps, where they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are ...
) or a
water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
-
ammonia
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...
mixture respectively.
History
The earliest example of a binary cycle geothermal power plant is thought to have been located on
Ischia
Ischia ( , , ) is a volcanic island in the Tyrrhenian Sea. It lies at the northern end of the Gulf of Naples, about from the city of Naples. It is the largest of the Phlegrean Islands. Although inhabited since the Bronze Age, as a Ancient G ...
,
Italy
Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land b ...
, between 1940-1943. The plant is thought to have used
Ethyl Chloride
Chloroethane, commonly known as ethyl chloride, is a chemical compound with chemical formula CH3CH2Cl, once widely used in producing tetraethyllead, a gasoline additive. It is a colorless, flammable gas or refrigerated liquid with a faintly sweet ...
as the working fluid at an effective capacity of 250 kW. However, owing to the
Second World War
World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
taking place at the same time, not much is known about this particular installation.
Another binary cycle geothermal power plant was taken into operation in 1967 near
Petropavlovsk on the
Kamchatka
The Kamchatka Peninsula (, ) is a peninsula in the Russian Far East, with an area of about . The Pacific Ocean and the Sea of Okhotsk make up the peninsula's eastern and western coastlines, respectively.
Immediately offshore along the Pacific ...
peninsula,
Russia
Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
. It was rated at 670 kW and ran for an unknown number of years, proving the concept of binary cycle geothermal power plants.
The first commercial-sized binary cycle geothermal plant was completed in 1979. The 11 MW design by J. Hilbert Anderson, Inc. was implemented by Magma Power to harvest power from the hot water fields in East Mesa, Southern California.
As of December 2014, there were 203 binary cycle geothermal power plants across 15 countries worldwide, representing 35% of all geothermal power plants, but only generating 10.4% of total geothermal power (about 1250 MW).
Variations
Dual pressure
The working fluid is evaporated at two different pressure levels, and thus temperatures. This improves efficiency by reducing exergetic losses in the primary heat exchanger by maintaining a closer match between the geofluid cooling curve and the working fluid heating curve.
Dual fluid
Two secondary cycles are operated in tandem, each with a separate working fluid and boiling point. This improves efficiency by reducing the exergetic losses of the heat introduction process, by ensuring a closer match between the geofluid cooling curve and the working fluids' heating curves.
Performance

The performance of a simple binary cycle and its individual components can be calculated as follows:
Turbine
*
is the rate of work done by the turbine, in
kW
*
is the mass flow rate of working fluid, in kg/s
*
is the turbine efficiency, non-dimensional
*
is the specific
enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant extern ...
of the working fluid at the turbine inlet, in kJ/kg
*
is the specific enthalpy of the working fluid at the turbine outlet, assuming isentropic expansion in the turbine, in kJ/kg
Condenser
The equation below can be used to determine the condenser duty and mass flow rate of coolant required.
:
*
is the rate of heat removed from the working fluid in the condenser, in kW
*
&
are the specific enthalpy of the working fluid at the condenser inlet and outlet respectively, in kJ/kg
*
is the mass flow rate of coolant, in kg/s
*
&
are the specific enthalpy of coolant at the condenser inlet and outlet respectively, in kJ/kg
Feed Pump
:
*
is the rate of work done by the pump to repressurise the working fluid, in kW
*
is the specific enthalpy of the working fluid at the feed pump outlet, assuming isentropic compression, in kJ/kg
*
is the specific enthalpy of the working fluid at the feed pump inlet, in kJ/kg
*
is the pump efficiency, non-dimensional
Primary Heat Exchanger
The equation below can be used to determine the primary heat exchanger duty and mass flow rate of geofluid required.
:
*
is the rate of heat added to the working fluid within the primary heat exchanger, kW
*
is the specific enthalpy of the working fluid at the primary heat exchanger inlet, in kJ/kg
*
is the mass flow rate of geofluid, in kg/s
*
&
are the specific enthalpy of the geofluid at the primary heat exchanger inlet and outlet respectively, in kJ/kg
Efficiency
There are a number of different definitions of efficiency that may be considered; these are discussed below.
First law efficiency
The first law efficiency (from the
First law of thermodynamics
The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. For a thermodynamic process affecting a thermodynamic system without transfer of matter, the law distinguishes two ...
) is a measure of the conversion of the heat provided to the cycle into useful work. When accounting for real life losses and inefficiencies, real binary cycle geothermal plants have a first law efficiency of between 10-13%.
:
Carnot efficiency
The Carnot efficiency gives the efficiency of an ideal thermodynamic cycle, operating between two reservoirs of different temperatures, as such it provides a theoretical maximum to the efficiency of any heat engine. For this reason, a geothermal power plant producing hot geofluid at 180°C (≈450 K) and rejecting heat at 25°C (≈298 K) has a maximum efficiency of just 34%.
:
*
&
are the hot and cold absolute temperature respectively, in K
Second law efficiency
The second law efficiency (from the
Second law of thermodynamics
The second law of thermodynamics is a physical law based on Universal (metaphysics), universal empirical observation concerning heat and Energy transformation, energy interconversions. A simple statement of the law is that heat always flows spont ...
) is a measure of the utilisation of the ideally maximum work available and conversion into useful work.
:
:*
is the exergy rate of geofluid, in kW.
:*
,
&
are the specific enthalpy, in kJ/kg, the specific
entropy
Entropy is a scientific concept, most commonly associated with states of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the micros ...
, in kJ/kg/K and the absolute temperature, in K, of the geofluid at the local reference condition. This could be local ambient,
wet-bulb or reinjection conditions.
Working fluid selection
The working fluid plays a pivotal role in any binary cycle and must be selected with care. Some criteria for selecting a suitable fluid are given below.
#A critical temperature and pressure above the cycle maximum temperature and pressure - most of the heat is transferred at the maximum temperature, increasing efficiency.
#A saturation dome that resembles an inverted U - this prevents liquid drop out in the turbine, which reduces efficiency, damages the turbine blades and thus reduces the turbine's lifetime.
#High thermal conductivity - improves the heat transfer in the primary heat exchanger and the condenser, reducing the total heat transfer area required and therefore cost of the plant.
#Environmental compatibility - non-
toxic
Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
, non-
carciogenic, low
global warming potential
Global warming potential (GWP) is a measure of how much heat a greenhouse gas traps in the atmosphere over a specific time period, relative to carbon dioxide (). It is expressed as a multiple of warming caused by the same mass of carbon dioxide ( ...
, low
ozone depletion potential
The ozone depletion potential (ODP) of a chemical compound is the relative amount of degradation to the ozone layer it can cause, with trichlorofluoromethane (R-11 or CFC-11) being fixed at an ODP of 1.0. Chlorodifluoromethane (R-22), for examp ...
, non-
flammable
A combustible material is a material that can burn (i.e., sustain a flame) in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort ...
, chemically inert.
#Low cost and readily available.
Power plants
There are numerous binary cycle power stations in commercial production.
Organic Rankine cycle
*
Olkaria III, Kenya
*
Mammoth Lakes, California, United States
*
Steamboat Springs (Nevada), United States
*
Te Huka Power Station, New Zealand
*Kirchstockach (Munich), Germany
*Traunreut, Germany
Kalina cycle
*
Husavik Power station
*
Geothermie Unterhaching
See also
*
Geothermal electricity
Geothermal power is electricity generation, electrical power generated from geothermal energy. Technologies in use include dry steam power stations, flash steam power stations and binary cycle power stations. Geothermal electricity generation i ...
*
Working fluid
For fluid power, a working fluid is a gas or liquid that primarily transfers force, motion, or mechanical energy. In hydraulics, water or hydraulic fluid transfers force between hydraulic components such as hydraulic pumps, hydraulic cylinders, a ...
*
Organic Rankine cycle
In thermal engineering, the organic Rankine cycle (ORC) is a type of thermodynamic cycle. It is a variation of the Rankine cycle named for its use of an organic, high- molecular-mass fluid (compared to water) whose vaporization temperature is l ...
*
Kalina cycle
References
{{Geothermal power
Geothermal energy